Lubricant composition

Abstract

A lubricant composition for a compression-ignition internal combustion engine includes an amine and a detergent selected from metal sulfonates, phenates, salicylates, carboxylates, thiophosphonates, and combinations thereof. The lubricant composition has a TBN of from about 10 to about 100 mg KOH/g when tested according to ASTM D2896. The amine contributes from about 0.1 to about 28% of the TBN of the lubricant composition. Further, a method of lubricating an internal combustion engine with the lubricant composition includes the steps of injecting a fuel and the lubricant composition into a cylinder to form a mixture, and combusting the mixture via compression-ignition.

1 . A lubricant composition for a compression-ignition internal combustion engine, said lubricant composition comprising:
 (A) an amine selected from the group consisting of (I), (II), (III), (IV), and (IV) defined as follows:   
       
         
           
           
               
               
           
         
         
           wherein each of R 1  to R 9  are independently selected from a hydrogen, a C 1-6  branched or straight alkyl or a halogen; and 
           R 10  is selected from hydrogen, hydroxy or a C 1-20  branched or straight alkyl; 
         
       
       
         
           
           
               
               
           
         
         
           wherein R 1  and R 2  are independently selected from C 1-20  branched or straight alkyl; 
         
       
       
         
           
           
               
               
           
         
         
           wherein each of R 1  and R 2  are independently selected from a hydrogen, a C 1-6  branched or straight alkyl or a halogen; m and y are independently an integer of 1 to 6 and n is 1 to 7; 
         
       
       
         
           
           
               
               
           
         
         
           wherein R 1 . R 2 , and R 3  are independently selected from C 1-20  branched or straight alkyl; and 
         
       
       
         
           
           
               
               
           
         
         
           wherein R 1  to R 4  are independently selected from hydrogen and a C 1-6  alkyl and m is an integer of 1-12; and 
         
         (B) a detergent selected from metal sulfonates, phenates, salicylates, carboxylates, thiophosphonates, and combinations thereof,
 wherein a TBN of said lubricant composition is from about 10 to about 100 mg KOH/g when tested according to ASTM D2896; and 
 wherein a TBN contribution of said amine to said TBN of said lubricant composition is from about 0.1 to about 28%. 
 
       
     
     
         2 . The lubricant composition as set forth in  claim 1 , comprising the amine of group (I), wherein R 1 , R 2 , R 5 , R 8 , and R 9  are hydrogen and R 3 , R 4 , R 7  and R 8  are independently a C 1-3  alkyl; and wherein R 10  is a C 8-15  alkyl. 
     
     
         3 . The lubricant composition as set forth in  claim 2 , wherein R 1 , R 2 , R 5 , R 8 , and R 9  are hydrogen; R 3 , R 4 , R 7  and R 8  are a methyl; and R 10  is a C 11  alkyl. 
     
     
         4 . The lubricant composition as set forth in  claim 3 , wherein the amine has a structure of formula (Ia): 
       
         
           
           
               
               
           
         
       
     
     
         5 . The lubricant composition as set forth in  claim 1 , comprising the amine of group (II), wherein R 1  and R 2  are independently selected from a C 6-12  alkyl. 
     
     
         6 . The lubricant composition as set forth in  claim 5 , wherein R 1  and R 2  are both a branched C 8  alkyl. 
     
     
         7 . The lubricant composition as set forth in  claim 6 , wherein the amine has a structure of formula (IIa): 
       
         
           
           
               
               
           
         
       
     
     
         8 . The lubricant composition as set forth in  claim 1 , comprising the amine of group (III), wherein R 1  and R 2  are independently selected from a C 1-3  alkyl, and wherein m and y are independently an integer of 1-3. 
     
     
         9 . The lubricant composition as set forth in  claim 8 , wherein R 1  and R 2  are both a methyl, and wherein m and y are both 1. 
     
     
         10 . The lubricant composition as set forth in  claim 9 , wherein the amine has a structure of formula (IIIa): 
       
         
           
           
               
               
           
         
       
     
     
         11 . The lubricant composition as set forth in  claim 10 , wherein n ranges from 2 to 6.5 and the amine has a molecular weight ranging from 200 to 450. 
     
     
         12 . The lubricant composition as set forth in  claim 1 , comprising the amine of group (IV), wherein R 1 , R 2  and R 3  are independently selected from a C 6-12  alkyl. 
     
     
         13 . The lubricant composition as set forth in  claim 12 , wherein R 1 , R 2  and R 3  are both a branched C 8  alkyl. 
     
     
         14 . The lubricant composition as set forth in  claim 13 , wherein the amine has a structure of formula (IVa): 
       
         
           
           
               
               
           
         
       
     
     
         15 . The lubricant composition as set forth in  claim 1 , comprising the amine of group (V), wherein R 1  to R 4  are a C 1-3  alkyl and m is an integer of 4-8. 
     
     
         16 . The lubricant composition as set forth in  claim 15 , wherein R 1  to R 4  are a methyl and m is 6. 
     
     
         17 . The lubricant composition as set forth in  claim 16 , wherein the amine has a structure of formula (Va): 
       
         
           
           
               
               
           
         
       
     
     
         18 . The lubricant composition as set forth in  claim 1  wherein a TBN contribution of said amine to said TBN of said lubricant composition is from about 0.1 to about 20%. 
     
     
         19 . The lubricant composition as set forth in  claim 1  wherein said detergent comprises calcium. 
     
     
         20 . The lubricant composition as set forth in  claim 1  wherein said detergent comprises a calcium sulfonate. 
     
     
         21 .- 49 . (canceled)