Method of forming high thermal conductivity composite dielectric materials

Abstract

Disclosed herein are embodiments of materials having high thermal conductivity along with a high dielectric constants. In some embodiments, a two phase composite ceramic material can be formed having a contiguous aluminum oxide phase with a secondary phase embedded within the continuous phase. Example secondary phases include calcium titanate, strontium titanate, or titanium dioxide.

1 . A method of forming a composite ceramic material, the method comprising:
 mixing together materials that will form out a primary phase of aluminum oxide, a first secondary phase of CaTiO 3  located within the primary phase, and a second secondary phase of LaAlO 3  located within the primary phase, the materials forming the primary phase being generally non-reactive with materials forming the first and second secondary phases; and   sintering the materials to form a composite ceramic having the primary phase and the first and second secondary phases, the composite ceramic having a dielectric constant of greater than 20 and a thermal conductivity of greater than 20 W·m −1 ·K −1 .   
     
     
         2 . (canceled) 
     
     
         3 . The method of  claim 1  wherein the composite ceramic has a thermal conductivity of greater than 30 W·m −1 ·K −1 . 
     
     
         4 . (canceled) 
     
     
         5 . The method of  claim 1  wherein the primary phase is generally contiguous. 
     
     
         6 . The method of  claim 1  wherein the composite ceramic has a dielectric constant of greater than 25. 
     
     
         7 . The method of  claim 1  wherein the composite ceramic has a dielectric constant of greater than 35. 
     
     
         8 . The method of  claim 1  wherein the composite ceramic has a temperature drift of resonant frequency lower than 1000 ppm/Degree C. 
     
     
         9 . The method of  claim 1  further comprising machining the composite ceramic. 
     
     
         10 . The method of  claim 9  further comprising forming a radiofrequency component from the composite ceramic. 
     
     
         11 . A method of forming a composite ceramic material, the method comprising:
 mixing together materials that will form out a primary phase of aluminum oxide, a first secondary phase of CaTiO 3  located within the primary phase, and a second secondary phase of La 2 MgTiO 6  located within the primary phase, the materials forming the primary phase being generally non-reactive with materials forming the first and second secondary phases; and   sintering the materials to form a composite ceramic having the primary phase and the first and second secondary phases, the composite ceramic having a dielectric constant of greater than 20 and a thermal conductivity of greater than 20 W·m −1 ·K −1 .   
     
     
         12 . The method of  claim 11  wherein the composite ceramic has a thermal conductivity of greater than 30 W·m −1 ·K −1 . 
     
     
         13 . The method of  claim 11  wherein the primary phase is generally contiguous. 
     
     
         14 . The method of  claim 11  wherein the composite ceramic has a dielectric constant of greater than 25. 
     
     
         15 . The method of  claim 11  wherein the composite ceramic has a dielectric constant of greater than 35. 
     
     
         16 . The method of  claim 11  wherein the composite ceramic has a temperature drift of resonant frequency lower than 1000 ppm/Degree C. 
     
     
         17 . A method of forming a composite ceramic material, the method comprising:
 mixing together materials that will form out a primary phase of aluminum oxide, and a plurality of secondary phases, a first of the plurality of secondary phases being CaTiO 3  and a second of the plurality of secondary phases being selected from the group consisting of LaAlO 3 , La 2 MgTiO 6 , YALO 3 , SmAlO 3 , Mg 4 Nb 2 O 9 , and La 4 Ti 3 O 12 ; and   sintering the materials to form a composite ceramic having the primary phase and the plurality of secondary phases, the composite ceramic having a dielectric constant of greater than 20.   
     
     
         18 . The method of  claim 17  wherein the composite ceramic has a thermal conductivity of greater than 20 W·m −1 ·K −1 . 
     
     
         19 . The method of  claim 17  wherein the composite ceramic has a thermal conductivity of greater than 30 W·m −1 ·K −1 . 
     
     
         20 . The method of  claim 17  wherein the composite ceramic has a dielectric constant of greater than 25. 
     
     
         21 . The method of  claim 17  wherein the composite ceramic has a dielectric constant of greater than 35. 
     
     
         22 . The method of  claim 17  wherein the composite ceramic has a temperature drift of resonant frequency lower than 1000 ppm/Degree C.