Polarizing film with adhesive layer, and liquid crystal display device

Abstract

Provided is a polarizing film with a pressure-sensitive adhesive layer that can contribute to the widening of the color gamut of an image display apparatus, the polarizing film with a pressure-sensitive adhesive layer being suppressed in brightness reduction and being excellent in durability. The polarizing film with a pressure-sensitive adhesive layer of the present invention includes a polarizer and a pressure-sensitive adhesive layer arranged on at least one side of the polarizer. A distance between the polarizer and the pressure-sensitive adhesive layer is 25 μm or less. The pressure-sensitive adhesive layer has an absorption peak in a wavelength band in the range of from 580 nm to 610 nm. The pressure-sensitive adhesive layer contains a compound X represented by the general formula (I) or the general formula (II).

1 . A polarizing film with a pressure-sensitive adhesive layer, comprising:
 a polarizer; and   a pressure-sensitive adhesive layer arranged on at least one side of the polarizer,   wherein a distance between the polarizer and the pressure-sensitive adhesive layer is 25 μm or less,   wherein the pressure-sensitive adhesive layer has an absorption peak in a wavelength band in a range of from 580 nm to 610 nm, and   wherein the pressure-sensitive adhesive layer contains a compound X represented by the following general formula (I) or general formula (II):   
       
         
           
           
               
               
           
         
       
       in the formula (I),
 R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , and R 8  each independently represent a hydrogen atom, a halogen atom, a substituted or unsubstituted alkyl group having 1 or more and 20 or less carbon atoms, a substituent represented by the formula (a), or a substituent represented by the formula (b), 
 R 1  and R 2  form a saturated cyclic skeleton including 5 or 6 carbon atoms, and R 3 , R 4 , R 5 , R 6 , R 7 , and R 8  each independently represent a hydrogen atom, a halogen atom, which is preferably Cl, a substituted or unsubstituted alkyl group having 1 or more and 20 or less carbon atoms, a substituent represented by the formula (a), or a substituent represented by the formula (b), 
 R 2  and R 3  form a saturated cyclic skeleton including 5 to 7 carbon atoms, and R 1 , R 4 , R 5 , R 6 , R 7 , and R 8  each independently represent a hydrogen atom, a halogen atom, which is preferably Cl, a substituted or unsubstituted alkyl group having 1 or more and 20 or less carbon atoms, a substituent represented by the formula (a), or a substituent represented by the formula (b), 
 R 5  and R 6  form a saturated cyclic skeleton including 5 or 6 carbon atoms, and R 1 , R 2 , R 3 , R 4 , R 7 , and R 8  each independently represent a hydrogen atom, a halogen atom, which is preferably Cl, a substituted or unsubstituted alkyl group having 1 or more and 20 or less carbon atoms, a substituent represented by the formula (a), or a substituent represented by the formula (b), 
 R 6  and R 7  form a saturated cyclic skeleton including 5 to 7 carbon atoms, and R 1 , R 2 , R 3 , R 4 , R 5 , and R 8  each independently represent a hydrogen atom, a halogen atom, which is preferably Cl, a substituted or unsubstituted alkyl group having 1 or more and 20 or less carbon atoms, a substituent represented by the formula (a), or a substituent represented by the formula (b), 
 R 1  and R 2  form a saturated cyclic skeleton including 5 or 6 carbon atoms, R 5  and R 6  form a saturated cyclic skeleton including 5 or 6 carbon atoms, and R 3 , R 4 , R 7 , and R 8  each independently represent a hydrogen atom, a halogen atom, which is preferably Cl, a substituted or unsubstituted alkyl group having 1 or more and 20 or less carbon atoms, a substituent represented by the formula (a), or a substituent represented by the formula (b), or 
 R 2  and R 3  form a saturated cyclic skeleton including 5 to 7 carbon atoms, R 6  and R 7  form a saturated cyclic skeleton including 5 to 7 carbon atoms, and R 1 , R 4 , R 5 , and R 8  each independently represent a hydrogen atom, a halogen atom, which is preferably Cl, a substituted or unsubstituted alkyl group having 1 or more and 20 or less carbon atoms, a substituent represented by the formula (a), or a substituent represented by the formula (b); and 
 in the formula (II), R 4  and R 8  each independently represent a hydrogen atom, or a substituted or unsubstituted alkyl group having 1 or more and 20 or less carbon atoms. 
 
     
     
         2 . The polarizing film with a pressure-sensitive adhesive layer according to  claim 1 , wherein the polarizer is a polyvinyl alcohol-based polarizer. 
     
     
         3 . The polarizing film with a pressure-sensitive adhesive layer according to  claim 1 , wherein the polarizer and the pressure-sensitive adhesive layer are directly laminated. 
     
     
         4 . The polarizing film with a pressure-sensitive adhesive layer according to  claim 1 , wherein the polarizer has an oxygen permeability of 1 [cm 3 /(m 2 ·24 h·atm)] or less. 
     
     
         5 . The polarizing film with a pressure-sensitive adhesive layer according to  claim 1 , wherein the pressure-sensitive adhesive layer has a thickness of 25 μm or less. 
     
     
         6 . An image display apparatus, comprising the polarizing film with a pressure-sensitive adhesive layer of  claim 1 .