Method for treatment of elements obtained by an additive manufacturing process

Abstract

A method for treatment of elements obtained by an additive manufacturing process comprises applying on the element a treating agent in liquid or gaseous form.

1 . A method for treatment of polymer elements obtained by a powder-based additive manufacturing process comprising applying on the element a treating agent in liquid and/or gaseous form comprising at least one monovalent or polyvalent alcohol, and thereafter removing the treating agent and optionally recovering at least part of the treating agent. 
     
     
         2 . The method according to  claim 1 , wherein the treating agent comprises at least one substituted or unsubstituted aliphatic C 1 -C 10  alcohol or substituted or unsubstituted aromatic C 6 -C 12  alcohol or a mixture thereof. 
     
     
         3 . The method of  claim 1 , wherein the alcohol is ethanol, propanol, isopropanol, butanol, glycol, glycerol, benzyl alcohol, chloro benzene, trsiethylene glycol, 2,2,2-trifluoroethanol, hexafluoroisopropanol or a mixture thereof 
     
     
         4 . The method of  claim 1 , wherein the treating agent comprises at least one additional solvent and/or at least one plasticizer. 
     
     
         5 . The method of  claim 4 , wherein the additional solvent is esters, ethers, ketones, lactones, or DMSO and/or wherein the plasticizer is aromatic esters, aliphatic esters, cycloaliphatic esters, or bio-based compounds, wherein optionally the solvent is DMSO or γ-butyrolactone, and/or wherein optionally the plasticizer is at least one of phthalates, benzoates, citrates, adipates, sebacates, cyclohexane dicarboxylic acid alkyl esters, fatty oils, or essential oils. 
     
     
         6 . The method of  claim 1 , wherein the treating agent is applied for a period of about 1 second to about 60 minutes. 
     
     
         7 . The method of  claim 1 , wherein the treating agent comprises hexafluoroisopropanol and is applied in liquid form, optionally at a temperature in the range from about −3° C. up to the boiling point of the solvent used for a period of about 1 second to about 35 minutes; or is applied in vapor form, optionally for a time period of about 2 minutes to about 45 minutes. 
     
     
         8 . The method of  claim 1 , wherein the treating agent comprises at least ethanol and is applied at a temperature in the range of about 100° C. to about 165° C. for a period of about 5 seconds to about 40 minutes. 
     
     
         9 . The method of  claim 1 , wherein the treating agent is removed by extracting the vapor and/or drying the elements in an oven for a period of about 5 minutes to about 48 hours. 
     
     
         10 . The method of  claim 1 , wherein the treating agent is removed by contacting treated elements with an aqueous composition and thereafter by drying the elements. 
     
     
         11 . The method of  claim 1 , wherein the treating agent comprises HFIP and the treating agent is applied under a pressure of about 0.01 to about 0.9 bar. 
     
     
         12 . The method of  claim 1  further additionally comprising a functionalizing step, which comprises applying at least one functionalizing agent on the element during or after treatment with the treating agent. 
     
     
         13 . The method of  claim 1  wherein in addition to the application step at least one further application step and/or at least one functionalising step, which comprises applying at least one functionalizing agent on the element during or after treatment with the treating agent, are carried out. 
     
     
         14 . The method of  claim 1  wherein during at least one of the application steps and/or functionalising steps distribution means are used, wherein the distribution means optionally is a microwave, a fan propeller, and/or an ultrasound unit. 
     
     
         15 . The method of  claim 1  wherein a post-processing step is carried out after application of the treating agent and optionally a functionalising step, wherein the post-processing step comprises treating the elements with a post-processing composition. 
     
     
         16 . The method of  claim 1 , wherein the functionalizing agent comprises at least one agent a colorant, a dye, a pigment, a fiber, a hardening agent, a metal powder, an inorganic pigment or powder, an electrostatic discharge agent, a filler, a base, a finishing agent, and/or a plasticizer. 
     
     
         17 . The method of  claim 1 , wherein a colorant or dye solution is applied having a temperature in the range of about 50 to about 95° C., wherein the temperature is maintained over the treatment period or is increased or decreased continuously or incrementally. 
     
     
         18 . The method of  claim 1 , wherein the element has been obtained by a sintering/melting process, such as selected from the group consisting of a multi jet fusion process (MJF), a selective laser sintering process (SLS), a high-speed sintering process (HSS), a binder-jetting process, and a light induced process. 
     
     
         19 . The method of  claim 1 , wherein the polymer is polyamide selected from the group consisting of polyamide 6 (PA6), polyamide 6.6 (PA6.6), polyamide 11 (PA11), polyamide 12 (PA12), PA 4.6 (PA4.6), polyamide 612 (PA612), polyphthalamide (PPA); a thermoplastic polyamide or co-polyamide, and a blended or filled polyamide, or a copolymer, blend, or mixture thereof, polymethyl methacrylate (PMMA), polyoxy methylene (POM), polyethylene terephthalate (PET), polyether block amide (PEBA), poly carbonate (PC), polyethylene furanoate (PEF), polylactide (PLA), polyvinylchloride (PVC), thermoplastic polyurethane (TPU), thermoplastic polyamides (TPA), thermoplastic copolyester compounds (TPC), polyurethane, polysulfone, polyetherimide (PEI), styrene polymer or copolymer, or a thermoplastic polymer comprising polyetherimide and polycarbonate, or copolymers, blends, or mixtures of these polymers. 
     
     
         20 . (canceled) 
     
     
         21 . The method of  claim 1 , wherein a treatment agent recovery step is carried out by removing treating agent with a filtration unit with absorbed solvent and desorbing the solvent. 
     
     
         22 . The method of  claim 1 , wherein the treating agent is applied until the surface roughness has been reduced by 2 to 20 μm and the resultant element surface roughness Ra is from 0.3 to 10 μm. 
     
     
         23 . (canceled) 
     
     
         24 . A device for treatment of an element obtained by an additive manufacturing process comprising a chamber with a lid, at least one element contact area, a dosing unit for treating agent comprising a solvent feed line for feeding solvent into chamber from a solvent container, and a dosing means, optionally at least one distributor, a fan propeller, a withdrawal unit comprising a pump, and/or at least one recovery unit comprising at least one filter unit or a recovery trap. 
     
     
         25 . The device of  claim 24 , wherein the chamber is a vacuum unit or chamber comprising a microwave and/or ultrasound unit.