US2019316237A1PendingUtilityA1

Ferritic stainless steel having excellent ridging property and excellent surface quality and method of manufacturing the same

Assignee: POSCOPriority: Dec 13, 2016Filed: Jul 4, 2017Published: Oct 17, 2019
Est. expiryDec 13, 2036(~10.4 yrs left)· nominal 20-yr term from priority
C21D 8/04C22C 38/001C22C 38/40C22C 38/18C22C 38/004C21D 8/0263C21D 9/46C21D 9/0081C21D 8/0426C22C 38/06C21D 8/0273C22C 38/02C21D 8/0226C21D 2211/005C21D 6/002C21D 8/0436C21D 8/0236C21D 9/48C21D 8/0473C21D 8/0268C22C 38/04C22C 38/00
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Claims

Abstract

A ferritic stainless steel according to the present disclosure includes, by wt %, 0.005 to 0.1% of carbon (C), 0.01 to 2.0% of silicon (Si), 0.01 to 1.5% of manganese (Mn), 0.05% or less of phosphorus (P), 0.005% or less of sulfur (S), 10 to 30% of chromium (Cr), 0.005 to 0.1% of nitrogen (N), 0.005 to 0.2% of aluminum (Al), and the remainder of iron (Fe) and other impurities, wherein a γmax value is in the range of 20% to less than 50%, and a surface microgroove area ratio is 2.0% or less.

Claims

exact text as granted — not AI-modified
1 . A ferritic stainless steel having excellent ridging properties and excellent surface quality comprising, by wt %, 0.005 to 0.1% of carbon (C), 0.01 to 2.0% of silicon (Si), 0.01 to 1.5% of manganese (Mn), 0.05% or less of phosphorus (P), 0.005% or less of sulfur (S), 10 to 30% of chromium (Cr), 0.005 to 0.1% of nitrogen (N), 0.005 to 0.2% of aluminum (Al), and the remainder of iron (Fe) and other impurities,
 wherein a γ max  value represented by Formula 1 below is in the range of 20% to less than 50%,
   420×C+470×N+10×Mn+180−11.5×Cr−11.5×Si−52.0×Al  (1)
 
   wherein C, N, Mn, Cr, Si, and Al refer to amounts of respective elements (wt %).   
     
     
         2 . The ferritic stainless steel according to  claim 1 , wherein the stainless steel has a surface microgroove area ratio of 2.0% or less. 
     
     
         3 . The ferritic stainless steel according to  claim 1 , wherein the stainless steel has a ridging height of 12 μm or less. 
     
     
         4 . The ferritic stainless steel according to  claim 1 , wherein the stainless steel has an r-bar value of 1.2 or greater. 
     
     
         5 . A method of manufacturing a ferritic stainless steel having excellent ridging properties and excellent surface quality, the method comprising:
 preparing a slab comprising, by wt %, 0.005 to 0.1% of carbon (C), 0.01 to 2.0% of silicon (Si), 0.01 to 1.5% of manganese (Mn), 0.05% or less of phosphorus (P), 0.005% or less of sulfur (S), 10 to 30% of chromium (Cr), 0.005 to 0.1% of nitrogen (N), 0.005 to 0.2% of aluminum (Al), and the remainder of iron (Fe) and other impurities and having a γ max  value represented by Formula 1 below and satisfying 20% to less than 50%;   hot rolling the slab by reheating;   coiling the hot rolled steel sheet; and   cold rolling the coiled hot rolled steel sheet before conducting hot annealing:
   420×C+470×N+10×Mn+180−11.5×Cr−11.5×Si−52.0×Al  (1)
 
   wherein C, N, Mn, Cr, Si, and Al refer to amounts of respective elements (wt %).   
     
     
         6 . The method according to  claim 5 , wherein a coiling temperature is 750° C. or higher in the coiling of the hot rolled steel sheet. 
     
     
         7 . The method according to  claim 5 , wherein the cold rolling is performed by asymmetric cold rolling. 
     
     
         8 . The method according to  claim 5 , wherein the cold rolling or the asymmetric cold rolling is performed with a reduction ratio of 30% or more. 
     
     
         9 . The method according to  claim 7 , wherein the asymmetric cold rolling is performed under rolling conditions of a speed ratio between upper and lower rolling rolls (V h /V l ) of 1.25 or greater and a rolling shape factor (l/d) of 1.7 or greater.
 wherein   V h : speed of fast roll,   V l : speed of slow roll,   rolling shape factor: l/d=2√{square root over (r(h 0 −h))}/(h 0 +h),   l: length to which contact arc between roll and steel sheet in rolling roll bite is projected,   d: average thickness of the steel sheet, d=(h 0 +h)/2,   r: radius of rolling roll,   h 0 : initial thickness of steel sheet, and   h: final thickness of steel sheet.   
     
     
         10 . The method according to  claim 9 , wherein a height of a stainless steel prepared by performing hot annealing, secondary cold rolling, and cold annealing after the asymmetric cold rolling is 10 μm or less. 
     
     
         11 . The method according to  claim 5 , further comprising hot annealing after the cold rolling. 
     
     
         12 . The method according to  claim 11 , wherein the hot annealing is performed in a temperature range of 550 to 950° C. for 60 minutes or less. 
     
     
         13 . The method according to  claim 11 , wherein an average aspect ratio of a structure of a thickness center of a cross-section of the hot annealed steel sheet is 4.0 or less after the hot annealing.

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