Cation-disordered oxides for rechargeable lithium batteries and other applications

Abstract

Embodiments related to cation-disordered lithium metal oxide compounds, their methods of manufacture, and use are described. In one embodiment, a cation-disordered lithium metal oxide includes LiaMbM′cO2 with a greater than 1. M includes at least one redox-active species with a first oxidation state n and an oxidation state n′ greater than n, and M is chosen such that a lithium-M oxide having a formula LiMO2 forms a cation-disordered rocksalt structure. M′ includes at least one charge-compensating species that has an oxidation state y that is greater than n.

1 . A lithium metal oxide having a general formula: Li a M b M′ c O 2 , said lithium metal oxide comprising LiMO 2  and Li d M′ e O 2 , said lithium metal oxide having a cation-disordered rocksalt structure, wherein M comprises one or more of a metallic species chosen from a group consisting of Ti, V, Cr, Ni, Co, Fe, Mn, Zr, Sb, and Mo, M being chosen such that LiMO 2  forms a cation-disordered rocksalt structure, and M having a first average oxidation degree n, wherein M′ comprises one or more of a metallic species chosen from a group consisting of Ti, Cr, Mn, Zr, Mo, Sn, Sb, and W, and M′ having a second average oxidation degree y greater than or equal to n, with 4<=y<=6, and wherein 1<a<=1.4, a+b+c=2, d+e=2, d+(e·y)=4, a+(b·n)+(c·y)=4, 1.3<=d<=1.7, and 0.2<=b<1. 
     
     
         2 - 47 . (canceled) 
     
     
         48 . The lithium metal oxide of  claim 1  wherein said disordered LiMO 2  rocksalt structure is enriched with Li d M′ e O 2 . 
     
     
         49 . The lithium metal oxide of  claim 1 , comprising Li 1+x/100 (NiTi) 1/2−x/120 Mo x/150 O 2 , and wherein 0<x<=30. 
     
     
         50 . The lithium metal oxide of  claim 1 , wherein n is between 2.7 and 3.3. 
     
     
         51 . The lithium metal oxide of  claim 1 , wherein M′ is one or more of a metallic species chosen from a group consisting of Mo and Cr, and wherein b=(8−5a)/3, c=[2(a−1)]/3, d=1.6, and e=0.4. 
     
     
         52 . The lithium metal oxide of  claim 1 , wherein M is an alloy of Ni and Ti in a 1:1 molar ratio and/or M′ is Mo and y is equal to 6. 
     
     
         53 . The lithium metal oxide of  claim 1 , wherein XRD of the lithium metal oxide collected using Cu Kα (K alpha) radiation shows, in a range 5-70 degrees of 2θ (2 theta), a series of normalized intensity ratios I′z, with I′z=Iz/I(111), Iz being an first intensity of a (z) peak and I(111) being a second intensity of a (111) peak, wherein when z refers to a (111) peak, I′z=1, when z refers to a (022) peak, 2 <I′z<5, and when z refers to a (002) peak, 4<I′z<10, wherein said series of normalized intensity ratios I′z corresponds to a disordered rocksalt LiMO 2  structure having a Fm-3 m space group. 
     
     
         54 . The lithium metal oxide of  claim 1 , wherein the lithium metal oxide has a lattice parameter greater than or equal to 4 Angstroms. 
     
     
         55 . The lithium metal oxide of  claim 1 , wherein the lithium metal oxide has a first capacity greater than 109 mAh/g when charged and discharged between 1.5 and 4.5V at 20 mA/g at room temperature. 
     
     
         56 . The lithium metal oxide of  claim 1 , wherein the lithium metal oxide presents a single phase cation-disordered rocksalt structure. 
     
     
         57 . The lithium metal oxide of  claim 1 , wherein the lattice parameter is between 4.13 Angstroms and 4.15 Angstroms. 
     
     
         58 . The lithium metal oxide of  claim 1 , wherein the lithium metal oxide has a first capacity greater than 150 mAh/g when charged and discharged between 1.5 and 4.5V at 20 mA/g at room temperature. 
     
     
         59 . An electrical device, comprising an electrode comprising the lithium metal oxide of  claim 1 . 
     
     
         60 . A lithium metal oxide comprising Li 1+x/100 (NiTi) 1/2−x/120 Mo x/150 O 2 , wherein 0<x<=30. 
     
     
         61 . A lithium metal oxide comprising:
 Li a M b M′ c O 2  having a cation-disordered rocksalt structure, wherein M comprises at least one redox-active metallic species having a first oxidation state n and a second oxidation state n′ greater than n, M′ comprises at least one charge-compensating metallic species having an oxidation state y greater than or equal to n, a is greater than 1, and b and c are greater than or equal to 0, and wherein M is chosen such that a lithium-M oxide having a formula LiMO 2  has a cation-disordered rocksalt structure.   
     
     
         62 . The lithium metal oxide of  claim 61 , wherein n is at least 1.8. 
     
     
         63 . The lithium metal oxide of  claim 61 , wherein y is at least 4. 
     
     
         64 . The lithium metal oxide of  claim 61 , wherein M includes at least one of Ti, V, Cr, Mn, Fe, Co, Ni, Zr, Sb, and Mo. 
     
     
         65 . The lithium metal oxide of  claim 61 , wherein M′ includes at least one of Ti, Cr, Mn, Zr, Mo, Sn, Sb, and W. 
     
     
         66 . The lithium metal oxide of  claim 61 , wherein a is less than or equal to 1.4.