Method for producing silver nanoparticles, silver nanoparticles, and silver coating composition

Abstract

The present invention provides silver nano-particles that are excellent in stability and develop excellent conductivity by low-temperature calcining, a producing method for same, and a silver coating composition comprising the silver nano-particles. A method for producing silver nano-particles comprising: preparing an amine mixture liquid comprising: an aliphatic hydrocarbon monoamine (A) comprising an aliphatic hydrocarbon group and one amino group, said aliphatic hydrocarbon group having 6 or more carbon atoms in total; an aliphatic hydrocarbon monoamine (B) comprising an aliphatic hydrocarbon group and one amino group, said aliphatic hydrocarbon group having 5 or less carbon atoms in total; and an aliphatic hydrocarbon diamine (C) comprising an aliphatic hydrocarbon group and two amino groups, said aliphatic hydrocarbon group having 8 or less carbon atoms in total; mixing a silver compound and the amine mixture liquid to forma complex compound comprising the silver compound and the amines; and thermally decomposing the complex compound by heating to form silver nano-particles.

1 . A method for producing silver nano-particles comprising:
 preparing an amine mixture liquid comprising:   an aliphatic hydrocarbon monoamine (A) comprising an aliphatic hydrocarbon group and one amino group, said aliphatic hydrocarbon group having 6 or more carbon atoms in total;   an aliphatic hydrocarbon monoamine (B) comprising an aliphatic hydrocarbon group and one amino group, said aliphatic hydrocarbon group having 5 or less carbon atoms in total; and   an aliphatic hydrocarbon diamine (C) comprising an aliphatic hydrocarbon group and two amino groups, said aliphatic hydrocarbon group having 8 or less carbon atoms in total;   mixing a silver compound and the amine mixture liquid to form a complex compound comprising the silver compound and the amines; and   thermally decomposing the complex compound by heating to form silver nano-particles.   
     
     
         2 . The method for producing silver nano-particles according to  claim 1 , wherein the aliphatic hydrocarbon monoamine (A) is an alkylmonoamine having 6 or more and 12 or less carbon atoms. 
     
     
         3 . The method for producing silver nano-particles according to  claim 1  or  2 , wherein the aliphatic hydrocarbon monoamine (B) is an alkylmonoamine having 2 or more and 5 or less carbon atoms. 
     
     
         4 . The method for producing silver nano-particles according to any one of  claims 1  to  3 , wherein the aliphatic hydrocarbon monoamine (B) is a butylamine. 
     
     
         5 . The method for producing silver nano-particles according to any one of  claims 1  to  4 , wherein the silver compound is silver oxalate. 
     
     
         6 . The method for producing silver nano-particles according to any one of  claims 1  to  5 , wherein the aliphatic hydrocarbon monoamine (A) is contained in the amine mixture liquid in an amount of 10 mol % to 65 mol % of a total of the monoamine (A), the monoamine (B), and the diamine (C). 
     
     
         7 . The method for producing silver nano-particles according to any one of  claims 1  to  6 , wherein the aliphatic hydrocarbon monoamine (B) is contained in the amine mixture liquid in an amount of 5 mol % to 50 mol % of a total of the monoamine (A), the monoamine (B), and the diamine (C). 
     
     
         8 . The method for producing silver nano-particles according to any one of  claims 1  to  7 , wherein the aliphatic hydrocarbon diamine (C) is contained in the amine mixture liquid in an amount of 15 mol % to 50 mol % of a total of the monoamine (A), the monoamine (B), and the diamine (C). 
     
     
         9 . The method for producing silver nano-particles according to any one of  claims 1  to  8 , wherein the monoamine (A), the monoamine (B), and the diamine (C) are used in a total amount of 1 to 20 moles per mole of silver atoms in the silver compound. 
     
     
         10 . The method for producing silver nano-particles according to any one of  claims 1  to  9 , wherein the amine mixture liquid further contains an aliphatic carboxylic acid (D). 
     
     
         11 . Silver nano-particles produced by the method according to any one of  claims 1  to  10 . 
     
     
         12 . A silver coating composition comprising silver nano-particles produced by the method according to any one of  claims 1  to  10 , and an organic solvent. 
     
     
         13 . A silver conductive material comprising:
 a substrate, and   a silver conductive layer obtained by applying, onto the substrate, a silver coating composition comprising silver nano-particles produced by the method according to any one of  claims 1  to  10  and an organic solvent, and calcining the silver coating composition.