US2021002319A1PendingUtilityA1

Compounds Produced From Stevia And Process For Producing The Same

64
Assignee: PURECIRCLE SDN BHDPriority: Apr 2, 2014Filed: Sep 21, 2020Published: Jan 7, 2021
Est. expiryApr 2, 2034(~7.7 yrs left)· nominal 20-yr term from priority
Inventors:Avetik Markosyan
C07H 1/00A23L 27/36A23L 27/33A61Q 19/00A23V 2002/00C07H 1/06C07H 15/24A23L 2/60A23L 33/10A61K 47/26A61K 36/28A61K 8/602A61K 2800/10
64
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Claims

Abstract

Various ingredients and compositions are prepared from Stevia rebaudiana Bertoni plant. The compositions can be used as bulking agents, and sweeteners in foods, beverages, cosmetics and pharmaceuticals.

Claims

exact text as granted — not AI-modified
We claim: 
     
         1 . A sweetener composition comprising:
 at least one isomerized  Stevia  compound; wherein the at least one isomerized  Stevia  compound has the formula:   
       
         
           
           
               
               
           
         
         and is selected from the group consisting of: 
       
       (1) iso-Rubusoside, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Glc.beta.1-; 
       (2) iso-Steviolbioside, where R.sub.1 is H, and R.sub.2 is Glc.beta.(1-2)Glc.beta.1-; 
       (3) iso-Stevioside, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Glc.beta.(1-2)Glc.beta.1-; 
       (4) Isomerized steviol glycoside formula 4, where R.sub.1 is Glc.beta.(1-2)Glc.beta.1-, and R.sub.2 is Glc.beta.1-; 
       (5) iso-Rebaudioside E, where R.sub.1 is Glc.beta.(1-2)Glc.beta.1-, and R.sub.2 is Glc.beta.(1-2)Glc.beta.1-; 
       (6) iso-Rebaudioside B, where R.sub.1 is H, and R.sub.2 is Glc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (7) DAQ3, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Glc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (8) iso-Rebaudioside D, where R.sub.1 is Glc.beta.(1-2)Glc.beta.1-, and R.sub.2 is Glc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (9) iso-Rebaudioside I, where R.sub.1 is Glc.beta.(1-3)Glc.beta.1-, and R.sub.2 is Glc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (10) iso-Rebaudioside G, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Glc.beta.(1-3)Glc.beta.1-; 
       (11) iso-Rebaudioside M, where R.sub.1 is Glc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-, and R.sub.2 is Glc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (12) Isomerized steviol glycoside formula 12, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Glc.beta.(1-6)Glc.beta.(1-2)Glc.beta.1-; 
       (13) iso-Rebaudioside L, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Glc.beta.(1-6)Glc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (14) iso-Dulcoside A, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Rha.alpha.(1-2)Glc.beta.1-; 
