US2021214816A1PendingUtilityA1

Method for fabricating steel sheet for press hardening, and parts obtained by this method

Assignee: ARCELORMITTALPriority: Jul 30, 2014Filed: Mar 30, 2021Published: Jul 15, 2021
Est. expiryJul 30, 2034(~8 yrs left)· nominal 20-yr term from priority
C21D 8/00C22C 38/18C21D 9/0068B21B 3/02C23C 2/12C22C 38/40C22C 38/38C21D 9/46C21D 8/02C22C 38/32C22C 38/04C22C 38/54C21D 8/0278C22C 38/48B21D 22/022C21D 8/0263C22C 38/08C22C 38/14C22C 38/12C22C 38/02C22C 38/06C21D 1/18C22C 38/44C21D 2211/009C22C 38/001C22C 38/002C21D 2211/008C22C 38/50C21D 1/673C21D 8/0236C23F 17/00C23C 2/40C22C 38/58C21D 1/06C21D 8/0226C21D 2211/002C21D 2211/005C21D 8/0273C23C 2/06C21D 8/005C23C 2/28C23C 2/29C23C 2/261
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Claims

Abstract

The present invention provides fabrication methods for cold rolled, precoated and press hardened steel sheets, for which the chemical composition includes, with contents expressed by weight, 0.24%≤C≤0.38%, 0.40%≤Mn≤3%, 0.10%≤Si≤0.70%, 0.015%≤Al≤0.070%, 0%≤Cr≤2%, 0.25%≤Ni≤2%, 0.015%≤Ti≤0.10%, 0%≤Nb≤0.060%, 0.0005%≤B≤0.0040%, 0.003%≤N≤0.010%, 0.0001%≤S≤0.005%, 0.0001%≤P≤0.025%, it being understood that the titanium and nitrogen content satisfy: Ti/N>3.42, and that the carbon, manganese, chromium and silicon content satisfy: 2.6C+Mn/5.3+Cr/13+Si/15≥1.1%, with the chemical composition optionally including one or more of the following elements: 0.05%≤Mo≤0.65%, 0.001%≤W≤0.30%, 0.0005%≤Ca≤0.005%, with the remainder made up of iron and inevitable impurities coming from preparation.

Claims

exact text as granted — not AI-modified
What is claimed is: 
     
         1 . A fabrication method for a cold rolled and annealed sheet, comprising the steps of:
 supplying a hot rolled sheet, coiled and pickled, and fabricated by:
 casting an intermediate product with a chemical composition including, with contents being expressed by weight:
 0.24%≤C≤0.38%; 
 0.40%≤Mn≤3%; 
 0.10%≤Si≤0.70%; 
 0.015%≤Al≤0.070%; 
 0%≤Cr≤2%; 
 0.25%≤Ni≤2%; 
 0.015%≤Ti≤0.10%; 
 0%≤Nb≤0.060%; 
 0.0005%≤B≤0.0040%; 
 0.003%≤N≤0.010%; 
 0.0001%≤S≤0.005%; and 
 0.0001%≤P≤0.025%; 
 
 the titanium and nitrogen contents satisfying Ti/N>3.42; 
 the carbon, manganese, chromium and silicon contents satisfying: 
   
       
         
           
             
               
                 
                   
                     
                       
                         2 
                         . 
                         6 
                       
                       ⁢ 
                       C 
                     
                     + 
                     
                       Mn 
                       
                         5 
                         . 
                         3 
                       
                     
                     + 
                     
                       Cr 
                       
                         1 
                         ⁢ 
                         3 
                       
                     
                     + 
                     
                       Si 
                       
                         1 
                         ⁢ 
                         5 
                       
                     
                   
                   ≥ 
                   1 
                 
                 ⁢ 
                 .1 
                 ⁢ 
                 % 
               
               ; 
             
           
         
         a remainder of the chemical composition being made up of iron and inevitable impurities resulting from processing;
 reheating the intermediate product to a temperature between 1250° C. and 1300° C. for a hold time between 20 and 45 minutes; 
 hot rolling the intermediate product until an end of rolling temperature, ERT, between 825° C. and 950° C. to obtain a heat rolled sheet; 
 coiling the hot rolled sheet at a temperature between 500° C. and 750° C. to obtain a hot rolled and coiled sheet; and 
 pickling an oxide layer formed during the preceding steps; 
 
         cold rolling the hot rolled, coiled and pickled sheet to obtain a cold rolled sheet; and 
         annealing the cold rolled sheet at a temperature between 740° C. and 820° to obtain a cold rolled and annealed sheet. 
       
