Graphene membrane

Abstract

The present invention relates to a method of altering the relative proportions of protons, deuterons and tritons in a sample using a membrane. The membrane comprises a 2D material and an ionomer. The invention also relates to a method of making said membranes.

1 . A process for reducing or increasing the amount of tritium in a substance containing a mixture of tritium containing compounds on the one hand and hydrogen-containing and/or deuterium-containing compounds on the other, the process comprising;
 a) providing a membrane, the membrane comprising:
 a monolithic, continuous layer of graphene or hBN, wherein the monolithic, continuous layer of graphene or hBN is formed by chemical vapor deposition; 
 an ionomer coating provided on at least one side of the graphene or hBN; and 
 optionally a substrate, 
   b) providing a first sample of a substance containing a mixture of two or more of: hydrogen-containing, deuterium-containing or tritium-containing molecules which is in contact with a first face of the membrane,   c) providing a container which is in fluid communication with a second face of the membrane,   d) applying a potential difference between the first face and the second face, wherein applying the potential difference results in a second sample of the substance on the second side of the membrane, wherein the second sample of the substance contains proportionally less tritium than the first sample of the substance, and/or wherein applying the potential difference results in the first sample of the substance on the first side of the membrane containing proportionally more tritium than the first sample of the substance, and   e) recovering from the second side of the membrane a second sample of the substance which contains proportionally less tritium than the first sample of the substance and/or recovering from the first side of the membrane a product sample of the substance which contains proportionally more tritium than the first sample of the substance.   
     
     
         4 . The process of  claim 1 , wherein the ionomer is a proton conducting polymer. 
     
     
         5 . The process of  claim 4 , wherein the polymer is a sulfonated polymer. 
     
     
         6 . The process of  claim 5 , wherein the sulfonated polymer is Nafion®. 
     
     
         7 . The process of  claim 1 , wherein the monolithic layer of graphene or hBN is monolayer thick. 
     
     
         8 . The process of  claim 1 , wherein the monolithic layer of hBN is 2-5 layers thick. 
     
     
         9 . The process of  claim 1 , wherein the graphene or hBN includes a catalytic metal. 
     
     
         10 . The process of  claim 1 , wherein the substance is in solution.