US2019144510A1PendingUtilityA1

Modified antimicrobial peptide derived from an arginine-rich domain

Assignee: SHIH CHIAHOPriority: May 27, 2016Filed: May 25, 2017Published: May 16, 2019
Est. expiryMay 27, 2036(~9.8 yrs left)· nominal 20-yr term from priority
A61P 31/04C07K 2319/00C12N 2730/10122C12N 2730/10133C07K 14/005A01N 37/46A61K 38/00C07K 7/08C12N 2730/10033C12N 2730/10031C07K 14/02A61K 38/162A61K 38/04A01N 63/40A01N 63/50
40
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Claims

Abstract

An antimicrobial peptide, the peptide comprising 2 to 20 variable domains, each variable domain is a sequence of 2 to 20 consecutive basic amino acids, wherein (a) the variable domains are separated from each other by a variable linker, (b) the variable linker can have 1 to 20 any amino acids other than two or more consecutive basic amino acids, and (c) the peptide has no more than 100 amino acids.

Claims

exact text as granted — not AI-modified
What is claimed is: 
     
         1 . An antimicrobial peptide, the peptide comprising 2 to 20 variable domains, each variable domain is a sequence of 2 to 20 consecutive basic amino acids, wherein (a) the variable domains are separated from each other by a variable linker, (b) the variable linker can have 1 to 20 any amino acids other than two or more consecutive basic amino acids, and (c) the peptide has no more than 100 amino acids. 
     
     
         2 . The antimicrobial peptide of  claim 1 , wherein the peptide has at least 3 variable domains. 
     
     
         3 . The antimicrobial peptide of  claim 1 , wherein the peptide has a C-terminal cysteine. 
     
     
         4 . The antimicrobial peptide of  claim 1 , wherein at least one of the basic amino acids in the variable domains is an arginine. 
     
     
         5 . The antimicrobial peptide of  claim 4 , wherein all of the basic amino acids in each variable domain are arginine residues. 
     
     
         6 . The antimicrobial peptide of  claim 1 , wherein at least one of the basic amino acids is a chemically-modified amino acid. 
     
     
         7 . The antimicrobial peptide of  claim 6 , wherein the chemically-modified amino acid is a D-amino acid. 
     
     
         8 . The antimicrobial peptide of  claim 7 , wherein the D-amino acid is D-arginine. 
     
     
         9 . The antimicrobial peptide of any of  claims 1 - 8 , wherein the variable domains and the variable linkers are derived from the arginine-rich domain of a hepadnavirus core protein (HBcARD). 
     
     
         10 . The antimicrobial peptide of  claim 9 , wherein the HBcARD contains a sequence from residue 147 to the C-terminal residue of a hepadnavirus core protein. 
     
     
         11 . The antimicrobial peptide of  claim 10 , wherein each variable domain has three or four arginine residues and each variable linker has 2 to 4 amino acids. 
     
     
         12 . The peptide of  claim 11 , wherein the peptide contains a consensus sequence selected from the group consisting of:
 (i) (X 1 )GRX 2 P(X 3 )X 4 PX 5 P(X 6 )X 7 QX 8 P(X 9 ), wherein each of X 1 , X 3 , X 6 , and X 9 , individually, is a variable domain, and each of X 2 , X 4 , X 5 , X 7 , and X 8 , individually, is any amino acid or absent,   (ii) (X 1 )GRX 2 P(X 3 )X 4 PX 5 P(X 6 ), wherein each of X 1 , X 3 , and X 6 , individually, is a variable domain, and each of X 2 , X 4 , and X 5 , individually, is any amino acid or absent, and   (iii) (X 1 )X 2 PX 3 P(X 4 X 5 QX 6 P(X 7 ), wherein each of X 1 , X 4 , and X 7 , individually, is a variable domain, and each of X 2 , X 3 , X 5 , and X 6 , individually, is any amino acid or absent,   
     
     
         13 . The antimicrobial peptide of  claim 12 , wherein the peptide has a C-terminal cysteine. 
     
     
         14 . The antimicrobial peptide of  claim 12 , wherein the peptide has a consensus sequence selected from the group consisting of:
 (i) (X 1 )GRX 2 P(X 3 )X 4 PX 5 P(X 6 )X 7 QX 8 P(X 9 )X 10 C, and   (ii) (X 1 )GRX 2 P(X 3 )X 4 PX 5 P(X 6 )X 7 QX 8 P(X 9 )X 10 Q,   
       wherein each of X 1 , X 3 , X 6 , and X 9 , individually, is a variable domain, and each of X 2 , X 4 , X 5 , X 7 , X 8 , and X 10 , individually, is any amino acid or absent. 
     
