US2019275181A1PendingUtilityA1

Compounds for Positron Emission Tomography

Assignee: ENDOCYTE INCPriority: Nov 14, 2013Filed: Oct 10, 2018Published: Sep 12, 2019
Est. expiryNov 14, 2033(~7.3 yrs left)· nominal 20-yr term from priority
A61P 35/00A61P 13/08A61K 51/0459A61K 51/0497A61K 51/04A61K 51/0482G01N 33/52G01N 2800/00G01N 33/60
60
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Claims

Abstract

Described herein are compounds, compositions, and methods for diagnosing and/or monitoring pathogenic disease using positron emission tomography. Also described are conjugates of the formula B-L-P, wherein B is a radical of a targeting agent selected from vitamin receptor binding ligands (such as folate), PSMA binding ligands, or PSMA inhibitors; L is a divalent linker comprising aspartic acid, lysine, or arginine, and P is a radical of an imaging agent or radiotherapy agent, such as a radionuclide or radionuclide containing group, or a radical of a compound capable of binding a radionuclide, such as a metal chelating group.

Claims

exact text as granted — not AI-modified
1 . A conjugate of the formula
   B-L-P   
       or a pharmaceutically acceptable salt thereof, wherein B is a radical of a targeting agent selected from vitamin receptor binding ligands, PSMA binding ligands, and PSMA inhibitors, L is a divalent linker, and P is a radical comprising a formula chosen from the group consisting of: 
       
         
           
           
               
               
           
         
       
     
     
         2 . The conjugate of  claim 1  comprising folate-Asp. 
     
     
         3 . The conjugate of  claim 1  comprising folate-Arg. 
     
     
         4 . The conjugate of  claim 1 , wherein the divalent linker L comprises a polypeptide comprising phenylalanine, lysine, arginine, or aspartic acid, or a combination thereof. 
     
     
         5 . The conjugate of  claim 1  wherein the divalent linker L does not include a diradical of the formula *NH—(CH 2 ) 2 —NH*. 
     
     
         6 . The conjugate of  claim 1 , wherein P comprises: 
       
         
           
           
               
               
           
         
         or a derivative thereof comprising a chelated metal. 
       
     
     
         7 . The conjugate of  claim 1  comprising folate-PEG. 
     
     
         8 . The conjugate of  claim 1 , wherein P comprises: 
       
         
           
           
               
               
           
         
         or a derivative thereof comprising a chelated metal. 
       
     
     
         9 . The conjugate of  claim 1 , wherein P comprises: 
       
         
           
           
               
               
           
         
         or a derivative thereof comprising a chelated metal. 
       
     
     
         10 . The conjugate of  claim 1  wherein the targeting agent is a radical of a PSMA binding ligand or PSMA inhibitor. 
     
     
         11 . The conjugate of  claim 10  comprising the formula 
       
         
           
           
               
               
           
         
         where n is an integer selected from 1, 2, 3, 4, 5, 6, 7, 8, 9, or 10; or 
       
       
         
           
           
               
               
           
         
         where n is an integer selected from 1, 2, 3, 4, 5, 6, 7, 8, 9, or 10; or 
       
       
         
           
           
               
               
           
         
         where W is O or S. 
       
     
     
         12 . The conjugate of  claim 10  wherein the linker comprises a polypeptide comprising phenylalanine, lysine, arginine, or aspartic acid, or a combination thereof. 
     
     
         13 . The conjugate of  claim 1 , wherein P comprises: 
       
         
           
           
               
               
           
         
         or a derivative thereof comprising a chelated metal. 
       
     
     
         14 . The conjugate of  claim 10  comprising the formula 
       
         
           
           
               
               
           
         
         where n is an integer selected from 1, 2, 3, 4, 5, 6, 7, 8, 9, or 10. 
       
     
     
         15 . The conjugate of  claim 10  wherein the divalent linker L comprises the formula 
       
         
           
           
               
               
           
         
       
     
     
         16 . The conjugate of  claim 10  wherein the divalent linker L comprises the formula 
       
         
           
           
               
               
           
         
       
     
     
         17 . The conjugate of  claim 1 , wherein P comprises: 
       
         
           
           
               
               
           
         
         or a derivative thereof comprising a chelated metal. 
       
     
     
         18 . The conjugate of  claim 1 , further comprising a positron-emitting radionuclide or radionuclide containing group. 
     
     
         19 . The conjugate of  claim 18  wherein the radionuclide is a radiotherapy agent. 
     
     
         20 . The conjugate of  claim 18 , wherein the positron-emitting radionuclide or radionuclide containing group is selected from the group consisting of  89 Zr,  45 Ti,  51 Mn,  64 Cu,  61 Cu,  63 Zn,  82 Rb,  68 Ga,  66 Ga,  11 C,  13 N,  15 O,  124 I,  34 Cl,  18 F, and  19 F.

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