Skin- or hair-cleansing composition containing aqueous gelling agent, and methods for producing aqueous gelling agent and cleansing composition

Abstract

A skin- or hair-cleansing composition including a component (A), which is an aqueous gelling agent represented by general formula (1) described in the specification, and a component (B), which is an anionic surfactant, wherein the component (A) presents a viscosity of an aqueous solution containing 1 mass % of at 25° C. of 1,000 to 5,000 mPa·s and a clouding point of the aqueous solution containing 1 mass % of component (A) of 60° C. to 80° C., and has a weight average molecular weight of 10,000 to 30,000; a method for producing the aqueous gelling agent and a method for producing the skin- or hair-cleansing composition are provided.

1 . A skin- or hair-cleansing composition comprising components (A) and (B) below, wherein the component (A) presents a viscosity of an aqueous solution containing 1 mass % of at 25° C. of 1,000 to 5,000 mPa·s and a clouding point of the aqueous solution containing 1 mass % of component (A) of 60° C. to 80° C., and has a weight average molecular weight of 10,000 to 30,000;
 component (A): an aqueous gelling agent represented by general formula (1) below: 
 
       
         
           
           
               
               
           
         
         wherein R 1 , R 2 , R 8  and R 9  each independently denote a hydrocarbon group having 4 to 20 carbon atoms, R 3 , R 5  and R 7  each independently denote a divalent hydrocarbon group having 2 to 4 carbon atoms, R 4  and R 6  each independently denote a divalent hydrocarbon group having 3 to 16 carbon atoms, a and e each independently denote a number from 10 to 100, d denotes a number from 100 to 500, and g denotes a number from 0 to 10; and 
         component (B): an anionic surfactant. 
       
     
     
         2 . The skin- or hair-cleansing composition according to  claim 1 , wherein R 1 , R 2 , R 8  and R 9  in the aqueous gelling agent represented by general formula (1) as the component (A) each independently denote an aliphatic hydrocarbon group having 10 to 12 carbon atoms. 
     
     
         3 . The skin- or hair-cleansing composition according to  claim 1 , wherein R 4  and R 6  in the aqueous gelling agent represented by general formula (1) as the component (A) each independently denote a divalent aliphatic hydrocarbon group having 4 to 8 carbon atoms. 
     
     
         4 . The skin- or hair-cleansing composition according to  claim 1 , wherein component (B) is one or more selected from the group consisting of a higher fatty acid salt-based surfactant, a sulfonic acid salt-based surfactant and a sulfate ester salt-based surfactant. 
     
     
         5 . The skin- or hair-cleansing composition according to  claim 1 , further comprising an amphoteric surfactant as a component (C). 
     
     
         6 . The skin- or hair-cleansing composition according to  claim 5 , wherein component (C) is a betaine-based amphoteric surfactant. 
     
     
         7 . The skin- or hair-cleansing composition according to  claim 1 , further comprising a polyoxyethylene-polyoxypropylene block copolymer as a component (D). 
     
     
         8 . A method for producing an aqueous gelling agent represented by general formula (1) below and used to produce a skin- or hair-cleansing composition, the method comprising:
 adding an alcohol compound represented by general formula (2) at a molar ratio of 1.5 to 2.4 and a polyalkylene glycol represented by general formula (3) at a molar ratio of 0.5 to 1.4 to a diisocyanate compound represented by general formula (4) at a molar ratio of 2, and allowing these components to react in the presence of a higher fatty acid metal salt;   
       
         
           
           
               
               
           
         
         wherein R 1 , R 2 , R 8  and R 9  each independently denote a hydrocarbon group having 4 to 20 carbon atoms, R 3 , R 5  and R 7  each denote represent a divalent hydrocarbon group having 2 to 4 carbon atoms, R 4  and R 6  each independently denote a divalent hydrocarbon group having 3 to 16 carbon atoms, a and e each independently denote a number from 10 to 100, d denotes a number from 100 to 500, and g denotes a number from 0 to 10; 
       
       
         
           
           
               
               
           
         
         wherein R 10  and R 11  each independently denote a hydrocarbon group having 4 to 20 carbon atoms; R 12  denotes a divalent hydrocarbon group having 2 to 4 carbon atoms; and r denotes a number from 10 to 100; 
       
       
         
           
           
               
               
           
         
         wherein R n  denotes a divalent hydrocarbon group having 2 to 4 carbon atoms, and t denotes a number from 100 to 500; and
   OCN-Q-NCO   (4)
 
 
         wherein Q denotes a divalent hydrocarbon group having 3 to 16 carbon atoms. 
       
     
     
         9 . The production method according to  claim 8 , wherein the higher fatty acid metal salt is one or more kinds of higher fatty acid metal salts selected from the group consisting of lauric acid metal salts, myristic acid metal salts, palmitic acid metal salts, stearic acid metal salts, and oleic acid metal salts. 
     
     
         10 . The production method according to  claim 8 , wherein the higher fatty acid metal salt is a lauric acid metal salt. 
     
     
         11 . A method for producing a skin- or hair-cleansing composition, the method comprising:
 a step of obtaining an aqueous gelling agent represented by general formula (1) below by adding an alcohol compound represented by general formula (2) at a molar ratio of 1.5 to 2.4 and a polyalkylene glycol represented by general formula (3) at a molar ratio of 0.5 to 1.4 to a diisocyanate compound represented by general formula (4) at a molar ratio of 2, and allowing these components to react in the presence of a higher fatty acid metal salt, and   a step of combining said aqueous gelling agent with an anionic surfactant;   
       
         
           
           
               
               
           
         
         wherein R 1 , R 2 , R 8  and R 9  each independently denote a hydrocarbon group having 4 to 20 carbon atoms, R 3 , R 5  and R 7  each denote represent a divalent hydrocarbon group having 2 to 4 carbon atoms, R 4  and R 6  each independently denote a divalent hydrocarbon group having 3 to 16 carbon atoms, a and e each independently denote a number from 10 to 100, d denotes a number from 100 to 500, and g denotes a number from 0 to 10; 
       
       
         
           
           
               
               
           
         
         wherein R 10  and R 11  each independently denote a hydrocarbon group having 4 to 20 carbon atoms, R 12  denotes a divalent hydrocarbon group having 2 to 4 carbon atoms, and r denotes a number from 10 to 100; 
       
       
         
           
           
               
               
           
         
         wherein R 13  denotes a divalent hydrocarbon group having 2 to 4 carbon atoms, and t denotes a number from 100 to 500; and
   OCN-Q-NCO   (4)
 
 
         wherein Q denotes a divalent hydrocarbon group having 3 to 16 carbon atoms.