US2020378600A1PendingUtilityA1

Methods and systems for minimizing NOx and CO emissions in natural draft heaters

Assignee: MARATHON PETROLEUM CO LPPriority: May 30, 2019Filed: May 29, 2020Published: Dec 3, 2020
Est. expiryMay 30, 2039(~12.8 yrs left)· nominal 20-yr term from priority
F23N 3/002F23N 2900/05003F23N 5/242F23N 2225/06F23N 1/022F23N 2900/05001
57
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Claims

Abstract

Systems and methods for reducing NO x and CO emissions in a natural draft heater are disclosed. For example, the disclosure provides embodiments of systems and methods for controlling a draft value within a heater shell to deliver an amount of excess air to a burner to thereby maintain at least one of NOx emissions not exceeding 0.025 lb/MMBtu (HHV) and CO emissions not exceeding 0.01 lb/MMBtu (HHV) in a natural draft heater.

Claims

exact text as granted — not AI-modified
1 . A natural draft heater system comprising:
 a heater shell having a base and designed to circulate a flue gas internally therein via negative pressure, the flue gas being generated by combustion of a fuel within the heater shell;   one or more heating coils positioned within the heater shell, the one or more heating coils containing a process fluid and being arranged to transfer heat from the circulated flue gas to thereby heat the process fluid;   a draft sensor positioned within the heater shell to measure a negative pressure of the flue gas within the heater shell during operation of the natural draft heater;   a stack attached to the heater shell for venting of at least a portion of the circulated flue gas to atmosphere, the stack including an outer shell and a split-range stack damper positioned within the outer shell to maintain a negative pressure of the flue gas being vented from the natural draft heater, the split-range stack damper including a set of inner blades, a set of outer blades, and one or more actuators arranged to actuate the set of inner blades and the set of outer blades to thereby effectuate movement thereof;   at least one burner assembly connected proximate the base of and within the heater shell to combust the fuel when supplied thereto, thereby generating the flue gas that transfers heat to the process fluid contained within the one or more heating coils, the at least one burner assembly having:
 a burner positioned within the at least one burner assembly to ignite the fuel when being supplied to the burner, 
 a burner air sensor positioned adjacent the burner to measure a level of excess air, 
 an air plenum adjacent to the burner to distribute air into the burner, the air plenum including an air input to receive atmospheric air, 
 a burner air register in fluid communication with the air input to direct the atmospheric air into the air plenum, the burner air register having a housing, one or more plates attached to the housing and positioned in fluid communication with the air plenum to direct air flow into the plenum, and a handle attached to the housing to adjust the position of the one or more plates to effectuate a movement thereof, each of the one or more plates being configurable between one or more of an open position, a partially open position, and a closed position to selectively supply air to the air plenum, and 
 a fuel supply system including at least a fuel input conduit to deliver fuel to the burner, and 
   a controller in electrical communication with the burner air register, the burner air sensor, the draft sensor, and the one or more actuators in the split-range stack damper to control the negative pressure of the flue gas within the heater shell to deliver an amount of excess air to the burner to thereby maintain at least one of NO x  emissions not exceeding 0.025 lb/MMBtu (HHV) and CO emissions not exceeding 0.01 lb/MMBtu (HHV) in the natural draft heater.   
     
     
         2 . The natural draft heater system of  claim 1 , wherein the controller receives an input signal representative of negative pressure of the flue gas from the draft sensor. 
     
     
         3 . The natural draft heater system of  claim 2 , wherein the controller provides an output signal to the one or more actuators in the split-range stack damper to adjust the positioning of the set of inner blades and the set of outer blades of the split-range stack damper and thereby maintain the negative pressure of the flue gas to within a preselected range. 
     
     
         4 . The natural draft heater system of  claim 3 , wherein the preselected range is maintained in the range of about 0.10-inches water-column to about 0.15-inches water-column. 
     
     
         5 . The natural draft heater system of  claim 3 , wherein the output signal is in the form of a current delivered to the one or more actuators, the current being in the range of about 2 mA to about 20 mA, the one or more actuators being arranged to adjust the position of at least one of the set of inner blades and the set of outer blades in response to the current received. 
     
     
         6 . The natural draft heater system of  claim 1 , wherein the controller receives an input signal representative of excess air level from the burner air sensor. 
     
     
         7 . The natural draft heater system of  claim 6 , wherein the controller alerts an operator to adjust configuration of the one or more plates and thereby control the excess air in the burner to a value in the range of between about 15% to about 25% by weight based on the combined weight of air and fuel needed for complete combustion. 
     
