High temperature melting

Abstract

The present invention relates to methods for making wear and oxidation resistant polymeric materials by high temperature melting. The invention also provides methods of making medical implants containing cross-linked antioxidant-containing tough and ductile polymers and materials used therewith also are provided.

What is claimed is: 
     
         1 - 63 . (canceled) 
     
     
         64 . A wear resistant polymeric material made by a process comprising the steps of:
 (i) blending a polymeric material with at least one type of antioxidant and one type of peroxide to form a blended polymeric material;   (ii) consolidating the blended polymeric material;   (iii) heating the consolidated blended polymeric material at a temperature that is about 200° C. or more at about ambient pressure; and   (iv) cooling the heated material to below the melting temperature of the polymeric material, thereby forming a wear resistant polymeric material.   
     
     
         65 . The wear resistant polymeric material of  claim 64 , wherein the polymeric material is machined after consolidating the blended polymeric material. 
     
     
         66 . The wear resistant polymeric material of  claim 64  is machined into a medical implant. 
     
     
         67 . The wear resistant polymeric material of  claim 66 , wherein the medical implant is further packaged and sterilized. 
     
     
         68 . The wear resistant polymeric material of  claim 67 , wherein the sterilization is done by gamma irradiation. 
     
     
         69 . The wear resistant polymeric material of  claim 64 , wherein the heating of the consolidated polymeric material is carried out above 200□C and is continued for at least 2 hours. 
     
     
         70 . The wear resistant polymeric material of  claim 64 , wherein the heating is performed in an inert atmosphere. 
     
     
         71 . The wear resistant polymeric material of  claim 64 , wherein the heating is carried in air or in an atmosphere containing oxygen, wherein the oxygen concentration is at least about 1%, 2%, 4%, or up to about 22%. 
     
     
         72 . The wear resistant polymeric material of  claim 64 , wherein the antioxidant is a phenolic antioxidant, vitamin E, or a mixture thereof. 
     
     
         73 . The wear resistant polymeric material of  claim 72 , wherein the phenolic antioxidant is Pentaerythritol Tetrakis (3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate). 
     
     
         74 . The wear resistant polymeric material of  claim 64 , wherein the polymeric material is compression molded as a single layer containing one or more antioxidants. 
     
     
         75 . The wear resistant polymeric material of  claim 64 , wherein the polymeric material is compression molded as multiple layers, wherein the layers contain different concentrations of one or more antioxidants. 
     
     
         76 . The wear resistant polymeric material of  claim 64 , wherein the polymeric material is compression molded to a second surface, thereby forming an interlocked hybrid material. 
     
     
         77 . The wear resistant polymeric material of  claim 64 , wherein the polymeric material is selected from the group consisting of a low-density polyethylene, high-density polyethylene, linear low-density polyethylene, ultra-high molecular weight polyethylene (UHMWPE), or a mixtures thereof. 
     
     
         78 . The wear resistant polymeric material of  claim 64 , wherein the polymeric material is ultra-high molecular weight polyethylene (UHMWPE).