High strength munitions structures with inherent chemical energy

Abstract

Munitions structures comprising one or more high strength reactive alloys, in particular reactive bulk metallic glasses, have significant amounts of inherent chemical energy. This energy may be discharged by subjection of the munitions structure to rapid impulsive loading and fragmentation in the presence of oxygen and/or nitrogen. A munitions structure can be configured in both large and small penetrators, e.g. warheads and bullets, with increased lethality. The lethality of these munitions structures is augmented by means of rapidly and simultaneously imparting both mechanical energy (kinetic energy through impact and fragmentation) and chemical energy (blast and/or fireball) to a target. A high-strength reactive alloy can substitute at least in part one or both of explosives and inert structural materials in conventional munitions systems to improve performance and reduce parasitic weight of structural casing.

1 . A munitions structure for use in one or more munitions systems, comprising:
 at least one high strength reactive alloy,   wherein said high strength reactive alloy has an elastic strain limit of at least 1.2% and an enthalpy of oxidation of at least 1,400 calories per gram.   
     
     
         2 . The munitions structure of  claim 1 , wherein the high strength reactive alloy is a bulk-cast object. 
     
     
         3 . The munitions structure of  claim 1 , wherein said at least one high strength reactive alloy is a bulk metallic glass. 
     
     
         4 . The munitions structure of  claim 3 , wherein said bulk metallic glass is Zr-based. 
     
     
         5 . The munitions structure of  claim 1 , wherein said at least one high strength reactive alloy is a Zr-based bulk metallic glass having the formula:
   Zr a Hf b (Ta,Nb,Ti) c Cu d (Ni,Fe,Co) e Al f      wherein a is in a range of from 40 to 60, b is in a range of from 0 to 14, c is in a range of from 2 to 5, d is in a range of from 10 to 35, e is in a range of from 5 to 20, and f is in a range of from 7 to 12.   
     
     
         6 . The munitions structure of  claim 5 , wherein said Zr-based bulk metallic glass has the following formula:
   Zr a Hf b (Ta,Nb,Ti) c Cu d (Ni,Fe,Co) e Al f      wherein the ratio of (a+b+c) to (d+e) is in a range of from 1.2 to 2.5, and the ratio of (a+b) to c is in a range of from 10 to 20.   
     
     
         7 . The munitions structure of  claim 5 , wherein said Zr-based bulk metallic glass is substantially defined by the formula Zr 43  Hf 14  Nb 5  Cu 15.4  Ni 12.6  Al 10 . 
     
     
         8 . The munitions structure of  claim 1 , wherein said high strength reactive alloy has a yield strength of at least 120 ksi. 
     
     
         9 . The munitions structure of  claim 1 , wherein said high strength reactive alloy has:
 a yield strength of at least 200 ksi;   an elastic strain limit of at least 1.8%; and   an enthalpy of oxidation of at least 2,000 calories per gram.   
     
     
         10 . The munitions structure of  claim 1 , wherein said high strength reactive alloy has:
 a yield strength of at least 200 ksi;   an elastic strain limit of at least 1.8%; and   an enthalpy of oxidation of at least 15,000 calories per cc.   
     
     
         11 . The munitions structure of  claim 1 , further comprising one or more reinforcement materials, said reinforcement materials being one or more refractory metals, ceramics, or a combination of refractory metals and ceramics. 
     
     
         12 . A bulk metallic glass (“BMG”) material comprising:
 at least one high strength reactive alloy having an elastic strain limit of at least 1.2% and an enthalpy of oxidation of at least 1,400 calories per gram. 
 
     
     
         13 . The BMG of  claim 12 , wherein the BMG is Zr-based. 
     
     
         14 . The BMG of  claim 1 , wherein the at least one high strength reactive alloy has a formula of:
   Zr a Hf b (Ta,Nb,Ti) c Cu d (Ni,Fe,Co) e Al f      wherein a ranges from 40 to 60, b ranges from 0 to 14, c ranges from 2 to 5, d ranges from 10 to 35, e ranges from 5 to 20, and f ranges from 7 to 12.   
     
     
         15 . The BMG of  claim 14 , wherein the at least one high strength reactive alloy has a formula of:
   Zr a Hf b (Ta,Nb,Ti) c Cu d (Ni,Fe,Co) e Al f      wherein a ratio of (a+b+c) to (d+e) ranges from 1.2 to 2.5, and a ratio of (a+b) to c ranges from 10 to 20.   
     
     
         16 . The BMG of  claim 14 , wherein the formula is:
   Zr 43 Hf 14 Nb 5 Cu 15.4 Ni 12.6 Al 10      
     
     
         17 . The BMG of  claim 12 , wherein the at least one high strength reactive alloy further has a yield strength of at least 120 ksi. 
     
     
         18 . The BMG of  claim 12 , wherein the at least one high strength reactive alloy further has:
 a yield strength of at least 200 ksi,   an elastic strain limit of at least 1.8%, and   an enthalpy of oxidation of at least 2,000 calories per gram.   
     
     
         19 . The BMG of  claim 12 , wherein the at least one high strength reactive alloy further has:
 a yield strength of at least 200 ksi,   an elastic strain limit of at least 1.8%, and   an enthalpy of oxidation of at least 15,000 calories per cc.   
     
     
         20 . The BMG of  claim 12 , further comprising one or more reinforcement materials including one or more refractory metals, ceramics, or a combination of refractory metals and ceramics.