       (15) iso-Dulcoside B, where R.sub.1 is H, and R.sub.2 is Rha.alpha.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (16) iso-Rebaudioside C, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Rha.alpha.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (17) iso-Rebaudioside H, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Glc.beta.(1-3)Rha.alpha.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (18) iso-Rebaudioside K, where R.sub.1 is Glc.beta.(1-2)Glc.beta.1-, and R.sub.2 is Rha.alpha.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (19) iso-Rebaudioside J, where R.sub.1 is Rha.alpha.(1-2)Glc.beta.1-, and R.sub.2 is Glc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (20) iso-Rebaudioside N, where R.sub.1 is Rha.alpha.(1-2)[Glc.beta.(1-3)]Glc.beta.1-, and R.sub.2 is Glc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (21) iso-Rebaudioside O, where R.sub.1 is Glc.beta.(1-3)Rha.alpha.(1-2)[Glc.beta.(1-3)]Glc.beta.1-, and R.sub.2 is Glc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (22) Isomerized steviol glycoside formula 22, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Xy1.beta.(1-2)Glc.beta.1-; 
       (23) iso-Rebaudioside F, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Xy1.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (24) Isomerized steviol glycoside formula 24, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Glc.beta.(1-2)[Xy1.beta.(1-3)]Glc.beta.1-; 
       (25) Isomerized steviol glycoside formula 25, where R.sub.1 is Xy1.beta.(1-6)Glc.beta.1-, and R.sub.2 is Glc.beta.(1-2)Glc.beta.1-; 
       (26) Isomerized steviol glycoside formula 26, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Glc.beta.(1-2)[Fru.beta.(1-3)]Glc.beta.1-; 
       (27) Isomerized steviol glycoside formula 27, where R.sub.1 is Glc.alpha.(1-2)Glc.alpha.(1-4)Glc.beta.1-, and R.sub.2 is Glc.beta.(1-2)Glc.beta.1-; 
       (28) Isomerized steviol glycoside formula 28, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Glc.alpha.(1-3)Glc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (29) Isomerized steviol glycoside formula 29, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Glc.alpha.(1-4)Glc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (30) Isomerized steviol glycoside formula 30, where R.sub.1 is Glc.beta.1-, and R.sub.2 is 6-deoxy Glc.beta.(1-2)Glc.beta.1-; 
       (31) Isomerized steviol glycoside formula 31, where R.sub.1 is Glc.beta.1-, and R.sub.2 is 6-deoxyGlc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; and 
       (32) Isomerized steviol glycoside formula 32, where R.sub.1 is 6-deoxyGlc.beta.1-, and R.sub.0.2 is Glc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; and
 at least one additional substance selected from the group consisting of steviol glycosides, stevioside, rebaudioside A, rebaudioside B, rebaudioside C, rebaudioside D, rebaudioside E, rebaudioside F, rebaudioside M, rebaudioside N, rebaudioside O, dulcoside A, steviolbioside, rubusoside, glycosylated steviol glycosides, glucosylated steviol glycosides as well as other steviol glycosides found in  Stevia rebaudiana  plant and mixtures thereof,  Stevia  extract, Luo Han Guo extract, mogrosides, high-fructose corn syrup, corn syrup, invert sugar, fructooligosaccharides, inulin, inulooligosaccharides, coupling sugar, maltooligosaccharides, maltodextins, corn syrup solids, glucose, maltose, sucrose, lactose, aspartame, saccharin, sucralose, sugar alcohols and combination thereof. 
 
