Compositions and adhesive articles including porous polymeric particles and methods of coating substrates

Abstract

Compositions are provided that include a coating and porous polymeric particles disposed in the coating. Adhesive articles are also provided including a substrate and a composition disposed on a first major surface of the substrate. The composition includes an adhesive and porous polymeric particles disposed in the adhesive. Further, a method of coating a substrate is provided including providing a composition, providing a substrate having a surface, and applying the composition on the surface of the substrate. The compositions and adhesive articles can be applied to wet substrates or dry substrates.

1 . A composition comprising 1) a coating; and 2) porous polymeric particles disposed in the coating, wherein the porous polymeric particles comprise a polymerized product of a reaction mixture comprising:
 a) a first phase comprising
 i) a compound of Formula (I)
   HO(—CH 2 —CH(OH)—CH2-O) n —H   (I)
 
 
   wherein n is an integer equal to at least 1; and
 ii) a nonionic surfactant; 
   b) a second phase dispersed in the first phase, wherein a volume of the first phase is greater than a volume of the second phase and wherein the second phase comprises
 i) a monomer composition comprising a monomer of Formula (II)
   CH 2 ═C(R 1 )—(CO)—O[—CH 2 —CH 2 —O] p —(CO)—C(R 1 )═CH 2    (II)
 
 
   wherein   p is an integer equal to at least 1;   R 1  is a hydrogen or alkyl; and
 ii) a poly(propylene glycol) having a weight average molecular weight of at least 500 grams/mole, wherein the poly(propylene glycol) is removed from the polymerized product to provide the porous polymeric particles. 
   
     
     
         2 . The composition of  claim 1 , wherein the coating comprises an adhesive. 
     
     
         3 . The composition of  claim 1 , wherein the porous polymeric particles are free of a coating applied to an exterior surface of the porous polymeric particles, are free of an active loaded into the porous polymeric particles, or both. 
     
     
         4 . The composition of  claim 1 , wherein the coating comprises an epoxy, an acrylic, a urethane, a silicone, a rubber, or a combination thereof. 
     
     
         5 . The composition of  claim 1 , wherein the particles are disposed in the coating in a pattern. 
     
     
         6 . An adhesive article comprising a substrate and a composition disposed on a first major surface of the substrate, the composition comprising 1) an adhesive; and 2) porous polymeric particles disposed in the adhesive, wherein the porous polymeric particles comprise a polymerized product of a reaction mixture comprising:
 a) a first phase comprising
 i) a compound of Formula (I)
   HO(—CH 2 —CH(OH)—CH2-O) n —H   (I)
 
 
   wherein n is an integer equal to at least 1; and
 ii) a nonionic surfactant; 
   b) a second phase dispersed in the first phase, wherein a volume of the first phase is greater than a volume of the second phase and wherein the second phase comprises
 i) a monomer composition comprising a monomer of Formula (II)
   CH 2 ═C(R 1 )—(CO)—O[—CH 2 —CH 2 —O] p —(CO)—C(R 1 )═CH 2    (II)
 
 
   wherein   p is an integer equal to at least 1;   R 1  is a hydrogen or alkyl; and
 ii) a poly(propylene glycol) having a weight average molecular weight of at least 500 grams/mole, wherein the poly(propylene glycol) is removed from the polymerized product to provide the porous polymeric particles. 
   
     
     
         7 . The adhesive article of  claim 6 , wherein the adhesive comprises a hot melt adhesive. 
     
     
         8 . The adhesive article of  claim 6 , wherein the adhesive comprises a pressure sensitive adhesive. 
     
     
         9 . The adhesive article of  claim 6 , further comprising a second composition disposed on a second major surface of the substrate. 
     
     
         10 . A method of coating a substrate comprising:
 a) providing a composition;   b) providing a substrate comprising a surface; and   c) applying the composition on the surface of the substrate;   wherein the composition comprises 1) a coating; and 2) porous polymeric particles disposed in the coating, wherein the porous polymeric particles comprise a polymerized product of a reaction mixture comprising:
 A) a first phase comprising
 i) a compound of Formula (I)
   HO(—CH 2 —CH(OH)—CH2-O) n —H   (I)
 
 
 wherein n is an integer equal to at least 1; and 
 ii) a nonionic surfactant; 
 
 B) a second phase dispersed in the first phase, wherein a volume of the first phase is greater than a volume of the second phase and wherein the second phase comprises
 i) a monomer composition comprising a monomer of Formula (II)
   CH 2 ═C(R 1 )—(CO)—O[—CH 2 —CH 2 —O] p —(CO)—C(R 1 )═CH 2    (II)
 
 
 
 wherein 
 p is an integer equal to at least 1; 
 R 1  is a hydrogen or alkyl; and
 ii) a poly(propylene glycol) having a weight average molecular weight of at least 500 grams/mole, wherein the poly(propylene glycol) is removed from the polymerized product to provide the porous polymeric particles. 
 
   
     
     
         11 . The method of  claim 10 , wherein an ambient air temperature is less than 5 degrees Fahrenheit (about 2.8 degrees Celsius) above an ambient air dew point at the time of coating the composition on the surface of the substrate. 
     
     
         12 . The method of  claim 10 , wherein water condensation is disposed on at least a portion of the surface of the substrate at the time of coating the composition on the surface of the substrate. 
     
     
         13 . The method of  claim 10 , wherein standing water is disposed on at least a portion of the substrate of the substrate at the time of coating the composition on the surface of the substrate. 
     
     
         14 . The method of  claim 10 , wherein the substrate is steel. 
     
     
         15 . The method of  claim 10 , wherein the composition is part of an adhesive article, and the applying the composition on the surface of the substrate comprises contacting the adhesive article with the surface of the substrate.