US2019017137A1PendingUtilityA1

Non-oriented electrical steel sheet and manufacturing method therefor

Assignee: POSCOPriority: Dec 23, 2015Filed: Dec 23, 2016Published: Jan 17, 2019
Est. expiryDec 23, 2035(~9.4 yrs left)· nominal 20-yr term from priority
C21D 2211/004C22C 38/004C22C 38/14C22C 38/06C21D 8/1222C22C 38/008C22C 38/60C21D 8/1233C22C 38/02C22C 38/001C22C 38/04C21D 8/1272C21D 8/1261C22C 38/00C21D 8/12
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Claims

Abstract

A non-oriented electrical steel sheet according to one embodiment of the present disclosure comprises 0.005 wt % or less of C (excluding 0 wt %), 1.0-4.0 wt % of Si, 0.15-1.5 wt % of Al, 0.1-1.0 wt % of Mn, 0.2 wt % or less of P (excluding 0 wt %), 0.005 wt % or less of N (excluding 0 wt %), 0.001-0.006 wt % of S, 0.005 wt % or less of Ti (excluding 0 wt %), and 0.005 wt % or less of O (excluding 0 wt %), and the remainder being Fe and other inevitable impurities, and satisfies formula 1 below, wherein a mean size of oxides in the precipitates is larger than a mean size of non-oxides. [ Si ] 1.8 + 1.3 × [ Al ] > 3.7 × [ Mn ] × [ Mn ] Formula   ( 1 ) (Here, [Si], [Al] and [Mn] represent the contents (in wt %) of Si, Al and Mn, respectively.)

Claims

exact text as granted — not AI-modified
1 . A non-oriented electrical steel sheet, comprising:
 0.005 wt % or less of C (excluding 0 wt %), 1.0-4.0 wt % of Si, 0.15-1.5 wt % of Al, 0.1-1.0 wt % of Mn, 0.2 wt % or less of P (excluding 0 wt %), 0.005 wt % or less of N (excluding 0 wt %), 0.001-0.006 wt % of S, 0.005 wt % or less of Ti (excluding 0 wt %), and 0.005 wt % or less of O (excluding 0 wt %), and the remainder being Fe and other inevitable impurities,   and satisfies formula 1 below,   wherein a mean size of oxides in the precipitates is larger than a mean size of non-oxides.   
       
         
           
             
               
                 
                   
                     
                       
                         
                           [ 
                           Si 
                           ] 
                         
                         1.8 
                       
                       + 
                       
                         1.3 
                         × 
                         
                           [ 
                           Al 
                           ] 
                         
                       
                     
                     > 
                     
                       3.7 
                       × 
                       
                         [ 
                         Mn 
                         ] 
                       
                       × 
                       
                         [ 
                         Mn 
                         ] 
                       
                     
                   
                 
                 
                   
                     Formula 
                      
                     
                         
                     
                      
                     
                       ( 
                       1 
                       ) 
                     
                   
                 
               
             
           
         
         (Here, [Si], [Al] and [Mn] represent the contents (in wt %) of Si, Al and Mn, respectively.) 
       
     
     
         2 . The non-oriented electrical steel sheet of  claim 1 , wherein
 a number of oxides in the precipitates is larger than that of non-oxides.   
     
     
         3 . The non-oriented electrical steel sheet of  claim 1 ,
 further comprising 0.01 to 0.2 wt % of Sn and Sb, individually or in combination, respectively.   
     
     
         4 . The non-oriented electrical steel sheet of  claim 1 ,
 wherein a number of FeO in the precipitates or precipitates containing FeO is 40% or more.   
     
     
         5 . The non-oriented electrical steel sheet of  claim 1 ,
 wherein a mean particle size is 50 to 180 μm.   
     
     
         6 . A method for manufacturing a non-oriented electrical steel sheet, comprising steps of:
 heating a slab comprising 0.005 wt % or less of C (excluding 0 wt %), 1.0-4.0 wt % of Si, 0.15-1.5 wt % of Al, 0.1-1.0 wt % of Mn, 0.2 wt % or less of P (excluding 0 wt %), 0.005 wt % or less of N (excluding 0 wt %), 0.001-0.006 wt % of S, 0.005 wt % or less of Ti (excluding 0 wt %), and 0.005 wt % or less of O (excluding 0 wt %), and the remainder being Fe and other inevitable impurities, and satisfying formula 1 below and then hot rolling the slab to prepare a hot rolled sheet;   winding and then cooling the hot rolled sheet;   annealing and then cooling the hot rolled sheet;   cold rolling the hot rolled annealing sheet to prepare a cold rolled sheet; and   final annealing and then cooling the cold rolled sheet,   wherein, the step of winding and cooling the hot rolled sheet comprises cooling at 600° C. or higher for 30 minutes or more,   the step of annealing and then cooling the hot rolled sheet includes cooling at 600° C. or higher for 5 seconds or more, and   the step of annealing and then cooling the cold rolled sheet includes cooling at 600° C. or higher for 5 seconds or more.   
       
         
           
             
               
                 
                   
                     
                       
                         
                           [ 
                           Si 
                           ] 
                         
                         1.8 
                       
                       + 
                       
                         1.3 
                         × 
                         
                           [ 
                           Al 
                           ] 
                         
                       
                     
                     > 
                     
                       3.7 
                       × 
                       
                         [ 
                         Mn 
                         ] 
                       
                       × 
                       
                         [ 
                         Mn 
                         ] 
                       
                     
                   
                 
                 
                   
                     Formula 
                      
                     
                         
                     
                      
                     
                       ( 
                       1 
                       ) 
                     
                   
                 
               
             
           
         
         (Here, [Si], [Al] and [Mn] represent the contents (in wt %) of Si, Al and Mn, respectively.) 
       
     
     
         7 . The method of  claim 6 , wherein
 wherein the slab further comprises 0.01 to 0.2 wt % of Sn and Sb, individually or in combination.   
     
     
         8 . The method of  claim 6 , wherein
 the step of preparing the hot rolled sheet comprises heating the slab at 1200° C. or lower.   
     
     
         9 . The method of  claim 6 , wherein
 a temperature of the winding is 600 to 800° C. in the step of winding and then cooling the hot rolled sheet.   
     
     
         10 . The method of  claim 6 , wherein
 a temperature of the hot rolled sheet annealing is 850 to 1150° C. in the step of annealing and then cooling the hot rolled sheet.   
     
     
         11 . The method of  claim 6 , wherein
 wherein the step of cold rolling the hot rolled annealing sheet to prepare a cold rolled sheet comprises cold rolling to a thickness of 0.1 to 0.7 mm.   
     
     
         12 . The method of  claim 6 , wherein
 the step of cold rolling the hot rolled annealing sheet to prepare a cold rolled sheet comprises primary cold rolling, intermediate annealing, and secondary cold rolling.   
     
     
         13 . The method of  claim 6 , wherein
 a cracking temperature of the cold rolled sheet annealing during annealing is 850 to 1100° C. in the step of annealing and then cooling the cold rolled sheet.   
     
     
         14 . The method of  claim 6 , wherein
 a mean size of oxides in the precipitates of a manufactured electrical steel sheet is larger than a mean size of non-oxides.   
     
     
         15 . The method of  claim 14 , wherein
 a number of oxides in the precipitates is larger than that of non-oxides.   
     
     
         16 . The method of  claim 14 , wherein
 a number of FeO in the precipitates or precipitates containing FeO is 40% or more.   
     
     
         17 . The method of  claim 14 ,
 wherein a mean particle size is 50 to 180 μm.

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