     
         8 . The natural draft heater system of  claim 1 , wherein the heater shell includes a burner section positioned proximate the base where combustion of the fuel occurs, a radiant section positioned adjacent the burner section to receive heat energy from the burner section and radiate heat energy therefrom, and a convective section positioned adjacent the radiant section to provide convection from the radiant section. 
     
     
         9 . The natural draft heater system of  claim 8 , further comprising a bridge wall connected to the heater shell and positioned between the radiant section and the convective section thereof. 
     
     
         10 . The natural draft heater system of  claim 9 , wherein the draft sensor is positioned proximate the bridge wall such that the negative pressure of the flue gas is measured proximate the location of the bridge wall. 
     
     
         11 . The natural draft heater system of  claim 1 , wherein the fuel supply system further comprises a primary manifold assembly and a second, staged manifold assembly, the fuel input conduit positioned in fluid communication with the primary manifold assembly to deliver fuel to the primary manifold assembly, the primary manifold assembly positioned in fluid communication with one or both of a burner tip of the burner and the second, staged manifold assembly to deliver fuel to one or both of the burner tip of the burner and the second, staged manifold, the second, staged manifold assembly positioned in fluid communication with another burner tip to deliver fuel to the another burner tip. 
     
     
         12 . The natural draft heater system of  claim 11 , wherein the second, staged manifold assembly includes a staged manifold valve configurable to be in a closed position to shut off fuel flow or in an at least partially open position to direct a preselected amount of fuel to the another burner tip to achieve a desired concentration of air and fuel mixture in the another burner tip. 
     
     
         13 . The natural draft heater system of  claim 1 , wherein the at least one burner assembly is a plurality of burner assemblies positioned in sequence along the base of and within the heater shell to provide substantially even heating within the heater shell, the plurality of burner assemblies are independently controlled and operated during operation of the natural draft heater, such that one or more of the plurality of burner assemblies may be taken out of service during operation of the natural draft heater while the remaining burner assemblies remain operational. 
     
     
         14 . The natural draft heater system of  claim 1 , further comprising a burner fuel tip positioned within the burner and at least partially enclosed by a riser plate positioned adjacent thereto, the riser plate having a burner riser positioned proximate a base thereof and connected thereto by one or more riser welds to allow air to enter the riser plate between riser welds during operation of the natural draft heater. 
     
     
         15 . The natural draft heater system of  claim 14 , further comprising one or more air rings positioned about the burner riser proximate the one or more riser welds to reduce air entering the riser plate. 
     
     
         16 . The natural draft heater system of  claim 15 , wherein the one or more air rings are positioned to reduce air entering the riser plate when the natural draft heater is operating at rates greater than about 40% of design capacity. 
     
     
         17 . The natural draft heater system of  claim 15 , wherein the one or more air rings are selectively installed in one of the at least one burner assembly when that one burner assembly is taken out of service during operation of the natural draft heater so as to prevent air leakage into the heater shell and thereby reduce NO x  formation in the heater shell. 
     
     
         18 . The natural draft heater system of  claim 14 , further comprising a silicone seal applied at the connection between the burner risers and the riser plates to prevent air infiltration into the burner thereby reducing NO x  formation in the heater shell. 
     
     
         19 . The natural draft heater system of  claim 1 , further comprising a flame scanner positioned adjacent the air plenum to detect the presence of a flame in the burner. 
     
     
         20 . The natural draft heater system of  claim 19 , further comprising a purge air injection input positioned adjacent the flame scanner to deliver purge air directly to the burner, the purge air being used as combustion air by the burner thereby reducing NO x  formation within the heater shell. 
     
     
         21 . The natural draft heater system of  claim 20 , wherein the flame scanner and the purge air injection input are included on alternating burner assemblies when the at least one burner assembly includes two or more burner assemblies. 
     
     
         22 . The natural draft heater system of  claim 20 , wherein the flame scanner and the purge air injection input are absent on at least one burner assembly when the at least one burner assembly includes two or more burner assemblies. 
     
