US2021180158A1PendingUtilityA1

Ni-Based Superalloy Powder for Additive Manufacturing and an Article Made Therefrom

Assignee: CRS HOLDINGS INCPriority: Jan 23, 2019Filed: Jan 23, 2020Published: Jun 17, 2021
Est. expiryJan 23, 2039(~12.5 yrs left)· nominal 20-yr term from priority
C22C 19/057B22F 10/64B22F 10/38B22F 10/366B22F 10/28B22F 10/36C22C 19/03C22F 1/10C22C 19/056Y02P10/25B33Y 70/00B23K 26/342C22C 19/007B23K 35/3033B33Y 80/00
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Claims

Abstract

A nickel base superalloy powder for additive manufacturing applications is disclosed. The alloy powder has the following broad weight percent composition:C 0-0.1Mn0.5 max.Si  0-0.03Cr 4-16Fe 0-1.5Mo0-6W0-8Co 0-15Ti0-2Al0.5-5.5Nb0-6Ta 7.5-14.5Hf 0-2.0Zr 0-0.1Re0-6Ru0-3B  0-0.03The balance of the alloy is at least 50% nickel and the usual impurities. An article of manufacture made from the alloy is also disclosed.

Claims

exact text as granted — not AI-modified
1 . A high γ′ volume fraction Ni-base alloy optimized for laser and electron beam additive manufacturing processes with improved solidification and strain-age cracking resistance and high strength and creep resistance at elevated temperature, said alloy consisting essentially of, in weight percent, about 
       
         
           
                 
                 
                 
               
                     
                     
                 
                     
                   C 
                       0-0.1 
                 
                     
                   Mn 
                   0.5 max. 
                 
                     
                   Si 
                     0-0.03 
                 
                     
                   Cr 
                    4-16 
                 
                     
                   Fe 
                   1.5 max. 
                 
                     
                   Mo 
                   0-6 
                 
                     
                   W 
                   0-8 
                 
                     
                   Co 
                    0-15 
                 
                     
                   Ti 
                   0-2 
                 
                     
                   Al 
                   0.5-5.5 
                 
                     
                   Nb 
                   0-6 
                 
                     
                   Ta 
                    7.5-14.5 
                 
                     
                   Hf 
                       0-2.0 
                 
                     
                   Zr 
                       0-0.1 
                 
                     
                   Re 
                   0-6 
                 
                     
                   Ru 
                   0-3 
                 
                     
                   B 
                     0-0.03 
                 
                     
                     
                 
             
                
               
               
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
               
            
           
         
         and the balance of the alloy is at least about 50% nickel and the usual impurities found in commercial grades of Ni-base superalloys intended for the same use and service. 
       
     
     
         2 . The alloy claimed in  claim 1  which contains, about 
       
         
           
                 
                 
                 
               
                     
                     
                 
                     
                   Cr 
                    9-11 
                 
                     
                   Fe 
                   1 max. 
                 
                     
                   Mo 
                   2-5 
                 
                     
                   W 
                   0.5-2     
                 
                     
                   Co 
                   4-6 
                 
                     
                   Ti 
                       0-0.5 
                 
                     
                   Al 
                   3-5 
                 
                     
                   Nb 
                   3-5 
                 
                     
                   Ta 
                   7.5-9.5 
                 
                     
                   Hf 
                       0-0.5 
                 
                     
                   Re 
                   0-1 
                 
                     
                   Ru 
                   0-1 
                 
                     
                     
                 
             
                
               
               
                
                
                
                
                
                
                
                
                
                
                
                
                
               
            
           
         
         and the balance of the alloy is at least about 50% nickel and usual impurities. 
       
     
     
         3 . The alloy claimed in  claim 1  which contains about 
       
         
           
                 
                 
                 
               
                     
                     
                 
                     
                   Cr 
                    9-11 
                 
                     
                   Fe 
                   1 max. 
                 
                     
                   Mo 
                   2-5 
                 
                     
                   W 
                   0.5-2     
                 
                     
                   Co 
                   0.5-2     
                 
                     
                   Ti 
                       0-0.5 
                 
                     
                   Al 
                   3-5 
                 
                     
                   Nb 
                   2.5-4     
                 
                     
                   Ta 
                    8.5-10.5 
                 
                     
                   Hf 
                       0-0.5 
                 
                     
                   Re 
                   0-1 
                 
                     
                   Ru 
                   0-1 
                 
                     
                     
                 
             
                
               
               
                
                
                
                
                
                
                
                
                
                
                
                
                
               
            
           
         
         and the balance of the alloy is at least about 50% nickel and usual impurities. 
       