     
     
         2 . A flavor composition comprising:
 at least one isomerized  Stevia  compound; wherein the at least one isomerized  Stevia  compound has the formula:   
       
         
           
           
               
               
           
         
         and is selected from the group consisting of: 
       
       (1) iso-Rubusoside, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Glc.beta.1-; 
       (2) iso-Steviolbioside, where R.sub.1 is H, and R.sub.2 is Glc.beta.(1-2)Glc.beta.1-; 
       (3) iso-Stevioside, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Glc.beta.(1-2)Glc.beta.1-; 
       (4) Isomerized steviol glycoside formula 4, where R.sub.1 is Glc.beta.(1-2)Glc.beta.1-, and R.sub.2 is Glc.beta.1-; 
       (5) iso-Rebaudioside E, where R.sub.1 is Glc.beta.(1-2)Glc.beta.1-, and R.sub.2 is Glc.beta.(1-2)Glc.beta.1-; 
       (6) iso-Rebaudioside B, where R.sub.1 is H, and R.sub.2 is Glc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (7) DAQ3, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Glc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (8) iso-Rebaudioside D, where R.sub.1 is Glc.beta.(1-2)Glc.beta.1-, and R.sub.2 is Glc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (9) iso-Rebaudioside I, where R.sub.1 is Glc.beta.(1-3)Glc.beta.1-, and R.sub.2 is Glc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (10) iso-Rebaudioside G, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Glc.beta.(1-3)Glc.beta.1-; 
       (11) iso-Rebaudioside M, where R.sub.1 is Glc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-, and R.sub.2 is Glc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (12) Isomerized steviol glycoside formula 12, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Glc.beta.(1-6)Glc.beta.(1-2)Glc.beta.1-; 
       (13) iso-Rebaudioside L, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Glc.beta.(1-6)Glc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (14) iso-Dulcoside A, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Rha.alpha.(1-2)Glc.beta.1-; 
       (15) iso-Dulcoside B, where R.sub.1 is H, and R.sub.2 is Rha.alpha.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (16) iso-Rebaudioside C, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Rha.alpha.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (17) iso-Rebaudioside H, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Glc.beta.(1-3)Rha.alpha.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (18) iso-Rebaudioside K, where R.sub.1 is Glc.beta.(1-2)Glc.beta.1-, and R.sub.2 is Rha.alpha.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (19) iso-Rebaudioside J, where R.sub.1 is Rha.alpha.(1-2)Glc.beta.1-, and R.sub.2 is Glc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (20) iso-Rebaudioside N, where R.sub.1 is Rha.alpha.(1-2)[Glc.beta.(1-3)]Glc.beta.1-, and R.sub.2 is Glc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (21) iso-Rebaudioside O, where R.sub.1 is Glc.beta.(1-3)Rha.alpha.(1-2)[Glc.beta.(1-3)]Glc.beta.1-, and R.sub.2 is Glc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (22) Isomerized steviol glycoside formula 22, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Xy1.beta.(1-2)Glc.beta.1-; 
       (23) iso-Rebaudioside F, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Xy1.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (24) Isomerized steviol glycoside formula 24, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Glc.beta.(1-2)[Xy1.beta.(1-3)]Glc.beta.1-; 
       (25) Isomerized steviol glycoside formula 25, where R.sub.1 is Xy1.beta.(1-6)Glc.beta.1-, and R.sub.2 is Glc.beta.(1-2)Glc.beta.1-; 
       (26) Isomerized steviol glycoside formula 26, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Glc.beta.(1-2)[Fru.beta.(1-3)]Glc.beta.1-; 
       (27) Isomerized steviol glycoside formula 27, where R.sub.1 is Glc.alpha.(1-2)Glc.alpha.(1-4)Glc.beta.1-, and R.sub.2 is Glc.beta.(1-2)Glc.beta.1-; 
       (28) Isomerized steviol glycoside formula 28, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Glc.alpha.(1-3)Glc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (29) Isomerized steviol glycoside formula 29, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Glc.alpha.(1-4)Glc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (30) Isomerized steviol glycoside formula 30, where R.sub.1 is Glc.beta.1-, and R.sub.2 is 6-deoxy Glc.beta.(1-2)Glc.beta.1-; 
       (31) Isomerized steviol glycoside formula 31, where R.sub.1 is Glc.beta.1-, and R.sub.2 is 6-deoxyGlc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; and 
       (32) Isomerized steviol glycoside formula 32, where R.sub.1 is 6-deoxyGlc.beta.1-, and R.sub.0.2 is Glc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; and
 at least one additional flavoring agent selected from the group consisting of lemon, berry, orange, fruit, banana, grape, pear, pineapple, mango, bitter almond, cola, cinnamon, sugar, cotton candy, vanilla, terpenoid glycosides and combination thereof. 
 
     
     
         3 . A food ingredient comprising:
 at least one isomerized  Stevia  compound; wherein the at least one isomerized  Stevia  compound has the formula:   
       
         
           
           
               
               
           
         
         and is selected from the group consisting of: 
       