     
         23 . A natural draft heater system comprising:
 a heater shell designed to circulate a flue gas internally therein via negative pressure, the flue gas being generated by combustion of a fuel within the heater shell, the heater shell including a base, a burner section positioned proximate the base where combustion of the fuel occurs, a radiant section positioned adjacent the burner section to receive heat energy from the burner section and radiate heat energy therefrom, and a convective section positioned adjacent the radiant section to provide convection from the radiant section,   a bridge wall connected to the heater shell and positioned between the radiant section and the convective section,   one or more heating coils positioned within the heater shell proximate one or both of the radiant section and the convective section, the one or more heating coils containing a process fluid and being arranged to transfer heat from the circulated flue gas to thereby heat the process fluid;   a draft sensor positioned proximate the bridge wall to measure a bridge wall draft value related to the negative pressure of the flue gas within the heater shell during operation of the natural draft heater;   a stack positioned proximate the convective section of the heater shell for venting of at least a portion of the circulated flue gas to atmosphere, the stack including an outer shell and a split-range stack damper positioned within the outer shell to maintain the bridge wall draft of the flue gas being vented from the natural draft heater, the split-range stack damper including a set of inner blades, a set of outer blades, and one or more actuators arranged to actuate the set of inner blades and the set of outer blades to thereby effectuate movement thereof;   at least one burner assembly connected proximate the base of and within the heater shell to combust the fuel when supplied thereto, thereby generating the flue gas that transfers heat to the process fluid contained within the one or more heating coils, the at least one burner assembly having:
 a burner positioned within the at least one burner assembly to ignite the fuel when being supplied to the burner, 
 a burner air sensor positioned adjacent the burner to measure a level of excess air, 
 an air plenum adjacent to the burner to distribute air into the burner, the air plenum including an air input to receive atmospheric air, 
 a burner air register in fluid communication with the air input to direct the atmospheric air into the air plenum, the burner air register having a housing, one or more plates attached to the housing and positioned in fluid communication with the air plenum to direct air flow into the plenum, and a handle attached to the housing to adjust the position of the one or more plates to effectuate a movement thereof, each of the one or more plates being configurable between one or more of an open position, a partially open position, and a closed position to selectively supply air to the air plenum, and 
 a fuel supply system including a fuel input conduit, a primary manifold assembly, and a second, staged manifold assembly, the fuel input conduit positioned in fluid communication with the primary manifold assembly to deliver fuel to the primary manifold assembly, the primary manifold assembly positioned in fluid communication with one or both of a burner tip of the burner and the second, staged manifold assembly to deliver fuel to one or both of the burner tip of the burner and the second, staged manifold, the second, staged manifold assembly positioned in fluid communication with another burner tip to deliver fuel to the another burner tip, the second, staged manifold assembly including a staged manifold valve configurable to be in a closed position to shut off fuel flow or in an at least partially open position to direct a preselected amount of fuel to the another burner tip to achieve a desired concentration of air and fuel mixture in the another burner tip, and 
 a controller in electrical communication with the burner air register, the burner air sensor, the draft sensor, and the one or more actuators in the split-range stack damper to (a) control the bridge wall draft within the heater shell to deliver an amount of excess air to the burner to thereby maintain at least one of NO x  emissions not exceeding 0.025 lb/MMBtu (HHV) and CO emissions not exceeding 0.01 lb/MMBtu (HHV) in the natural draft heater, (b) receive an input signal representative of negative pressure of the flue gas from the draft sensor, (c) provide an output signal to the one or more actuators in the split-range stack damper to adjust the positioning of the set of inner blades and the set of outer blades of the split-range stack damper and thereby maintain the bridge wall draft value to within a preselected range, (d) receive an input signal representative of excess air level from the burner air sensor, and (e) provide an alert to an operator to adjust configuration of the one or more plates and thereby control the excess air in the burner to a value in the range of between about 15% to about 25% by weight based on the combined weight of air and fuel needed for complete combustion. 
   
     
     
         24 . The natural draft heater system of  claim 23 , wherein the preselected range of the bridge wall draft value is maintained in the range of about 0.10-inches water-column to about 0.15-inches water-column to provide the desired negative pressure within the natural draft heater during operation. 
     
     
         25 . The natural draft heater system of  claim 23 , wherein the at least one burner assembly is a plurality of burner assemblies positioned in sequence along the base of and within the heater shell to provide substantially even heating within the heater shell, the plurality of burner assemblies are independently controlled and operated during operation of the natural draft heater, such that one or more of the plurality of burner assemblies may be taken out of service during operation of the natural draft heater while the remaining burner assemblies remain operational. 
     
     
         26 . The natural draft heater system of  claim 23 , further comprising a burner fuel tip positioned within the burner and a riser plate positioned adjacent thereto at least partially enclosing the burner fuel tip, the riser plate having a burner riser positioned proximate a base thereof and connected thereto by one or more riser welds to allow air to enter the riser plate between riser welds during operation of the natural draft heater. 
     
     
         27 . The natural draft heater system of  claim 26 , further comprising one or more air rings positioned about the burner riser proximate the one or more riser welds to reduce air entering the riser plate. 
     
