Polyol polymers, methods of preparing such polymers, and coating compositions containing the same

Abstract

A polyol polymer is obtained from reactants including: a) a non-aromatic epoxy functional compound that includes at least 30 weight % of the total solids weight of the reactants; and b) an aromatic mono-carboxylic acid functional compound, or anhydride thereof, that is substantially free of non-aromatic ethyl enic unsaturation. The polyol polymer has ester linkages and hydroxyl functional groups, Further, if the reactants further include an aromatic polycarboxylic acid, the aromatic polycarboxylic acid makes up less than 15 weight % of the total solids weight of the reactants. A coating composition is also prepared with the polyol polymer.

The invention claimed is: 
     
         1 . A polyol polymer obtained from reactants comprising:
 a) a non-aromatic epoxy functional compound that comprises at least 30 weight % of the total solids weight of the reactants; and   b) an aromatic mono-carboxylic acid functional compound, or anhydride thereof, that is substantially free of non-aromatic ethylenic unsaturation,   wherein the polyol polymer comprises ester linkages and hydroxyl functional groups, and   wherein, if the reactants further comprise an aromatic polycarboxylic acid, the aromatic polycarboxylic acid comprises less than 15 weight % of the total solids weight of the reactants.   
     
     
         2 . The polymer of  claim 1 , wherein the non-aromatic epoxy functional compound comprises a cycloaliphatic diglycidyl ether, a cycloaliphatic diglycidyl ester, a cycloaliphatic epoxide, or any combination thereof. 
     
     
         3 . The polymer of  claim 1 , wherein the non-aromatic epoxy functional compound comprises a hydrogenated bisphenol polyepoxide or a polyepoxide derived from a hydrogenated bisphenol compound. 
     
     
         4 . The polymer of  claim 1 , wherein the non-aromatic epoxy functional compound comprises at least 40 weight % of the total solids weight of the reactants. 
     
     
         5 . The polymer of  claim 1 , wherein the reactants further comprise a non-aromatic mono-carboxylic acid. 
     
     
         6 . The polymer of  claim 5 , wherein the non-aromatic mono-carboxylic acid further comprises a hydroxyl group. 
     
     
         7 . The polymer of  claim 1 , wherein the reactants further comprise a non-aromatic polycarboxylic acid. 
     
     
         8 . The polymer of  claim 1 , wherein the reactants further comprise an intramolecular cyclic ester. 
     
     
         9 . The polymer of  claim 1 , wherein the polyol polymer has a polydispersity index of 3.50 or less. 
     
     
         10 . The polymer of  claim 1 , wherein the polyol polymer has a hydroxyl value of at least 50 mg KOH/g. 
     
     
         11 . The polymer of  claim 1 , wherein the polyol polymer comprises carboxylic acid functional groups and epoxy functional groups, and has an epoxy-to-acid ratio of greater than 0.95. 
     
     
         12 . A coating composition comprising:
 i) a polyol polymer according to  claim 1 ; and   ii) a crosslinker reactive with the polyol polymer.   
     
     
         13 . The coating composition of  claim 12 , wherein the crosslinker comprises a polyisocyanate, aminoplast, or a combination thereof 
     
     
         14 . The coating composition of  claim 12 , further comprising a non-aqueous solvent. 
     
     
         15 . The coating composition of  claim 12 , further comprising a colorant. 
     
     
         16 . The coating composition of  claim 12 , wherein the reactants that form the polyol polymer further comprise a non-aromatic mono-carboxylic acid. 
     
     
         17 . The coating composition of  claim 12 , wherein the reactants that form the polyol polymer further comprise a non-aromatic polycarboxylic acid. 
     
     
         18 . The coating composition of  claim 12 , wherein the reactants that form the polyol polymer further comprise an intramolecular cyclic ester. 
     
     
         19 . A substrate at least partially coated with a coating formed from the composition of  claim 12 . 
     
     
         20 . The substrate of  claim 19 , wherein the coating is formed directly over a surface of the substrate. 
     
     
         21 . A method of forming a polyol polymer comprising:
 a) reacting reactants comprising:
 i) a non-aromatic epoxy functional compound that comprises at least 30 weight % of the total solids weight of the reactants; and 
 ii) an aromatic mono-carboxylic acid functional compound, or anhydride thereof, that is substantially free of non-aromatic ethylenic unsaturation, 
   wherein the polyol polymer comprises ester linkages and hydroxyl functional groups, and   wherein, if the reactants further comprise an aromatic polycarboxylic acid, the aromatic polycarboxylic acid comprises less than 15 weight % of the total solids weight of the reactants.   
     
     
         22 . The method of  claim 21 , wherein the reactants of step a) further comprise a non-aromatic mono-carboxylic acid, a non-aromatic polycarboxylic acid, or a combination thereof 
     
     
         23 . The method of  claim 21 , further comprising b) reacting a reaction product from step a) with an intramolecular cyclic ester.