Multi-stage polymer composition and films made therefrom

Abstract

A multi-stage polymer composition comprising a crosslinked core having a Tg of from −85 to −10° C.; an intermediate region which comprises one or more intermediate layers, wherein each of the intermediate layers comprises from 88.5 to 99.9 weight percent of units derived from a one or more monomers selected from the group consisting of alkyl (meth)acrylate monomers, from 0 to 5 weight percent of units derived from a cross-linking monomer, a graft-linking monomer, or a combination of two or more thereof, optionally from 0 to 2 weight percent units derived from one or more chain transfer agents; wherein there is a compositional gradient between the intermediate layers such that the Tg transitions from −30° C. to 70° C. over the width of the intermediate region, and an outermost layer which has a Tg of from 40° C. to 110° C. is provided.

1 . A multi-stage polymer composition comprising:
 a crosslinked core which comprises greater than 95 weight percent of units derived from one or more monomers selected from the group consisting of alkyl (meth)acrylate monomers, from 0.1 to 5 weight percent of units derived from a cross-linking monomer, graft-linking monomer, or combination thereof, and wherein the crosslinked core has a Tg of from −85 to −10° C.;   an intermediate region which comprises one or more intermediate layers, wherein each of the intermediate layers comprises from 88.5 to 100 weight percent of units derived from a one or more monomers selected from the group consisting of alkyl (meth)acrylate monomers, from 0 to 5 weight percent of units derived from a cross-linking monomer, a graft-linking monomer, or a combination of two or more thereof, optionally from 0 to 2.0 weight percent units derived from one or more chain transfer agents; wherein there is a compositional gradient between the intermediate layers such that the compositional gradient transitions between a lower Tg and an upper Tg, wherein said lower Tg is at least −10° C. and said upper Tg is 70° C. or less over the width of the intermediate region, and   an outermost layer which comprises from 98.5 to 100 weight percent units derived from one or more monomers selected from the group consisting of alkyl (meth)acrylate, styrenic monomers, and combinations of two or more thereof, from 0 to 1.5 weight percent units derived from one or more chain transfer agents, and has a Tg of from 40° C. to 110° C.   
     
     
         2 . The multi-stage polymer composition according to  claim 1 , wherein the outermost layer has a Tg of from 50° C. to 97° C. 
     
     
         3 . The multi-stage polymer composition according to  claim 1 , wherein the crosslinked core has a Tg of from −55 to −30 C. 
     
     
         4 . The multi-stage polymer composition according to  claim 1 , wherein the cross-linking monomer of the crosslinked core, the graft-linking monomer of the crosslinked core, the cross-linking monomer of the intermediate layer(s) and the graft-linking monomer of the intermediate layer(s) are selected from the group consisting of butanediol di(meth)acrylate, ethylene glycol di(meth)acrylate, divinyl benzene, diethylene glycol di(meth)acrylate, trimethylolpropane triacrylate, butylene glycol dimethacrylate, blends thereof, and combinations of two or more thereof. 
     
     
         5 . The multi-stage polymer composition according to  claim 1 , wherein the cross-linking monomer of the crosslinked core and the cross-linking monomer of the intermediate layer(s) are selected from the group consisting allyl methacrylate, diallyl maleate, blends thereof, and combinations of two or more thereof. 
     
     
         6 . The multi-stage polymer composition according to  claim 1 , wherein the cross-linking monomer of the crosslinked core is butanediol diacrylate, the graft-linking monomer of the crosslinked core is allyl methacrylate and the graft-linking monomer of the intermediate layer(s) is allyl methacrylate. 
     
     
         7 . The multi-stage polymer composition according to  claim 1 , wherein the alkyl (meth)acrylate monomers of the crosslinked core are selected from the group consisting of butyl acrylate, ethyl hexyl acrylate, ethyl acrylate, methyl methacrylate, and combinations of two or more thereof. 
     
     
         8 . The multi-stage polymer composition according to  claim 1 , wherein the alkyl (meth)acrylate monomers of the intermediate layer(s) are selected from the group consisting of butyl acrylate, ethyl hexyl acrylate, ethyl acrylate, methyl methacrylate, cyclohexyl (meth)acrylate, cyclopentyl methacrylate, tetrahydrofurfyl methacrylate, benzyl (meth)acryale and combinations of two or more thereof. 
     
     
         9 . The multi-stage polymer composition according to  claim 1 , wherein the alkyl (meth)acrylate monomers of the outermost layer are selected from the group consisting of butyl acrylate, ethyl hexyl acrylate, ethyl acrylate, methyl methacrylate, and combinations of two or more thereof. 
     
     
         10 . The multi-stage polymer composition according to  claim 1 , wherein the crosslinked core comprises at least 95 weight percent units of butyl acrylate and from 0.1 to 5.0 weight percent units of a combination of butylene glycol diacrylate and allyl methacrylate. 95 weight percent units derived from a combination of butyl acrylate and butylene glycol diacrylate monomers and from 0.1 to 5 weight percent units derived from allyl methacrylate. 
     
     
         11 . The multi-stage polymer composition according to  claim 1 , wherein the one or more intermediate layers each comprise units derived from butyl acrylate and methyl methacrylate. 
     
     
         12 . The multi-stage polymer composition according to  claim 1 , wherein the outermost layer comprises greater than 95 weight percent units derived from a combination of butyl acrylate and methyl methacrylate monomers. 
     
     
         13 . The multi-stage polymer composition according to  claim 1  are formed by emulsion polymerization, wherein the latex particles having an average particle size less than 250 nm. 
     
     
         14 . The multi-stage polymer composition according to  claim 1 , wherein the weight average (M w ) molecular weight of the outermost layer composition is less than 50,000 g/mol. 
     
     
         15 . A film or sheet comprising the multi-stage polymer composition according to  claim 1 . 
     
     
         16 . The film or sheet according to  claim 15 , wherein the film exhibits one or more of the following properties: a modulus of 30,000 psi or less; and an elongation at break of at least 200%. 
     
     
         17 . The film or sheet according to  claim 15 , wherein the film or sheet has a thickness of from 3 mil to 12 mil and exhibits one or more of the following properties: a haze of less than 1%; and a yellowness index of less than 1%.