     
         28 . The natural draft heater system of  claim 27 , wherein the one or more air rings are positioned to reduce air entering the riser plate when the natural draft heater is operating at rates greater than about 40% of design capacity. 
     
     
         29 . The natural draft heater system of  claim 27 , wherein the one or more air rings are selectively installed in one of the at least one burner assembly when that one burner assembly is taken out of service during operation of the natural draft heater so as to prevent air leakage into the heater shell and thereby reduce NO x  formation in the heater shell. 
     
     
         30 . The natural draft heater system of  claim 26 , further comprising a silicone seal applied at the connection between the burner risers and the riser plates to prevent air infiltration into the burner thereby reducing NO x  formation in the heater shell. 
     
     
         31 . The natural draft heater system of  claim 23 , further comprising a flame scanner positioned adjacent the air plenum to detect the presence of a flame in the burner. 
     
     
         32 . The natural draft heater system of  claim 31 , further comprising a purge air injection input positioned adjacent the flame scanner to deliver purge air directly to the burner, the purge air being used as combustion air by the burner thereby reducing NO x  formation within the heater shell. 
     
     
         33 . The natural draft heater system of  claim 32 , wherein the flame scanner and the purge air injection input are included on alternating burner assemblies when the at least one burner assembly includes two or more burner assemblies. 
     
     
         34 . The natural draft heater system of  claim 32 , wherein the flame scanner and the purge air injection input are absent on at least one burner assembly when the at least one burner assembly includes two or more burner assemblies. 
     
     
         35 . The natural draft heater system of  claim 23 , wherein the output signal is in the form of a current delivered to the one or more actuators from the controller, the current being in the range of about 2 mA to about 20 mA, the one or more actuators being arranged to adjust the position of at least one of the set of inner blades and the set of outer blades in response to the current received from the controller. 
     
     
         36 . The natural draft heater system of  claim 23 , wherein the set of inner blades and the set of outer blades in the split-range stack damper are configured to be fully open during startup of the natural draft heater to maximize the bridge wall draft value and the amount of excess air in the burner. 
     
     
         37 . A method of reducing at least one of NO x  and CO emissions in a natural draft heater, the method comprising:
 measuring a selected draft value related to the negative pressure of flue gas within the heater shell when operation of the natural draft heater occurs;   adjusting a split-range stack damper associated with the natural draft heater to maintain the selected draft value to within a preselected range;   measuring an excess air level in a burner when operation of the natural draft heater occurs;   controlling excess air in a burner associated with the natural draft heater to a value in the range of between about 15% to about 25% by weight based on the combined weight of air and fuel needed for complete combustion within the burner; and   controlling the draft within the heater shell within a preselected range thereby to control the amount of excess air in the burner and maintain at least one of NO x  emissions not exceeding 0.025 lb/MMBtu (HHV) and CO emissions not exceeding 0.01 lb/MMBtu (HHV) in the natural draft heater.   
     
     
         38 . The method of  claim 37 , wherein the preselected range of the selected draft value is maintained in the range of about 0.10-inches water-column to about 0.15-inches water-column to provide the desired negative pressure within the natural draft heater. 
     
     
         39 . The method of  claim 37 , wherein the split-range stack damper comprises a set of inner blades, a set of outer blades, and one or more actuators arranged to actuate the set of inner blades and the set of outer blades to thereby effectuate movement thereof to maintain the selected draft value to within the preselected range. 
     
     
         40 . The method of  claim 37 , further comprising detecting the presence of a flame in the burner when operation of the natural draft heater occurs. 
     
     
         41 . The method of  claim 40 , further comprising injecting a purge air directly into the burner, the purge air being used as combustion air by the burner to thereby reduce NO x  formation within the heater shell. 
     
     
         42 . The method of  claim 37 , further comprising sealing one or more connections proximate the burner to prevent air infiltration into the burner to thereby reduce NO x  formation in the heater shell. 
     
