Pesticidally Active Heterocyclic Derivatives With Sulphur Containing Substituents

Abstract

Compounds of formula (I) wherein the substituents are as defined in claim 1, and the agrochemically acceptable salts, stereoisomers, enantiomers, tautomers and N-oxides of those compounds, can be used as insecticides and can be prepared in a manner known per se.

1 . A compound of formula I, 
       
         
           
           
               
               
           
         
       
       wherein
 A 1  is CH or N; 
 G 1  is CH and G 2  is CH; 
 X is S, SO or SO 2 ; 
 R 1  is C 1 -C 4 alkyl or C 3 -C 6 cycloalkyl-C 1 -C 4 alkyl; 
 R 2  is halogen, C 1 -C 4 haloalkylsulfanyl, C 1 -C 4 haloalkylsulfinyl, C 1 -C 4 haloalkylsulfonyl or C 1 -C 6 haloalkyl; 
 R 3  is hydrogen, halogen, cyano, C 1 -C 4 haloalkyl or C 1 -C 4 alkyl; and 
 Q is phenyl which can be mono- or polysubstituted by substituents selected from the group consisting of halogen, cyano, C 1 -C 4 alkyl, C 1 -C 4 haloalkyl, C 1 -C 4 haloalkoxy, C 1 -C 4 alkoxy, C 1 -C 4 alkylsulfanyl, C 1 -C 4 alkylsulfonyl, C 1 -C 4 haloalkylsulfanyl, C 1 -C 4 haloalkylsuffinyl and C 1 -C 4 haloalkylsulfonyl; or 
 Q is pyrimidinyl which can be mono- or polysubstituted by substituents selected from the group consisting halogen, cyano, C 1 -C 4 haloalkyl, C 1 -C 4 haloalkoxy, C 1 -C 4 alkoxy, C 1 -C 4 alkylsulfanyl, C 4 alkylsulfinyl, C 1 -C 4 alkylsulfonyl, C 1 -C 4 haloalkylsulfanyl, C 1 -C 4 haloalkylsulfinyl and C 1 -C 4 haloalkylsulfonyl; or 
 Q is pyridinyl which can be mono- or polysubstituted by substituents selected from the group consisting of halogen, cyano, C 1 -C 4 alkyl, C 1 -C 4 haloalkyl, C 1 -C 4 haloalkoxy, C 1 -C 4 -alkoxy, C 1 -C 4 alkylsulfanyl, C 1 -C 4 alkylsulfinyl, C 1 -C 4 alkylsulfonyl, C 1 -C 4 haloalkylsulfanyl, C 1 -C 4 haloalkylsulfinyl and C 1 -C 4 haloalkylsulfonyl; or 
 agrochemically acceptable salts, stereoisomers, enantiomers, tautomers and N-oxides of the compounds of formula I. 
 
     
     
         2 . The compound of  claim 1  represented by the compounds of formula I-3 
       
         
           
           
               
               
           
         
         wherein A 1 , Q, X, R 1 , R 2  and R 3  are as defined under formula I in  claim 1 . 
       
     
     
         3 . The compound of  claim 1  represented by the compounds of formula I-4 
       
         
           
           
               
               
           
         
         wherein A 1 , Q, X, R 1,  R 2  and R 3  are as defined under formula I in  claim 1 . 
       
     
     
         4 . The compound of  claim 1 , wherein A 1  is N. 
     
     
         5 . The compound of  claim 4 , wherein R 1  is C 1 -C 4 alkyl. 
     
     
         6 . The compound of  claim 5 , wherein X is SO 2 . 
     
     
         7 . The compound of  claim 6 , wherein R 2  is halogen or C 1 -C 6 haloalkyl. 
     
     
         8 . The compound of  claim 7 , wherein Q is mono-or polysubstituted phenyl. 
     
     
         9 . The compound of  claim 7 , wherein Q is mono-or polysubstituted pyrimindyl. 
     
     
         10 . The compound of  claim 7 , wherein Q is mono-or polysubstituted pyridinyl. 
     
     
         11 . The compound of  claim 1 , wherein the compound is 
       
         
           
           
               
               
           
         
       
     
     
         12 . The compound of  claim 1 , wherein the compound is 
       
         
           
           
               
               
           
         
       
     
     
         13 . A composition, comprising:
 at least one compound of formula I according to  claim 1  or, where appropriate, a tautomer thereof, in each case in free form or in agrochemically utilizable salt form, as active ingredient; and   at least one auxiliary.   
     
     
         14 . A method for controlling arthropods, comprising applying a composition according to  claim 13  to the arthropods or their environment with the exception of a method for treatment of the human or animal body by surgery or therapy and diagnostic methods practiced on the human or animal body. 
     
     
         15 . A method for protecting plant propagation material from attack by insects or Acarina, comprising treating the propagation material or a site, where the propagation material is planted, with a composition according to  claim 13 . 
     
     
         16 . A plant propagation material treated with the composition of  claim 13 .