     
     
         4 . The alloy claimed in  claim 1  which contains about 
       
         
           
                 
                 
                 
               
                     
                     
                 
                     
                   Cr 
                   4-8 
                 
                     
                   Fe 
                   1 max. 
                 
                     
                   Mo 
                   0.5-1.5 
                 
                     
                   W 
                   6-8 
                 
                     
                   Co 
                   0-1 
                 
                     
                   Ti 
                   0-1 
                 
                     
                   Al 
                   3-5 
                 
                     
                   Nb 
                   0-1 
                 
                     
                   Ta 
                    8.5-10.5 
                 
                     
                   Hf 
                   0.5-1.5 
                 
                     
                   Re 
                   0-1 
                 
                     
                   Ru 
                   0-1 
                 
                     
                     
                 
             
                
               
               
                
                
                
                
                
                
                
                
                
                
                
                
                
               
            
           
         
         and the balance of the alloy is at least about 50% nickel and usual impurities. 
       
     
     
         5 . The alloy claimed in  claim 1  which contains about 
       
         
           
                 
                 
                 
               
                     
                     
                 
                     
                   Cr 
                    9-11 
                 
                     
                   Fe 
                   1 max. 
                 
                     
                   Mo 
                   2-5 
                 
                     
                   W 
                   3.5-4.5 
                 
                     
                   Co 
                   0.5-2     
                 
                     
                   Ti 
                       0-0.5 
                 
                     
                   Al 
                   3-5 
                 
                     
                   Nb 
                   2.5-4     
                 
                     
                   Ta 
                    8.5-10.5 
                 
                     
                   Hf 
                       0-0.5 
                 
                     
                   Re 
                   0-1 
                 
                     
                   Ru 
                   0-1 
                 
                     
                     
                 
             
                
               
               
                
                
                
                
                
                
                
                
                
                
                
                
                
               
            
           
         
         and the balance of the alloy is at least about 50% nickel and usual impurities. 
       
     
     
         6 . The alloy claimed in  claim 1  which contains about: 
       
         
           
                 
                 
                 
               
                     
                     
                 
                     
                   Cr 
                    8-10 
                 
                     
                   Fe 
                   1 max. 
                 
                     
                   Mo 
                   2-5 
                 
                     
                   W 
                   4-6 
                 
                     
                   Co 
                    9-11 
                 
                     
                   Ti 
                       0-0.5 
                 
                     
                   Al 
                       4-5.5 
                 
                     
                   Nb 
                   0-1 
                 
                     
                   Ta 
                    9.5-11.5 
                 
                     
                   Hf 
                       0-0.5 
                 
                     
                   Re 
                   0-1 
                 
                     
                   Ru 
                   0-1 
                 
                     
                     
                 
             
                
               
               
                
                
                
                
                
                
                
                
                
                
                
                
                
               
            
           
         
         and the balance of the alloy is at least about 50% nickel and the usual impurities. 
       
     
     
         7 . The alloy claimed in  claim 1  wherein Al+Ti is about 3 to about 6 weight percent and W+Mo+Ru+Re is about 2 to about 12 weight percent. 
     
     
         8 . The alloy claimed in  claim 7  wherein C+B+Si+Zr is less than about 0.15 weight percent for reducing solidification range and improving solidification cracking resistance. 
     
     
         9 . A high γ′ volume fraction Ni-base alloy optimized for laser and electron beam additive manufacturing processes with improved solidification and strain-age cracking resistance and high strength and creep resistance at elevated temperature, said alloy consisting essentially of, in weight percent, about 
       
         
           
                 
                 
                 
               
                     
                     
                 
                     
                   C 
                       0-0.1 
                 
                     
                   Mn 
                   0.5 max.   
                 
                     
                   Si 
                     0-0.03 
                 
                     
                   Cr 
                    4-11 
                 
                     
                   Fe 
                   1 max. 
                 
                     
                   Mo 
                   0-5 
                 
                     
                   W 
                   0.5-8     
                 
                     
                   Co 
                    0-10 
                 
                     
                   Ti 
                   0-1 
                 
                     
                   Al 
                   3-5 
                 
                     
                   Nb 
                   0-5 
                 
                     
                   Ta 
                    7.5-11.5 
                 
                     
                   Hf 
                       0-1.5 
                 
                     
                   Zr 
                       0-0.1 
                 
                     
                   Re 
                   0-5 
                 
                     
                   Ru 
                   0-3 
                 
                     
                   B 
                     0-0.03 
                 
                     
                     
                 
             
                
               
               
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
               
            
           
         
         and the balance of the alloy is at least about 50% nickel and the usual impurities found in commercial grades of Ni-base superalloys intended for the same use and service. 
       
