Bottle closure assembly including a polyethylene composition

Abstract

The present disclosure describes bottle closure assemblies which are made at least in part with a high density unimodal polyethylene. The bottle closure assembly includes a cap portion, an elongated tether portion and a retaining means portion. The retaining means portions engages a bottle neck or an upper portion of a bottle. The elongated tether portion connects at least one point on the cap portion to at least one point on the retaining means portion so as to prevent loss of the cap portion from a bottle.

We claim: 
     
         1 . A bottle closure assembly comprising:
 a cap portion, a tether portion, and a retaining means portion, the cap portion being molded to reversibly engage and cover a bottle opening, the retaining means portion being molded to irreversibly engage a bottle neck or an upper portion of a bottle, and where the tether portion connects at least one point on the cap portion to at least one point on the retaining means portion, wherein the cap portion, optionally the tether portion, and optionally the retaining means portion comprise a high density polyethylene which is not a polymer blend and has a density of from 0.940 to 0.965 g/cm 3 , a melt index, I 2  of less than 35 g/10 min, a molecular weight distribution, M W /M n  of less than 5.0, and a unimodal profile in a GPC chromatograph.   
     
     
         2 . A bottle closure assembly comprising:
 a cap portion, an elongated tether portion, and a retaining means portion, the cap portion being molded to reversibly engage and cover a bottle opening, the retaining means portion being molded to irreversibly engage a bottle neck or an upper portion of a bottle, and the elongated tether portion being molded to connect at least one point on the cap portion to at least one point on the retaining means portion, wherein the cap portion, optionally the elongated tether portion, and optionally the retaining means portion are made from a high density polyethylene which is not a polymer blend and has a density of from 0.940 to 0.965 g/cm 3 , a melt index, I 2  of less than 35 g/10 min, a molecular weight distribution, M W /M n  of less than 5.0, and a unimodal profile in a GPC chromatograph.   
     
     
         3 . A bottle closure assembly comprising:
 an integrally molded: cap portion, tether portion, and retaining means portion; the cap portion being molded to reversibly engage and cover a bottle opening, the retaining means portion being molded to irreversibly engage a bottle neck or an upper portion of a bottle, and the tether portion being molded to connect at least one point on the cap portion to at least one point on the retaining means portion; wherein the integrally molded: cap portion, tether portion and retaining means portion are made from a high density polyethylene which is not a polymer blend and has a density of from 0.940 to 0.965 g/cm 3 , a melt index, I 2  of less than 35 g/10 min, a molecular weight distribution, M W /M n  of less than 5.0, and a unimodal profile in a GPC chromatograph.   
     
     
         4 . A bottle closure assembly comprising:
 an integrally molded: cap portion, elongated tether portion, and retaining means portion; the cap portion being molded to reversibly engage and cover a bottle opening, the retaining means portion being molded to irreversibly engage a bottle neck or an upper portion of a bottle, and the elongated tether portion being molded to connect at least one point on the cap portion to at least one point on the retaining means portion; wherein the integrally molded: cap portion, elongated tether portion and retaining means portion are made from a high density polyethylene which is not a polymer blend and has a density of from 0.940 to 0.965 g/cm 3 , a melt index, I 2  of less than 35 g/10 min, a molecular weight distribution, M W /M n  of less than 5.0, and a unimodal profile in a GPC chromatograph.   
     
     
         5 . A bottle closure assembly comprising:
 an integrally molded: cap portion, elongated tether portion, and retaining collar portion; the cap portion being molded to reversibly engage and cover a bottle opening, the retaining collar portion being molded to irreversibly engage a bottle neck or an upper portion of a bottle, and the elongated tether portion being molded to connect at least one point on the cap portion to at least one point on the retaining collar portion; wherein the integrally molded: cap portion, elongated tether portion and retaining collar portion are made from a high density polyethylene which is not a polymer blend and has a density of from 0.940 to 0.965 g/cm 3 , a melt index, I 2  of less than 35 g/10 min, a molecular weight distribution, M W /M n  of less than 5.0, and a unimodal profile in a GPC chromatograph.   
     
     
         6 . A bottle closure assembly comprising:
 a closure portion,   an elongated tether portion,   and a retaining collar portion,
 the closure portion being molded to reversibly engage and cover a bottle opening, the elongated tether portion comprising a tether strip which is frangibly connected along a portion of its upper edge to a descending annular edge of the closure portion and which is frangibly connected along a portion of its lower edge to an upper annular edge of the retaining collar portion, the tether strip being integrally formed with and connected at one end to at least one point on the closure portion and integrally formed with and connected at another end to at least one point on the retaining collar portion, the frangible sections being breakable when the closure portion is removed from a bottle opening, but where the closure portion remains connected to the retaining collar via the tether strip; wherein the cap portion, the elongated tether portion and the retaining collar portion are integrally molded from a high density polyethylene which is not a polymer blend and has a density of from 0.940 to 0.965 g/cm 3 , a melt index, I 2  of less than 35 g/10 min, a molecular weight distribution, M W /M n  of less than 5.0, and a unimodal profile in a GPC chromatograph. 
   
     
     
         7 . The bottle closure assembly of  claim 1  wherein the high density polyethylene which is not a polymer blend has a melt index, I 2  of less than 15 g/10 min. 
     
     
         8 . The bottle closure assembly of  claim 2  wherein the high density polyethylene which is not a polymer blend has a melt index, I 2  of less than 15 g/10 min. 
     
     
         9 . The bottle closure assembly of  claim 3  wherein the high density polyethylene which is not a polymer blend has a melt index, I 2  of less than 15 g/10 min. 
     
     
         10 . The bottle closure assembly of  claim 4  wherein the high density polyethylene which is not a polymer blend has a melt index, I 2  of less than 15 g/10 min. 
     
     
         11 . The bottle closure assembly of  claim 5  wherein the high density polyethylene which is not a polymer blend has a melt index, I 2  of less than 15 g/10 min. 
     
     
         12 . The bottle closure assembly of  claim 6  wherein the high density polyethylene which is not a polymer blend has a melt index, I 2  of less than 15 g/10 min. 
     
     
         13 . The bottle closure assembly of  claim 1  wherein the high density polyethylene which is not a polymer blend has a molecular weight distribution, M W /M n  from about 2.0 to about 4.5. 
     
     
         14 . The bottle closure assembly of  claim 2  wherein the high density polyethylene which is not a polymer blend has a molecular weight distribution, M W /M n  from about 2.0 to about 4.5. 
     
     
         15 . The bottle closure assembly of  claim 3  wherein the high density polyethylene which is not a polymer blend has a molecular weight distribution, M W /M n  from about 2.0 to about 4.5. 
     
     
         16 . The bottle closure assembly of  claim 4  wherein the high density polyethylene which is not a polymer blend has a molecular weight distribution, M W /M n  from about 2.0 to about 4.5. 
     
     
         17 . The bottle closure assembly of  claim 5  wherein the high density polyethylene which is not a polymer blend has a molecular weight distribution, M W /M n  from about 2.0 to about 4.5. 
     
     
         18 . The bottle closure assembly of  claim 6  wherein the high density polyethylene which is not a polymer blend has a molecular weight distribution, M W /M n  from about 2.0 to about 4.5.