Semiconducting particles in electronic elements

Abstract

The present invention relates inter alia to a color display comprising nanoparticles and color filters.

1 - 24 . (canceled) 
     
     
         25 . Electronic element comprising
 a) a pixelated organic electroluminescent device  100  comprising a first  101 , a second  102 , and a third  103  light emitting pixel that are identical, but that are electronically controlled separately;   b) a first color converter layer  201  disposed in the light output path  151  of the first pixel  101  via a printing method, wherein the color converter layer  201  comprises at least one light emitting semiconducting nanoparticle acting as first color converter;   c) a first color filter layer  301  disposed in the light output path  251  of the first color converter layer  201  comprising a first color filter.   
     
     
         26 . An electronic element comprising
 a) a pixelated organic electroluminescent device  100  comprising a first  101 , a second  102 , and a third  103  light emitting pixel that are identical, and are electronically controlled separately,   b) a first color converter layer  201  disposed in the light output path  151  of the first pixel  101  via a printing method, wherein the color converter layer  201  comprises at least one light emitting semiconducting nanoparticle acting as first color converter;   c) a first color filter layer  301  disposed in the light output path  251  of the first color converter layer  201  comprising a first color filter,
 and wherein the electronic element comprises scattering particles. 
   
     
     
         27 . The electronic element according to  claim 25 , wherein the first color filter layer  301  comprises a red color filter as first color filter and the first color converter layer  201  comprises a red light emitting semiconducting nanoparticle as first color converter. 
     
     
         28 . The electronic element according to  claim 25 , wherein a second color filter layer  302  comprising a second color filter is disposed in the light output path of the second pixel  102 . 
     
     
         29 . The electronic element according to  claim 25 , wherein a third color filter layer  303  comprising a third color filter is disposed in the light output path of the third pixel  103 . 
     
     
         30 . The electronic element according to  claim 25 , wherein the first color filter and the first color converter are located in the same layer as first combined layer  501 . 
     
     
         31 . The electronic element according to  claim 25 , wherein the element further comprises a fourth pixel  104 . 
     
     
         32 . The electronic element according to  claim 25 , wherein the pixelated organic electroluminescent device emits white light. 
     
     
         33 . The electronic element according to  claim 25 , wherein the device comprises in the light output path  152  of the second pixel  102  between the second pixel  102  and the second color filter layer  302  a second color converter layer  202  comprising a second color converter. 
     
     
         34 . The electronic element according to  claim 33 , wherein the first color converter layer  201  and the second color converter layer  202  are represented by a single common color converter layer  212  being disposed in the light output paths of the first  101  and the second  102  pixel, wherein the common color converter layer  212  comprises a composition of the first color converter and the second color converter. 
     
     
         35 . The electronic element according to  claim 25 , wherein the organic electroluminescent device emits blue light. 
     
     
         36 . The electronic element according to  claim 25 , wherein the device comprises a common color filter layer  523  in the light output paths of the second  152  and a third  153  pixel, wherein the common color filter layer comprises a composition of the second and third color filter. 
     
     
         37 . The electronic element according to  claim 25 , wherein the organic electroluminescent device emits bluish-green light. 
     
     
         38 . The electronic element according to  claim 25 , wherein the concentration of the light emitting semiconducting nanoparticle in the first, second or third color converter layer is 10 mg/m 2  to 1 g/m 2 . 
     
     
         39 . The electronic element according to  claim 25 , wherein the light emitting semiconducting nanoparticle(s) is(are) selected from the group consisting of quantum dots, core shell type quantum dots, quantum rods, core shell type quantum rods and combinations thereof. 
     
     
         40 . The electronic element according to  claim 25 , wherein the light emitting semiconducting nanoparticle(s) is(are) selected from the group consisting of InGaP, CdSe, CdS, CdTe, ZnO, ZnSe, ZnS, ZnTe, HgSe, HgTe, CdZnSe, InP, InN, GaN, InSb, InAsP, InGaAs, GaAs, GaP, GaSb, AlP, AlN, AlAs, AlSb, CdSeTe, ZnCdSe, PbSe, PbTe, PbS, PbSnTe, and Tl 2 SnTe 5  and combinations thereof. 
     
     
         41 . The electronic element according to  claim 25 , wherein the color filters are selected from dyes and pigments. 
     
     
         42 . The electronic element according to  claim 25 , wherein the device further comprises a planarization layer  150  between the pixelated organic electroluminescent device  100  and the color converter layer(s) or if no color converter layer is present between the pixelated organic electroluminescent device  100  and the color filter layer(s). 
     
     
         43 . A color display comprising the electronic element according to  claim 25 . 
     
     
         44 . The color display according to  claim 43 , which comprises a TFT backplane  600 . 
     
     
         45 . A method for preparing the electronic element according to  claim 25 , wherein the color converter layer comprising the quantum rod, core shell type quantum rod or combination thereof is, at least in part, oriented. 
     
     
         46 . An electronic element obtainable according to the method of  claim 45 . 
     
     
         47 . The electronic element according to  claim 26 , wherein the average particle diameter of the scattering particles is 350 nm to 5 μm. 
     
     
         48 . The electronic element according to  claim 26 , wherein the scattering particles are SiO 2 , SnO 2 , CuO, CoO, Al 2 O 3  TiO 2 , Fe 2 O 3 , Y 2 O 3 , ZnO, or MgO particles, or organic particles of polymerized polystyrene or polymerized PMMA, or hollow silica particles or BaSO 4  particles or a combination thereof. 
     
     
         49 . The electronic element according to  claim 25 , wherein the printing method is screen printing, off-set printing or ink-jet printing. 
     
     
         50 . A process for preparing the electronic element comprising
 a) a pixelated organic electroluminescent device  100  comprising a first  101 , a second  102 , and a third  103  light emitting pixel that are identical, but that are electronically controlled separately;   b) a first color converter layer  201  disposed in the light output path  151  of the first pixel  101 , wherein the color converter layer  201  comprises at least one light emitting semiconducting nanoparticle acting as first color converter;   c) a first color filter layer  301  disposed in the light output path  251  of the first color converter layer  201  comprising a first color filter,
 said process comprising printing the first color converter layer  201  disposed in the light output path, wherein the color converter layer  201  comprises at least one light emitting semiconducting nanoparticle acting as first color converter of the first pixel  101 , wherein the color converter layer  201  comprises at least one light emitting semiconducting nanoparticle acting as first color converter. 
   
     
     
         51 . The process according to  claim 50 , wherein the printing is screen printing, off-set printing or ink-jet printing. 
     
     
         52 . A process for preparing the electronic element according to  claim 26 , comprising printing the first color converter layer  201  disposed in the light output path, wherein the color converter layer  201  comprises at least one light emitting semiconducting nanoparticle acting as first color converter of the first pixel  101 , wherein the color converter layer  201  comprises at least one light emitting semiconducting nanoparticle acting as first color converter. 
     
     
         53 . The electronic element according to  claim 25 , wherein the color converter is embedded in a matrix material in the color converter layer, which matrix material is a transparent matrix material, and which is selected from the group consisting of polymers, photo-curable polymers and photo-sensitive polymers. 
     
     
         54 . The electronic element according to  claim 53 , wherein matrix material is selected from the group consisting of acrylate resins which are useful in an LCD color filter, photo-curable polysiloxanes, polyvinylcinnamates which are useful as a photo-curable polymer or a combination thereof.