Polyolefin resin modifier, polyolefin resin composition, modified polyolefin resin film, and laminated film

Abstract

Polyolefin resin modifiers are provided that contain a nonionic surfactant, an organic sulfonate salt, and an inorganic salt. The organic sulfonate salt can be at least one selected from the group consisting of alkylsulfonic acid alkali metal salts whose alkyl group has 6 to 22 carbon atoms, alkylarylsulfonic acid alkali metal salts whose alkyl group has 6 to 22 carbon atoms, and sulfonic aliphatic ester alkali metal salts whose alkyl group has 6 to 22 carbon atoms. The inorganic salt can be at least one selected from the group consisting of sodium sulfate, potassium sulfate, calcium sulfate, lithium sulfate, sodium chloride, potassium chloride, lithium chloride, magnesium chloride, and calcium chloride.

1 . A polyolefin resin modifier, comprising a nonionic surfactant, an organic sulfonate salt, and an inorganic salt, wherein
 the organic sulfonate salt is at least one selected from the group consisting of alkylsulfonic acid alkali metal salts whose alkyl group has 6 to 22 carbon atoms, alkylarylsulfonic acid alkali metal salts whose alkyl group has 6 to 22 carbon atoms, and sulfonic aliphatic ester alkali metal salts whose alkyl group has 6 to 22 carbon atoms, and   the inorganic salt is at least one selected from the group consisting of sodium sulfate, potassium sulfate, calcium sulfate, lithium sulfate, sodium chloride, potassium chloride, lithium chloride, magnesium chloride, and calcium chloride   
     
     
         2 . The polyolefin resin modifier according to  claim 1 , wherein the inorganic salt is sodium sulfate and/or sodium chloride. 
     
     
         3 . The polyolefin resin modifier according to  claim 1 , wherein the nonionic surfactant, the organic sulfonate salt, and the inorganic salt are contained at a mass ratio of (the nonionic surfactant+the organic sulfonate salt)/the inorganic salt=99.9995/0.0005 to 75/25. 
     
     
         4 . The polyolefin resin modifier according to  claim 1 , wherein the organic sulfonate salt is at least one selected from the group consisting of alkylsulfonic acid alkali metal salts whose alkyl group has 6 to 22 carbon atoms. 
     
     
         5 . The polyolefin resin modifier according to  claim 1 , wherein the nonionic surfactant is at least one selected from the group consisting of partial esters of a tri- to hexa-hydric polyol with an aliphatic carboxylic acid having 6 to 22 carbon atoms, alkyldiethanolamides whose acyl group has 6 to 22 carbon atoms, ester compounds represented by Chemical Formula 1, ester compounds represented by Chemical Formula 2, and ether compounds represented by Chemical Formula 3, 
       
         
           
           
               
               
           
         
         wherein R 1  is a hydrocarbon group having 5 to 21 carbon atoms, and 
         R 2  is a residue of a (poly)oxyalkylene glycol from which all hydroxyl groups have been eliminated, the (poly)oxyalkylene glycol having 2 to 200 carbon atoms having a (poly)oxyalkylene group constituted of oxyalkylene units having 2 to 4 carbon atoms in its molecule; 
       
       
         
           
           
               
               
           
         
         wherein R 3  and R 5  are each a hydrocarbon group having 5 to 21 carbon atoms, and 
         R 4  is a residue of a (poly)oxyalkylene glycol from which all hydroxyl groups have been eliminated, the (poly)oxyalkylene glycol having 2 to 200 carbon atoms having a (poly)oxyalkylene group constituted of oxyalkylene units having 2 to 4 carbon atoms in is molecule; and
   R 6 —O—R 7 -—OH   Chemical Formula 3:
 
 
         wherein R 6  is a hydrocarbon group having 6 to 22 carbon atoms, and 
         R 7  is a residue of a (poly)oxyalkylene glycol from which all hydroxyl groups have been eliminated, the (poly)oxyalkylene glycol having 2 to 200 carbon atoms having a (poly)oxyalkylene group constituted of oxyalkylene units having 2 to 4 carbon atoms in is molecule. 
       
     
     
         6 . The polyolefin resin modifier according to  claim 1 , wherein the nonionic surfactant is at least one selected from the group consisting of partial esters of a tri- to hexa-hydric polyol with an aliphatic carboxylic acid having 8 to 18 carbon atoms, ester compounds represented by Chemical Formula 1 in which R 1  is a hydrocarbon group having 7 to 17 carbon atoms, ester compounds represented by Chemical Formula 2 in which R 3  and R 5  are each a hydrocarbon group having 7 to 17 carbon atoms, and ether compounds represented by Chemical Formula 3 in which R 6  is a hydrocarbon group having 8 to 18 carbon atoms. 
     
     
         7 . A polyolefin resin composition, comprising a polyolefin resin and the polyolefin resin modifier according to  claim 1 . 
     
     
         8 . The polyolefin resin composition according to  claim 7 , wherein the polyolefin resin and the polyolefin resin modifier are contained in the polyolefin resin composition in amounts of 99.9% to 95.0% by mass and 0.1% to 5.0% by mass, respectively, so that the sum of the amounts of the polyolefin resin and the polyolefin resin modifier is equal to 100% by mass. 
     
     
         9 . A modified polyolefin resin film, which is formed by using the polyolefin resin composition according to  claim 7 . 
     
     
         10 . A laminated film, which is a two- or more layer laminated film, wherein at least one surface layer of the laminated film is formed by using the polyolefin resin composition according to  claim 7 .