Wood adhesives for producing particle boards

Abstract

A composition based on phenolic resin comprising at least one phenolic resin, a vegetable protein hydrolysate, preferentially a wheat gluten hydrolysate, and an agent for accelerating curing, and also to the process for the production thereof.

1 . A composition based on phenolic resin, characterized in that it comprises at least one phenolic resin, a vegetable protein hydrolysate, and an agent for accelerating curing. 
     
     
         2 . The composition of  claim 1 , wherein the vegetable protein hydrolysate is a wheat gluten hydrolysate. 
     
     
         3 . The composition of  claim 2 , wherein the agent for accelerating curing is selected from triacetin, butyrolactone, caprolactone and propylene carbonate. 
     
     
         4 . The composition as claimed in  claim 1 , characterized in that the phenol and the wheat gluten hydrolysate are mixed in a phenol:wheat gluten hydrolysate ratio of 3.2:1 to 7.2:1 by weight. 
     
     
         5 . The composition as claimed in  claim 1 , characterized in that the content of the agent for accelerating curing is between 4% and 10% by weight of the resin solids. 
     
     
         6 . The composition as claimed in  claim 5 , characterized in that the content of the agent for accelerating curing is between 6% and 8% by weight of the resin solids. 
     
     
         7 . The composition as claimed in  claim 1 , characterized in that the wheat gluten hydrolysate is obtained by acid or enzymatic hydrolysis. 
     
     
         8 . The composition as claimed in  claim 1 , characterized in that the wheat gluten hydrolysate is obtained by enzymatic hydrolysis and has an average molecular weight of between 3 and 20 kDa. 
     
     
         9 . The composition as claimed in  claim 8 , characterized in that the wheat gluten hydrolysate is obtained by enzymatic hydrolysis and has an average molecular weight of between 4 and 15 kDa. 
     
     
         10 . The composition as claimed in  claim 1 , characterized in that the wheat gluten hydrolysate is also deamidated. 
     
     
         11 . A rigid phenolic foam board comprising a composition as claimed in  claim 1 . 
     
     
         12 . A particle or fiber board comprising a composition as claimed in  claim 1 . 
     
     
         13 . The composition of  claim 1 , wherein the phenolic resin is a product of resinous reaction of a phenol with an aldehyde and wherein the phenol:aldehyde mole ratio is from 1:1.5 to 1:1.7. 
     
     
         14 . The composition of  claim 13 , wherein the agent for accelerating curing is selected from triacetin, butyrolactone, caprolactone and propylene carbonate. 
     
     
         15 . The composition as claimed in  claim 13 , characterized in that the phenol and the vegetable protein hydrolysate are mixed in a phenol:wheat gluten hydrolysate ratio of 3.2:1 to 7.2:1 by weight. 
     
     
         16 . The composition as claimed in  claim 13 , characterized in that the content of the agent for accelerating curing is between 6% and 8% by weight of the resin solids. 
     
     
         17 . The composition as claimed in  claim 13 , characterized in that the vegetable protein hydrolysate is obtained by enzymatic hydrolysis and has an average molecular weight of between 4 and 15 kDa. 
     
     
         18 . A rigid phenolic foam board comprising a composition as claimed in  claim 13 . 
     
     
         19 . A particle or fiber board comprising a composition as claimed in  claim 13 . 
     
     
         20 . A process for the formation of a composition based on phenolic resin, said phenolic resin being a product of resinous reaction of a phenol with an aldehyde, characterized in that the process comprises the following steps:
 mixing phenol and a wheat gluten hydrolysate, in the presence of a base solution and of a molar excess of 10% of formaldehyde in a mixer;   heating the mixture obtained to a temperature of between 90 and 98° C. and maintaining it at this temperature for approximately 15 minutes up to one hour;   adding an additional amount of formaldehyde so as to achieve a phenol:formaldehyde ratio of 1:1.5 to 1:1.7;   continuing the reaction until a resin with a viscosity of between 0.5 and 0.8 Pa·s at 25° C. is obtained;   mixing the resin obtained with an agent for accelerating curing.