     
     
         2 . A fabrication method for a precoated sheet, comprising the steps of:
 supplying a rolled sheet and fabricated by:
 casting an intermediate product with a chemical composition including, with contents being expressed by weight:
 0.24%≤C≤0.38%; 
 0.40%≤Mn≤3%; 
 0.10%≤Si≤0.70%; 
 0.015%≤Al≤0.070%; 
 0%≤Cr≤2%; 
 0.25%≤Ni≤2%; 
 0.015%≤Ti≤0.10%; 
 0%≤Nb≤0.060%; 
 0.0005%≤B≤0.0040%; 
 0.003%≤N≤0.010%; 
 0.0001%≤S≤0.005%; and 
 0.0001%≤P≤0.025%; 
 
 the titanium and nitrogen contents satisfying Ti/N>3.42; 
 the carbon, manganese, chromium and silicon contents satisfying: 
   
       
         
           
             
               
                 
                   
                     
                       
                         2 
                         . 
                         6 
                       
                       ⁢ 
                       C 
                     
                     + 
                     
                       Mn 
                       
                         5 
                         . 
                         3 
                       
                     
                     + 
                     
                       Cr 
                       
                         1 
                         ⁢ 
                         3 
                       
                     
                     + 
                     
                       Si 
                       
                         1 
                         ⁢ 
                         5 
                       
                     
                   
                   ≥ 
                   1 
                 
                 ⁢ 
                 .1 
                 ⁢ 
                 % 
               
               ; 
             
           
         
          and
 a remainder of the chemical composition being made up of iron and inevitable impurities resulting from processing; 
 reheating the intermediate product to a temperature between 1250° C. and 1300° C. for a hold time between 20 and 45 minutes; 
 hot rolling the intermediate product until an end of rolling temperature, ERT, between 825° C. and 950° C. to obtain a heat rolled sheet; 
 coiling the hot rolled sheet at a temperature between 500° C. and 750° C. to obtain a hot rolled and coiled sheet; and 
 pickling an oxide layer formed during the preceding steps; and 
 
         performing a continuous hot-dip pre-coating, the precoating being aluminum or an aluminum or aluminum-based alloy, or zinc or a zinc or zinc-based alloy. 
       
     
     
         3 . The fabrication method as recited in  claim 2  wherein the performing step is with the aluminum or aluminum-based alloy; and further comprising performing a thermal pretreatment of the precoated sheet at a temperature θ1 between 620° C. and 680° C. for a holding time t1 between 6 and 15 hours, such that the pre-coating no longer contains free aluminum of phase τ 5  of type Fe 3 Si 2 Al 2 , and τ 6  of type Fe 2 Si 2 Al 9 , and such that an austenitic transformation does not occur in the steel substrate, the pretreatment being done in a furnace under hydrogen and nitrogen atmosphere. 
     
     
         4 . A fabrication method for a press hardened part comprising the steps of:
 supplying a sheet fabricated by:
 casting an intermediate product with a chemical composition including, with contents being expressed by weight:
 0.24%≤C≤0.38%; 
 0.40%≤Mn≤3%; 
 0.10%≤Si≤0.70%; 
 0.015%≤Al≤0.070%; 
 0%≤Cr≤2%; 
 0.25%≤Ni≤2%; 
 0.015%≤Ti≤0.10%; 
 0%≤Nb≤0.060%; 
 0.0005%≤B≤0.0040%; 
 0.003%≤N≤0.010%; 
 0.0001%≤S≤0.005%; and 
 0.0001%≤P≤0.025%; 
 
 the titanium and nitrogen contents satisfying Ti/N>3.42; 
 the carbon, manganese, chromium and silicon contents satisfying: 
   
