US2021070781A1PendingUtilityA1

A process for the preparation of crisaborole

Assignee: OLON SPAPriority: Dec 21, 2017Filed: Jun 25, 2018Published: Mar 11, 2021
Est. expiryDec 21, 2037(~11.4 yrs left)· nominal 20-yr term from priority
C07B 2200/13C07C 253/30C07C 255/54C07B 47/00B01J 23/42C07F 5/027C07F 5/025C07C 39/15B01J 27/053C07C 39/205B01J 23/44C07C 37/02B01J 27/232
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Claims

Abstract

The present invention relates to a process for the preparation of crisaborole of formula (I): by preparing intermediates of formulas (II) and (III):

Claims

exact text as granted — not AI-modified
1 - 15 . (canceled) 
     
     
         16 . A process for the purification of Crisaborole which comprises dropwise addition of a 5:1 to 8:1 acetone:water mixture of the compound to water, followed by stirring at room temperature and filtration of the resulting product. 
     
     
         17 . A process according to claim  1  comprising the dropwise addition of a 7:1 acetone:water mixture. 
     
     
         18 . A process according to claim  1  wherein crisaborole of formula (I) 
       
         
           
           
               
               
           
         
         is obtained by: 
         a) converting compound of formula (II): 
       
       
         
           
           
               
               
           
         
         
           into compound of formula (III): 
         
       
       
         
           
           
               
               
           
         
         
           in the presence of a tri (C 1 -C 4 ) alkyl borate and a (C 4 -C 6 )alkyl lithium or aryl lithium and subsequent acidification of the reaction medium; and 
         
         b) converting the resulting compound of formula (III) into Crisaborole of formula (I) by catalytic hydrogenation.

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