       (1) iso-Rubusoside, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Glc.beta.1-; 
       (2) iso-Steviolbioside, where R.sub.1 is H, and R.sub.2 is Glc.beta.(1-2)Glc.beta.1-; 
       (3) iso-Stevioside, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Glc.beta.(1-2)Glc.beta.1-; 
       (4) Isomerized steviol glycoside formula 4, where R.sub.1 is Glc.beta.(1-2)Glc.beta.1-, and R.sub.2 is Glc.beta.1-; 
       (5) iso-Rebaudioside E, where R.sub.1 is Glc.beta.(1-2)Glc.beta.1-, and R.sub.2 is Glc.beta.(1-2)Glc.beta.1-; 
       (6) iso-Rebaudioside B, where R.sub.1 is H, and R.sub.2 is Glc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (7) DAQ3, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Glc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (8) iso-Rebaudioside D, where R.sub.1 is Glc.beta.(1-2)Glc.beta.1-, and R.sub.2 is Glc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (9) iso-Rebaudioside I, where R.sub.1 is Glc.beta.(1-3)Glc.beta.1-, and R.sub.2 is Glc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (10) iso-Rebaudioside G, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Glc.beta.(1-3)Glc.beta.1-; 
       (11) iso-Rebaudioside M, where R.sub.1 is Glc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-, and R.sub.2 is Glc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (12) Isomerized steviol glycoside formula 12, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Glc.beta.(1-6)Glc.beta.(1-2)Glc.beta.1-; 
       (13) iso-Rebaudioside L, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Glc.beta.(1-6)Glc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (14) iso-Dulcoside A, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Rha.alpha.(1-2)Glc.beta.1-; 
       (15) iso-Dulcoside B, where R.sub.1 is H, and R.sub.2 is Rha.alpha.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (16) iso-Rebaudioside C, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Rha.alpha.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (17) iso-Rebaudioside H, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Glc.beta.(1-3)Rha.alpha.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (18) iso-Rebaudioside K, where R.sub.1 is Glc.beta.(1-2)Glc.beta.1-, and R.sub.2 is Rha.alpha.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (19) iso-Rebaudioside J, where R.sub.1 is Rha.alpha.(1-2)Glc.beta.1-, and R.sub.2 is Glc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (20) iso-Rebaudioside N, where R.sub.1 is Rha.alpha.(1-2)[Glc.beta.(1-3)]Glc.beta.1-, and R.sub.2 is Glc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (21) iso-Rebaudioside O, where R.sub.1 is Glc.beta.(1-3)Rha.alpha.(1-2)[Glc.beta.(1-3)]Glc.beta.1-, and R.sub.0.2 is Glc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (22) Isomerized steviol glycoside formula 22, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Xy1.beta.(1-2)Glc.beta.1-; 
       (23) iso-Rebaudioside F, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Xy1.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (24) Isomerized steviol glycoside formula 24, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Glc.beta.(1-2)[Xy1.beta.(1-3)]Glc.beta.1-; 
       (25) Isomerized steviol glycoside formula 25, where R.sub.1 is Xy1.beta.(1-6)Glc.beta.1-, and R.sub.0.2 is Glc.beta.(1-2)Glc.beta.1-; 
       (26) Isomerized steviol glycoside formula 26, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Glc.beta.(1-2)[Fru.beta.(1-3)]Glc.beta.1-; 
       (27) Isomerized steviol glycoside formula 27, where R.sub.1 is Glc.alpha.(1-2)Glc.alpha.(1-4)Glc.beta.1-, and R.sub.0.2 is Glc.beta.(1-2)Glc.beta.1-; 
       (28) Isomerized steviol glycoside formula 28, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Glc.alpha.(1-3)Glc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (29) Isomerized steviol glycoside formula 29, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Glc.alpha.(1-4)Glc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (30) Isomerized steviol glycoside formula 30, where R.sub.1 is Glc.beta.1-, and R.sub.2 is 6-deoxy Glc.beta.(1-2)Glc.beta.1-; 
       (31) Isomerized steviol glycoside formula 31, where R.sub.1 is Glc.beta.1-, and R.sub.2 is 6-deoxyGlc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; and 
       (32) Isomerized steviol glycoside formula 32, where R.sub.1 is 6-deoxyGlc.beta.1-, and R.sub.0.2 is Glc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; and
 at least one additional food ingredient selected from the group consisting of acidulants, organic and amino acids, coloring agents, bulking agents, modified starches, gums, texturizers, preservatives, antioxidants, emulsifiers, stabilisers, thickeners, gelling agents, and combination thereof. 
 