     
         43 . A method of reducing at least one of NO x  and CO emissions in a natural draft heater, the method comprising:
 providing a natural draft heater including:
 a heater shell designed to circulate a flue gas internally therein via negative pressure, the flue gas being generated by combustion of a fuel within the heater shell, the heater shell including a base, a burner section positioned proximate the base where combustion of the fuel occurs, a radiant section positioned adjacent the burner section to receive heat energy from the burner section and radiate heat energy therefrom, and a convective section positioned adjacent the radiant section to provide convection from the radiant section, 
 a bridge wall connected to the heater shell and positioned between the radiant section and the convective section, 
 one or more heating coils positioned within the heater shell proximate one or both of the radiant section and the convective section, the one or more heating coils containing a process fluid and being arranged to transfer heat from the circulated flue gas to thereby heat the process fluid; 
 a draft sensor positioned proximate the bridge wall to measure a bridge wall draft value related to the negative pressure of the flue gas within the heater shell; 
 a stack positioned proximate the convective section of the heater shell for venting of at least a portion of the circulated flue gas to atmosphere, the stack including an outer shell and a split-range stack damper positioned within the outer shell to maintain the bridge wall draft of the flue gas being vented from the natural draft heater, the split-range stack damper including a set of inner blades, a set of outer blades, and one or more actuators arranged to actuate the set of inner blades and the set of outer blades to thereby effectuate movement thereof; 
 at least one burner assembly connected proximate the base of the heater shell to combust the fuel when supplied thereto, thereby generating the flue gas that transfers heat to the process fluid contained within the one or more heating coils, the at least one burner assembly having:
 a burner positioned within the at least one burner assembly to ignite the fuel when being supplied to the burner, 
 a burner air sensor positioned adjacent the burner to measure a level of excess air, 
 an air plenum adjacent to the burner to distribute air into the burner, the air plenum including an air input to receive atmospheric air, 
 a burner air register in fluid communication with the air input to direct the atmospheric air into the air plenum, the burner air register having a housing, one or more plates attached to the housing and positioned in fluid communication with the air plenum to direct air flow into the plenum, and a handle attached to the housing to adjust the position of the one or more plates to effectuate a movement thereof, each of the one or more plates being configurable between one or more of an open position, a partially open position, and a closed position to selectively supply air to the air plenum, 
 a fuel supply system including a fuel input conduit, a primary manifold assembly, and a second, staged manifold assembly, the first input conduit positioned in fluid communication with the primary manifold assembly to deliver fuel to the primary manifold assembly, the primary manifold assembly positioned in fluid communication with one or both of a burner tip of the burner and the second, staged manifold assembly to deliver fuel to one or both of the burner tip of the burner and the second, staged manifold, the second, staged manifold assembly positioned in fluid communication with another burner tip to deliver fuel to the another burner tip, the second, staged manifold assembly including a staged manifold valve configurable to be in a closed position to shut off fuel flow or in an at least partially open position to direct a preselected amount of fuel to the another burner tip to achieve a desired concentration of air and fuel mixture in the another burner tip, and 
 
 a controller in electrical communication with the burner air register, the burner air sensor, the draft sensor, and the one or more actuators in the split-range stack damper; 
   measuring a bridge wall draft value related to the negative pressure of the flue gas within the heater shell via the draft sensor during operation of the natural draft heater;   communicating the measured bridge wall draft value to the controller and from the controller to the one or more actuators in the split-range stack damper for adjustment of the position of the set of inner blades and the set of outer blades of the split-range stack damper;   adjusting the position of at least one of the set of inner blades and the set of outer blades of the split-range stack damper to maintain the bridge wall draft value to within a preselected range;   measuring an excess air level in the burner via a burner air sensor during operation of the natural draft heater;   communicating the measured excess air level to the controller whereby the controller alerts an operator to adjust configuration of the one or more plates positioned therein;   adjusting the configuration of the one or more plates to control the excess air in the burner to a value in the range of between about 15% to about 25% by weight based on the combined weight of air and fuel needed for complete combustion;   controlling the bridge wall draft within the heater shell to deliver an amount of excess air to the burner to thereby maintain at least one of NO x  emissions not exceeding 0.025 lb/MMBtu (HHV) and CO emissions not exceeding 0.01 lb/MMBtu (HHV) in the natural draft heater.   
     
     
         44 . The method of  claim 43 , wherein the preselected range of the bridge wall draft value is maintained in the range of about 0.10-inches water-column to about 0.15-inches water-column to provide the desired negative pressure within the natural draft heater. 
     
     
         45 . The method of  claim 43 , further comprising detecting the presence of a flame in the burner when operation of the natural draft heater occurs. 
     
     
         46 . The method of  claim 45 , further comprising injecting a purge air directly into the burner, the purge air being used as combustion air to thereby reduce NO x  formation within the heater shell. 
     
     
         47 . The method of  claim 46 , further comprising detecting the presence of a flame in the burner to thereby inject a purge air into the burner on alternating burner assemblies when the at least one burner assembly includes two or more burner assemblies. 
     
     
         48 . The method of  claim 43 , further comprising sealing one or more connections within the at least one burner assembly to prevent air infiltration into the burner to thereby reduce NO x  formation in the heater shell.

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