     
         15 . The antimicrobial peptide of  claim 12 , wherein the peptide contains a sequence selected from the group consisting of: 
       
         
           
                 
               
                   (i) 
                 
                   TVVRRRGRSPRRRTPSPRRRRSQSPRRRRSQSRESQC, in which at 
                 
                   least one of the arginine residues is D-arginine, 
                 
                     
                 
                   (ii) 
                 
                   RRRGRSPRRRTPSPRRRRSQSPRRRRSC, 
                 
                     
                 
                   (iii) 
                 
                   RRRGRSPRRRTPSPRRRRSQSPRRRRSQ, 
                 
                     
                 
                   (iv) 
                 
                   RRRGRPRRRPPRRRRQPRRRRC, 
                 
                     
                 
                   (v) 
                 
                   RRRGRSPRRRTPSPRRRRC, 
                 
                     
                 
                   (vi) 
                 
                   RRRGRPRRRPPRRRRC, 
                 
                     
                 
                   (vii) 
                 
                   RRRTPSPRRRRSQSPRRRRC, 
                 
                   or 
                 
                     
                 
                   (viii) 
                 
                   RRRPPRRRRQPRRRRC. 
                 
             
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
                
               
            
           
         
       
     
     
         16 . The antimicrobial peptide of  claim 15 , wherein the peptide contains the sequence of RRRGRSPRRRTPSPRRRRSQSPRRRRSC, in which each of the arginine residues in the sequence is L-arginine. 
     
     
         17 . The antimicrobial peptide of  claim 15 , wherein the peptide contains the sequence of RRRGRSPRRRTPSPRRRRSQSPRRRRSC, in which at least one of the arginine residues in the sequence is D-arginine. 
     
     
         18 . The antimicrobial peptide of  claim 17 , wherein each of the arginine residues in the sequence is D-arginine. 
     
     
         19 . The antimicrobial peptide of  claim 17 , wherein the sequence is rRrGRSPrRrTPSPrRrRSQSPrRrRSC, in which R is L-arginine and r is D-arginine. 
     
     
         20 . The antimicrobial peptide of  claim 17 , wherein the sequence is RrRGRSPRrRTPSPRrRrSQSPRrRrSC, in which R is L-arginine and r is D-arginine. 
     
     
         21 . The antimicrobial peptide of  claim 15 , wherein the peptide contains the sequence of RRRGRPRRRPPRRRRQPRRRRC, in which at least one of the arginine residues in the sequence is D-arginine. 
     
     
         22 . The antimicrobial peptide of  claim 15 , wherein the sequence is rRrGRPrRrPPrRrRQPrRrRC, in which R is L-arginine and r is D-arginine. 
     
     
         23 . The antimicrobial peptide of any of  claims 15 - 22 , wherein the sequence is at the C-terminus of the peptide. 
     
     
         24 . The antimicrobial peptide of any of  claims 1 - 23 , further comprising a non-HBcARD peptide. 
     
     
         25 . The antimicrobial peptide of  claim 24 , wherein the non-HBcARD peptide is an affinity tag, a signal sequence, a ligand, or another antimicrobial peptide or fragment thereof. 
     
     
         26 . The antimicrobial peptide of  claim 25 , wherein the non-HBcARD peptide is a poly-histidine or an analog thereof. 
     
     
         27 . The antimicrobial peptide of  claim 26 , wherein the peptide has a sequence selected from the group consisting of: 
       
         
           
                 
                 
               
                     
                   (i) 
                 
                     
                   RRRGRSPRRRTPSPRRRRSQSPRRRRSHHHHHH, 
                 
                     
                     
                 
                     
                   (ii) 
                 
                     
                   HHHHHHRRRGRSPRRRTPSPRRRRSQSPRRRRS, 
                 
                     
                     
                 
                     
                   (iii) 
                 
                     
                   RRRGRPRRRPPRRRRQPRRRRHHHHHH, 
                 
                     
                   and 
                 
                     
                     
                 
                     
                   (iv) 
                 
                     
                   HHHHHHRRRGRPRRRPPRRRRQPRRRR 
                 
             
                
                
                
                
                
                
                
                
                
                
                
                
               
            
           
         
       
     
     
         28 . The antimicrobial peptide of any of  claims 1 - 4 , wherein at least one variable domain has a lysine. 
     
     
         29 . The antimicrobial peptide of any of  claims 1 - 4 , wherein at least one variable domain has a histidine. 
     
     
         30 . The peptide of any of  claims 1 - 29 , wherein the peptide has a cyclic structure. 
     
     
         31 . The antimicrobial peptide of any of  claims 1 - 30 , wherein the peptide exhibits a broad spectrum antimicrobial activity against a gram-positive bacteria, gram-negative bacteria, fungus, parasite, or virus. 
     
     
         32 . An antimicrobial peptide conjugate, the conjugate comprising the peptide of any of  claims 1 - 31  and a non-peptide moiety. 
     
     
         33 . A pharmaceutical composition comprising the antimicrobial peptide of any of  claims 1 - 31  and a pharmaceutically acceptable carrier. 
     
     
         34 . A pharmaceutical composition comprising the antimicrobial peptide conjugate of  claim 32  and a pharmaceutically acceptable carrier. 
     
     
         35 . A method of treating a microbial infection, the method comprising administering the composition of  claim 33  or  34  to a subject in need thereof.

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