     
     
         4 . A food, beverage, cosmetic, pharmaceutical product or other consumable comprising at least one isomerized  Stevia  compound; wherein the at least one isomerized  Stevia  compound has the formula: 
       
         
           
           
               
               
           
         
         and is selected from the group consisting of: 
       
       (1) iso-Rubusoside, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Glc.beta.1-; 
       (2) iso-Steviolbioside, where R.sub.1 is H, and R.sub.2 is Glc.beta.(1-2)Glc.beta.1-; 
       (3) iso-Stevioside, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Glc.beta.(1-2)Glc.beta.1-; 
       (4) Isomerized steviol glycoside formula 4, where R.sub.1 is Glc.beta.(1-2)Glc.beta.1-, and R.sub.2 is Glc.beta.1-; 
       (5) iso-Rebaudioside E, where R.sub.1 is Glc.beta.(1-2)Glc.beta.1-, and R.sub.2 is Glc.beta.(1-2)Glc.beta.1-; 
       (6) iso-Rebaudioside B, where R.sub.1 is H, and R.sub.2 is Glc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (7) DAQ3, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Glc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (8) iso-Rebaudioside D, where R.sub.1 is Glc.beta.(1-2)Glc.beta.1-, and R.sub.2 is Glc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (9) iso-Rebaudioside I, where R.sub.1 is Glc.beta.(1-3)Glc.beta.1-, and R.sub.2 is Glc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (10) iso-Rebaudioside G, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Glc.beta.(1-3)Glc.beta.1-; 
       (11) iso-Rebaudioside M, where R.sub.1 is Glc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-, and R.sub.2 is Glc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (12) Isomerized steviol glycoside formula 12, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Glc.beta.(1-6)Glc.beta.(1-2)Glc.beta.1-; 
       (13) iso-Rebaudioside L, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Glc.beta.(1-6)Glc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (14) iso-Dulcoside A, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Rha.alpha.(1-2)Glc.beta.1-; 
       (15) iso-Dulcoside B, where R.sub.1 is H, and R.sub.2 is Rha.alpha.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (16) iso-Rebaudioside C, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Rha.alpha.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (17) iso-Rebaudioside H, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Glc.beta.(1-3)Rha.alpha.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (18) iso-Rebaudioside K, where R.sub.1 is Glc.beta.(1-2)Glc.beta.1-, and R.sub.2 is Rha.alpha.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (19) iso-Rebaudioside J, where R.sub.1 is Rha.alpha.(1-2)Glc.beta.1-, and R.sub.2 is Glc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (20) iso-Rebaudioside N, where R.sub.1 is Rha.alpha.(1-2)[Glc.beta.(1-3)]Glc.beta.1-, and R.sub.2 is Glc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (21) iso-Rebaudioside O, where R.sub.1 is Glc.beta.(1-3)Rha.alpha.(1-2)[Glc.beta.(1-3)]Glc.beta.1-, and R.sub.2 is Glc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (22) Isomerized steviol glycoside formula 22, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Xy1.beta.(1-2)Glc.beta.1-; 
       (23) iso-Rebaudioside F, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Xy1.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (24) Isomerized steviol glycoside formula 24, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Glc.beta.(1-2)[Xy1.beta.(1-3)]Glc.beta.1-; 
       (25) Isomerized steviol glycoside formula 25, where R.sub.1 is Xy1.beta.(1-6)Glc.beta.1-, and R.sub.2 is Glc.beta.(1-2)Glc.beta.1-; 
       (26) Isomerized steviol glycoside formula 26, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Glc.beta.(1-2)[Fru.beta.(1-3)]Glc.beta.1-; 
       (27) Isomerized steviol glycoside formula 27, where R.sub.1 is Glc.alpha.(1-2)Glc.alpha.(1-4)Glc.beta.1-, and R.sub.2 is Glc.beta.(1-2)Glc.beta.1-; 
       (28) Isomerized steviol glycoside formula 28, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Glc.alpha.(1-3)Glc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (29) Isomerized steviol glycoside formula 29, where R.sub.1 is Glc.beta.1-, and R.sub.2 is Glc.alpha.(1-4)Glc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; 
       (30) Isomerized steviol glycoside formula 30, where R.sub.1 is Glc.beta.1-, and R.sub.2 is 6-deoxyGlc.beta.(1-2)Glc.beta.1-; 
       (31) Isomerized steviol glycoside formula 31, where R.sub.1 is Glc.beta.1-, and R.sub.2 is 6-deoxyGlc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-; and 
       (32) Isomerized steviol glycoside formula 32, where R.sub.1 is 6-deoxyGlc.beta.1-, and R.sub.2 is Glc.beta.(1-2)[Glc.beta.(1-3)]Glc.beta.1-.

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