     
     
         10 . The alloy claimed in  claim 9  which contains, about 
       
         
           
                 
                 
                 
               
                     
                     
                 
                     
                   Cr 
                    9-11 
                 
                     
                   Fe 
                   1 max. 
                 
                     
                   Mo 
                   2-5 
                 
                     
                   W 
                   0.5-2     
                 
                     
                   Co 
                   4-6 
                 
                     
                   Ti 
                       0-0.5 
                 
                     
                   Al 
                   3-5 
                 
                     
                   Nb 
                   3-5 
                 
                     
                   Ta 
                   7.5-9.5 
                 
                     
                   Hf 
                       0-0.5 
                 
                     
                   Re 
                   0-1 
                 
                     
                   Ru 
                   0-1 
                 
                     
                     
                 
             
                
               
               
                
                
                
                
                
                
                
                
                
                
                
                
                
               
            
           
         
         and the balance of the alloy is at least about 50% nickel and usual impurities. 
       
     
     
         11 . The alloy claimed in  claim 9  which contains about 
       
         
           
                 
                 
                 
               
                     
                     
                 
                     
                   Cr 
                    9-11 
                 
                     
                   Fe 
                   1 max. 
                 
                     
                   Mo 
                   2-5 
                 
                     
                   W 
                   0.5-2     
                 
                     
                   Co 
                   0.5-2     
                 
                     
                   Ti 
                       0-0.5 
                 
                     
                   Al 
                   3-5 
                 
                     
                   Nb 
                   2.5-4     
                 
                     
                   Ta 
                    8.5-10.5 
                 
                     
                   Hf 
                       0-0.5 
                 
                     
                   Re 
                   0-1 
                 
                     
                   Ru 
                   0-1 
                 
                     
                     
                 
             
                
               
               
                
                
                
                
                
                
                
                
                
                
                
                
                
               
            
           
         
         and the balance of the alloy is at least about 50% nickel and usual impurities. 
       
     
     
         12 . The alloy claimed in  claim 9  which contains about 
       
         
           
                 
                 
                 
               
                     
                     
                 
                     
                   Cr 
                   4-8 
                 
                     
                   Fe 
                   1 max. 
                 
                     
                   Mo 
                   0.5-1.5 
                 
                     
                   W 
                   6-8 
                 
                     
                   Co 
                   0-1 
                 
                     
                   Ti 
                   0-1 
                 
                     
                   Al 
                   3-5 
                 
                     
                   Nb 
                   0-1 
                 
                     
                   Ta 
                    8.5-10.5 
                 
                     
                   Hf 
                   0.5-1.5 
                 
                     
                   Re 
                   0-1 
                 
                     
                   Ru 
                   0-1 
                 
                     
                     
                 
             
                
               
               
                
                
                
                
                
                
                
                
                
                
                
                
                
               
            
           
         
         and the balance of the alloy is at least about 50% nickel and usual impurities. 
       
     
     
         13 . The alloy claimed in  claim 9  which contains about: 
       
         
           
                 
                 
                 
               
                     
                     
                 
                     
                   Cr 
                    9-11 
                 
                     
                   Fe 
                   1 max. 
                 
                     
                   Mo 
                   2-5 
                 
                     
                   W 
                   3.5-4.5 
                 
                     
                   Co 
                   0.5-2     
                 
                     
                   Ti 
                       0-0.5 
                 
                     
                   Al 
                   3-5 
                 
                     
                   Nb 
                   2.5-4     
                 
                     
                   Ta 
                    8.5-10.5 
                 
                     
                   Hf 
                       0-0.5 
                 
                     
                   Re 
                   0-1 
                 
                     
                   Ru 
                   0-1 
                 
                     
                     
                 
             
                
               
               
                
                
                
                
                
                
                
                
                
                
                
                
                
               
            
           
         
         and the balance of the alloy is at least about 50% nickel and usual impurities. 
       
     
     
         14 . The alloy claimed in  claim 9  wherein Al+Ti is about 3.5 to about 5.5 weight percent and W+Mo+Ru+Re is about 3 to about 10 weight percent. 
     
     
         15 . The alloy claimed in  claim 14  wherein C+B+Si+Zr is less than about 0.10 weight percent for reducing solidification range and improving solidification cracking resistance. 
     
     
         16 . The alloy claimed in  claim 1  or  claim 9  comprising a γ′ strengthening phase. 
     
     
         17 . The alloy claimed in  claim 16  wherein the γ′ phase has a volume fraction that is greater than 35%. 
     
     
         18 . The alloy claimed in  claim 17  wherein the γ′ phase has a volume fraction that is greater than 50%. 
     
     
         19 . The alloy claimed in  claim 1  or  claim 9  which has a γ′ solvus temperature 7 higher than 2050° F. (1121° C.).

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