Thermal barrier coatings for components in high-temperature mechanical systems

Abstract

An article that includes a substrate; a first layer including yttria and zirconia or hafnia, where the first layer has a columnar microstructure and includes predominately the zirconia or hafnia; a second layer on the first layer, the second layer including zirconia or hafnia, ytterbia, samaria, and at least one of lutetia, scandia, ceria, neodymia, europia, and gadolinia, where the second layer includes predominately zirconia or hafnia, and where the second layer has a columnar microstructure; and a third layer on the second layer, the third layer including zirconia or hafnia, ytterbia, samaria, and a rare earth oxide including at least one of lutetia, scandia, ceria, neodymia, europia, and gadolinia, where the third layer has a dense microstructure and has a lower porosity than the second layer.

What is claimed is: 
     
         1 . An article comprising:
 a substrate;   a first layer comprising a first base oxide comprising zirconia or hafnia and a first rare earth oxide comprising yttria, wherein the first layer has a columnar microstructure, wherein the first layer comprises predominately the first base oxide;   a second layer on the first layer, the second layer comprising a second base oxide comprising zirconia or hafnia, a second rare earth oxide comprising ytterbia, a third rare earth oxide comprising samaria, and a fourth rare earth oxide comprising at least one of lutetia, scandia, ceria, neodymia, europia, and gadolinia, wherein the second layer comprises predominately the second base oxide, and wherein the second layer has a columnar microstructure; and   a third layer on the second layer, the third layer comprising a third base oxide comprising zirconia or hafnia, the second rare earth oxide, the third rare earth oxide, and a fifth rare earth oxide comprising at least one of lutetia, scandia, ceria, neodymia, europia, and gadolinia, wherein the third layer has a dense microstructure and has a lower porosity than the second layer.   
     
     
         2 . The article of  claim 1 , further comprising a bond coat between the substrate and the first layer. 
     
     
         3 . The article of  claim 1 , wherein the second layer comprises a cubic phase constitution, and wherein the third layer comprises a tetragonal prime phase constitution. 
     
     
         4 . The article of  claim 3 , wherein the second layer comprises between about 3 mol. % and about 10 mol. % ytterbia, between about 1 mol. % and about 5 mol. % gadolinia, between about 1 mol. % and about 5 mol. % samaria, and a balance zirconia, and wherein the third layer comprises between about 1 mol. % and about 5 mol. % ytterbia, between about 0.1 mol. % and about 3 mol. % gadolinia, and between about 0.1 mol. % and about 3 mol. % samaria, and a balance zirconia. 
     
     
         5 . The article of  claim 1 , wherein the third layer further comprises alumina in a separate phase. 
     
     
         6 . The article of  claim 1 , further comprising a fourth layer comprising a fourth base oxide comprising zirconia or hafnia, alumina, the second rare earth oxide, the third rare earth oxide, and a sixth rare earth oxide comprising at least one of lutetia, scandia, ceria, neodymia, europia, and gadolinia, wherein the fourth layer has a dense microstructure and has a lower porosity than the second layer. 
     
     
         7 . The article of  claim 6 , wherein the fourth layer comprises a tetragonal prime phase comprising the zirconia, ytterbia, gadolinia, samaria; and an alumina phase. 
     
     
         8 . The article of  claim 7 , wherein at least one of the first layer, the second layer, the third layer, or the fourth layer is deposited using a suspension plasma spray technique. 
     
     
         9 . A method comprising:
 depositing a first plurality of particles on a substrate to form a first layer, wherein the first plurality of particles comprises a first base oxide comprising zirconia or hafnia and a first rare earth oxide comprising yttria, and wherein the first layer comprises a columnar microstructure;   depositing a second plurality of particles on the first layer using a suspension plasma spray technique to form a second layer, wherein the second plurality of particles comprises a second base oxide comprising zirconia or hafnia, a second rare earth oxide comprising ytterbia, a third rare earth oxide comprising samaria, and a fourth rare earth oxide comprising at least one of lutetia, scandia, ceria, neodymia, europia, and gadolinia, wherein the second layer comprises a columnar microstructure; and   depositing a third plurality of particles using a suspension plasma spray technique to form a third layer on the second layer, wherein the third plurality of particles comprises a third base oxide comprising zirconia or hafnia, the second rare earth oxide, the third rare earth oxide, and a fifth rare earth oxide comprising at least one of lutetia, scandia, ceria, neodymia, europia, and gadolinia, wherein the third layer has a dense microstructure and has a lower porosity than the second layer.   
     
     
         10 . The method of  claim 9 , further comprising depositing a bond coat on the substrate, wherein the bond coat comprises at least one of Pt or MCrAlY, wherein M is Ni, Co, or NiCo, and wherein depositing the first plurality of particles comprises depositing the first plurality of particles on the bond coat. 
     
     
         11 . The method of  claim 9 , wherein the third plurality of particles further comprises alumina. 
     
     
         12 . The method of  claim 9 , further comprising depositing a fourth plurality of particles on the third layer to form a fourth layer, wherein the fourth plurality of particles comprises a fourth base oxide comprising zirconia or hafnia, alumina, the second rare earth oxide comprising ytterbia, the third rare earth oxide, and a sixth rare earth oxide comprising at least one of lutetia, scandia, ceria, neodymia, europia, and gadolinia, wherein the fourth layer comprises at least one of a dense microstructure or a columnar microstructure. 
     
     
         13 . The method of  claim 9 , wherein at least one of the first, second, or third plurality of particles defines an average diameter of about 1 μm or less. 
     
     
         14 . The method of  claim 9 , wherein the second plurality of particles comprises pre-alloyed particles, wherein the pre-alloyed particles comprise a cubic phase constitution. 
     
     
         15 . The method of  claim 9 , wherein the second plurality of particles comprises first particles comprising zirconia, second particles comprising ytterbia, third particles comprising samaria, and fourth particles comprising gadolinia. 
     
     
         16 . The method of  claim 15 , wherein once deposited, the second layer comprises a cubic phase constitution. 
     
     
         17 . The method of  claim 9 , wherein the third plurality of particles comprises pre-alloyed particles, wherein the pre-alloyed particles comprise a tetragonal prime phase constitution. 
     
     
         18 . The method of  claim 9 , wherein the third plurality of particles comprises first particles comprising zirconia, second particles comprising ytterbia, third particles comprising samaria, and fourth particles comprising gadolinia. 
     
     
         19 . The method of  claim 18 , wherein once deposited, the third layer comprises a tetragonal prime phase constitution. 
     
     
         20 . The method of  claim 9 , wherein depositing the second plurality of particles or depositing the third plurality of particles comprises:
 forming a suspension including a respective set of particles and a solvent;   introducing the suspension into a heating plume of a plasma spray device;   directing the respective set of particles in the suspension toward the substrate with the heating plume; and   depositing the respective set of particles to form a layer.