Multilayer biodegradable film

Abstract

This invention relates to a multilayer biodegradable film which is particularly suitable for the manufacture of packaging and is also characterised by appreciable optical transparency properties in addition to high level mechanical properties.

1 . A multilayer film comprising at least one first layer A and at least one second layer B, in which layers A and B have a mutual A/B/A arrangement, wherein the layer A and layer B are different from each other, in which layer A comprises an aliphatic and/or aliphatic-aromatic biodegradable polyester or a polyvinyl alcohol or copolymers thereof and in which layer B comprises:
 i)30-95% by weight, with respect to the sum of components i-v, of at least one polyester comprising:
 a) a dicarboxylic component containing with respect to the total dicarboxylic component:
 a1) 35-70% by moles of units deriving from at least one aromatic dicarboxylic acid, 
 a2) 65-30% by moles of units deriving from at least one saturated aliphatic dicarboxylic acid, and 
 a3) 0-5% by moles of units deriving from at least one unsaturated aliphatic dicarboxylic acid; and 
 
 b) a diol component comprising with respect to the total diol component:
 b1) 95-100% by moles of units deriving from at least one saturated aliphatic diol, and 
 2) 0-5% by moles of units deriving from at least one unsaturated aliphatic diol; 
 
   ii) 0.1-50% by weight, with respect to the sum of components i-v, of at least one polymer of natural origin;   iii) 1-40% by weight, with respect to the sum of components i-v, of at least one polyhydroxy alkanoate;   iv) 0-15% by weight, with respect to the sum of components i-v, of at least one inorganic filler; and   v) 0-5% by weight, with respect to the sum of components i.-v., of at least one cross-linking agent and/or chain extender comprising at least one compound having two and/or multiple functional groups including isocyanate, peroxide, carbodiimide, isocyanurate, oxazoline, epoxide, anhydride divinylether groups and mixtures thereof.   
     
     
         2 . The multilayer film according to  claim 1 , in which the said aliphatic-aromatic polyester in layer A comprises:
 c) a dicarboxylic component comprising with respect to the total dicarboxylic component:
 c1) 35-70% by moles of units deriving from at least one aromatic dicarboxylic acid, 
 c2) 65-30% by moles of units deriving from at least one saturated aliphatic dicarboxylic acid, and 
 c3) 0-5% by moles of units deriving from at least one unsaturated aliphatic dicarboxylic acid; and 
   d) a diol component comprising with respect to the total diol component:
 d1) 95-100% by moles of units deriving from at least one saturated aliphatic diol, and 
 d2) 0-5% by moles of units deriving from at least one unsaturated aliphatic diol. 
   
     
     
         3 . The multilayer film according to  claim 2 , in which the saturated aliphatic dicarboxylic acids in component c2 comprise mixtures comprising at least 50% by moles of at least one acid selected from succinic acid, adipic acid, azelaic acid, sebacic acid, brassylic acid, their C 1 -C 24 , preferably C 1 -C 4 , esters and mixtures thereof. 
     
     
         4 . The multilayer film according to  claim 3 , in which the saturated aliphatic dicarboxylic acids in component c2 are selected from adipic acid and azelaic acid or mixtures thereof. 
     
     
         5 . The multilayer film according to  claim 1 , in which in addition to the said aliphatic and/or aliphatic-aromatic polyester in layer A the said layer A comprises 1-40% by weight with respect to the total for layer A of at least one polyhydroxy alkanoate. 
     
     
         6 . The multilayer film according to  claim 1 , in which the saturated aliphatic dicarboxylic acid of component a2 of the polyester in layer B comprise mixtures comprising at least 50% by moles of at least one acid selected from succinic acid, adipic acid, azelaic acid, sebacic acid, brassylic acid, their C 1 -C 24 , preferably C 1 -C 4 , esters and mixtures thereof. 
     
     
         7 . The multilayer film according to  claim 6 , in which the saturated aliphatic dicarboxylic acids in said component a2 are selected from adipic acid and azelaic acid or mixtures thereof. 
     
     
         8 . The multilayer film according to  claim 1 , wherein transmittance values of more than 90%, Haze values of less than 65%, and clarity over 20%, measured according to standard ASTM D1003. 
     
     
         9 . The multilayer film according to  claim 1 , said film being biodegradable under home composting conditions according to UNI 11355. 
     
     
         10 . A packaging comprising the multilayer film according to  claim 1 . 
     
     
         11 . The packaging according to  claim 10 , said packaging being selected from bags for the carrying of goods and bags for food packaging. 
     
     
         12 . A bag for fruit and vegetables according to  claim 11 . 
     
     
         13 . A mulch film comprising the multilayer film according to  claim 1 . 
     
     
         14 . The multilayer film according to  claim 2 , in which in addition to the said aliphatic and/or aliphatic-aromatic polyester in layer A the said layer A comprises 1-40% by weight with respect to the total for layer A of at least one polyhydroxy alkanoate. 
     
     
         15 . The multilayer film according to  claim 3 , in which in addition to the said aliphatic and/or aliphatic-aromatic polyester in layer A the said layer A comprises 1-40% by weight with respect to the total for layer A of at least one polyhydroxy alkanoate. 
     
     
         16 . The multilayer film according to  claim 4 , in which in addition to the said aliphatic and/or aliphatic-aromatic polyester in layer A the said layer A comprises 1-40% by weight with respect to the total for layer A of at least one polyhydroxy alkanoate. 
     
     
         17 . The multilayer film according to  claim 2 , in which the saturated aliphatic dicarboxylic acid of component a2 of the polyester in layer B comprise mixtures comprising at least 50% by moles of at least one acid selected from succinic acid, adipic acid, azelaic acid, sebacic acid, brassylic acid, their C 1 -C 24 , preferably C 1 -C 4 , esters and mixtures thereof. 
     
     
         18 . The multilayer film according to  claim 3 , in which the saturated aliphatic dicarboxylic acid of component a2 of the polyester in layer B comprise mixtures comprising at least 50% by moles of at least one acid selected from succinic acid, adipic acid, azelaic acid, sebacic acid, brassylic acid, their C 1 -C 24 , preferably C 1 -C 4 , esters and mixtures thereof. 
     
     
         19 . The multilayer film according to  claim 4 , in which the saturated aliphatic dicarboxylic acid of component a2 of the polyester in layer B comprise mixtures comprising at least 50% by moles of at least one acid selected from succinic acid, adipic acid, azelaic acid, sebacic acid, brassylic acid, their C 1 -C 24 , preferably C 1 -C 4 , esters and mixtures thereof. 
     
     
         20 . The multilayer film according to  claim 5 , in which the saturated aliphatic dicarboxylic acid of component a2 of the polyester in layer B comprise mixtures comprising at least 50% by moles of at least one acid selected from succinic acid, adipic acid, azelaic acid, sebacic acid, brassylic acid, their C 1 -C 24 , preferably C 1 -C 4 , esters and mixtures thereof.