US2019071565A1PendingUtilityA1

Optical component

Assignee: ASAHI CHEMICAL INDPriority: Aug 30, 2016Filed: Nov 6, 2018Published: Mar 7, 2019
Est. expiryAug 30, 2036(~10.1 yrs left)· nominal 20-yr term from priority
C08F 222/00C08L 35/06C08F 220/14C08L 33/24C07D 207/448C08L 33/10
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Claims

Abstract

Provided is an optical component comprising a methacrylic resin composition having excellent surface processability and displaying excellent preservability of formed surface processing. The optical component contain a methacrylic resin including a structural unit (X) having a cyclic structure-containing main chain that is at least one selected from the group consisting of an N-substituted maleimide monomer-derived structural unit, a glutarimide-based structural unit, and a lactone ring structural unit. The methacrylic resin composition has a Vicat softening temperature of 120° C. to 160° C. Among methacrylic acid ester monomer-derived structural units, a ratio (S/H) of the integrated intensity (S) of a syndiotactic fraction (rr) relative to the integrated intensity (H) of a heterotactic fraction (mr), as determined by 1 H-NMR measurement, is 1.20 to 1.50. The amount of methanol-soluble content is 5 mass % or less relative to 100 mass %, in total, of methanol-soluble content and methanol-insoluble content.

Claims

exact text as granted — not AI-modified
1 . An optical component comprising a methacrylic resin composition comprising
 a methacrylic resin including a structural unit (X) having a cyclic structure-containing main chain, the structural unit (X) being at least one selected from the group consisting of an N-substituted maleimide monomer-derived structural unit, a glutarimide-based structural unit, and a lactone ring structural unit, wherein   the methacrylic resin composition has a Vicat softening temperature of 120° C. to 160° C.,   among methacrylic acid ester monomer-derived structural units, a ratio (S/H) of integrated intensity (S) of a syndiotactic fraction (rr) relative to integrated intensity (H) of a heterotactic fraction (mr), as determined by  1 H-NMR measurement, is 1.20 to 1.50,   methanol-soluble content is contained in an amount of 5 mass % or less relative to 100 mass %, in total, of the methanol-soluble content and methanol-insoluble content, and   the optical component has an embossed section on at least part of either or both of a front surface and a rear surface.   
     
     
         2 . The optical component according to  claim 1 , wherein the methacrylic resin composition has a weight average molecular weight (Mw) of 120,000 to 200,000 as measured by gel permeation chromatography as a polymethyl methacrylate equivalent molecular weight. 
     
     
         3 . The optical component according to  claim 1 , wherein
 the structural unit (X) includes an N-substituted maleimide monomer-derived structural unit, and   the N-substituted maleimide monomer-derived structural unit has a content of 5 mass % to 40 mass % relative to 100 mass % of the methacrylic resin.   
     
     
         4 . The optical component according to  claim 1 , wherein
 the structural unit (X) includes a lactone ring structural unit, and   the lactone ring structural unit has a content of 5 mass % to 40 mass % relative to 100 mass % of the methacrylic resin.   
     
     
         5 . The optical component according to  claim 1 , wherein the methacrylic resin composition has a photoelastic coefficient with an absolute value of 2.0×10 −12  Pa −1  or less. 
     
     
         6 . The optical component according to  claim 5 , wherein the methacrylic resin composition has a photoelastic coefficient with an absolute value of 1.0×10 −12  Pa −1  or less. 
     
     
         7 . An optical component according to  claim 1  that is an optical film.

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