       
         
           
             
               
                 
                   
                     
                       
                         2 
                         . 
                         6 
                       
                       ⁢ 
                       C 
                     
                     + 
                     
                       Mn 
                       
                         5 
                         . 
                         3 
                       
                     
                     + 
                     
                       Cr 
                       
                         1 
                         ⁢ 
                         3 
                       
                     
                     + 
                     
                       Si 
                       
                         1 
                         ⁢ 
                         5 
                       
                     
                   
                   ≥ 
                   1 
                 
                 ⁢ 
                 .1 
                 ⁢ 
                 % 
               
               ; 
             
           
         
          and
 a remainder of the chemical composition being made up of iron and inevitable impurities resulting from processing; 
 reheating the intermediate product to a temperature between 1250° C. and 1300° C. for a hold time between 20 and 45 minutes; 
 hot rolling the intermediate product until an end of rolling temperature, ERT, between 825° C. and 950° C. to obtain a heat rolled sheet; 
 coiling the hot rolled sheet at a temperature between 500° C. and 750° C. to obtain a hot rolled and coiled sheet; and 
 pickling an oxide layer formed during the preceding steps; 
 
         cutting the sheet to obtain a blank; 
         heating the blank to a temperature between 810° C. and 950° C. to obtain a fully austenitic structure in the steel; 
         transferring the blank inside a press; 
         hot stamping the blank to obtain a part; and 
         holding the part inside the press to obtain a hardening by martensitic transformation of the austenitic structure. 
       
     
     
         5 . The fabrication method as recited in  claim 4  wherein the steps are performed successively. 
     
     
         6 . The fabrication method as recited in  claim 4  further comprising the step of deforming the blank by cold stamping after the step of cutting the sheet. 
     
     
         7 . The fabrication method as recited in  claim 4  wherein the chemical composition includes at least one of the following elements, by weight:
 0.05%≤Mo≤0.65%; 
 0.001%≤W≤0.30%; and 
 0.0005%≤Ca≤0.005%. 
 
     
     
         8 . The fabrication method as recited in  claim 4  wherein the chemical composition includes, by weight:
 0.32%≤C≤0.36%; 
 0.40%≤Mn≤0.80%; and 
 0.05%≤Cr≤1.20%. 
 
     
     
         9 . The fabrication method as recited in  claim 4  wherein the chemical composition thereof includes, by weight:
 0.24%≤C≤0.28%; and 
 1.50%≤Mn≤3%. 
 
     
     
         10 . The fabrication method as recited in  claim 4  wherein the chemical composition includes, by weight:
 0.50%≤Si≤0.60%. 
 
     
     
         11 . The fabrication method as recited in  claim 4  wherein the chemical composition includes, by weight:
 0.30%≤Cr≤0.50%. 
 
     
     
         12 . The fabrication method as recited in  claim 4  wherein the chemical composition includes, by weight:
 0.30%≤Ni≤1.20%. 
 
     
     
         13 . The fabrication method as recited in  claim 4  wherein the chemical composition includes, by weight:
 0.30%≤Ni≤0.50%. 
 
     
     
         14 . The fabrication method as recited in  claim 4  wherein the chemical composition thereof comprises, by weight:
 0.020%≤Ti. 
 
     
     
         15 . The fabrication method as recited in  claim 4  wherein the chemical composition includes, by weight:
 0.020%≤Ti≤0.040%. 
 
     
     
         16 . The fabrication method as recited in  claim 4  wherein the chemical composition includes, by weight:
 0.15%≤Mo≤0.25%. 
 
     
     
         17 . The fabrication method as recited in  claim 4  wherein the chemical composition includes, by weight:
 0.010%≤Nb≤0.060%. 
 
     
     
         18 . The fabrication method as recited in  claim 4  wherein the chemical composition includes, by weight:
 0.030%≤Nb≤0.050%. 
 
     
     
         19 . The fabrication method as recited in  claim 4  wherein a diffusible hydrogen content below 0.16 ppm is obtained in the sheet.

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