US2018010226A1PendingUtilityA1

High-strength plated steel sheet having excellent plating properties, workability, and delayed fracture resistance, and method for producing same

Assignee: KK KOBE SEIKO SHO (KOBE STEEL LTDPriority: Jan 9, 2015Filed: Jan 5, 2016Published: Jan 11, 2018
Est. expiryJan 9, 2035(~8.5 yrs left)· nominal 20-yr term from priority
C21D 8/02C21D 8/0278Y10T428/265Y10T428/264Y10T428/263Y10T428/24967Y10T428/2495Y10T428/12972Y10T428/12799Y10T428/12792Y10T428/12667Y10T428/1266Y10T428/12611Y10T428/1259Y10T428/12583C22C 38/60C22C 38/54C22C 38/50C22C 38/32C22C 38/22C22C 38/20C22C 38/14C21D 8/0247C21D 1/74B32B 15/013C22C 38/28C22C 38/26C22C 38/24C23G 1/08C23G 1/06C23F 17/00C23C 30/005C23C 30/00C22C 38/48C22C 38/46C22C 38/44C22C 38/42C22C 38/40C22C 38/18C22C 38/16C22C 38/12C22C 38/08C22C 38/002C21D 8/0263C21D 8/0236C21D 8/0226B32B 15/18B32B 15/043B32B 15/04C21D 9/46C22C 38/001C22C 38/06C22C 38/04C22C 38/02C23C 2/40C23C 2/06C23C 2/28C23C 2/0222C23C 2/024C23C 2/29C21D 1/76C21D 8/0257C22C 38/38C21D 2211/008C22C 38/34C23C 2/0224C21D 2211/002C21D 2211/005
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Claims

Abstract

The high-strength plated steel sheet of the present invention has a plated layer on the surface of a base steel sheet and contains predetermined steel components. The steel sheet includes, in the order from the interface of the base steel sheet and the plated layer towards the base steel sheet: a soft layer having a Vickers hardness that is 90% or less of the Vickers hardness at a portion t/ 4 of the base steel sheet, where t is a sheet thickness of the base steel sheet: and a hard layer containing martensite, bainite, and ferrite in predetermined ranges. The average depth D of the soft layer is 20 μm or greater, and the average depth d of an internal oxide layer is 4 μm or greater and smaller than D.

Claims

exact text as granted — not AI-modified
1 . A high-strength plated steel sheet, comprising:
 a hot-dip galvanized or galvannealed layer on a surface of a base steel sheet,   wherein
 the base steel sheet comprises, in mass %, 
 C: 0.05 to 0.25%; 
 Si: 0.25 to 3%; 
 Mn: 1.5 to 4%; 
 P: more than 0% to 0.1% or less; 
 S: more than 0% to 0.05% or less; 
 Al: 0.005 to 1%; and 
 N: more than 0% to 0.01% or less, 
 the high-strength plated steel sheet sequentiaih has, from an interface of the base steel sheet and the hot-dip galvanized or galvannealed layer towards the base steel sheet: 
 an internal oxide layer containing at least one oxide selected from the group consisting of Si and Mn; 
 a soft layer including the internal oxide and having a Vickers hardness of 90% less of a Vickers hardness at a portion t/ 4  of the base steel sheet, where t is a sheet thickness of the base steel sheet; and 
 a hard layer containing martensite and bainite in a proportion of from 60 area % or more to less than 95 area %, and polygonal ferrite in a proportion of from more than 5 area % to 40 area % or less, 
   an average depth D of the soft layer is 20 μm or greater,   an average depth d of the internal oxide layer is 4 μm or greater and smaller than the D, and   the high strength plated steel sheet has a tensile strength of 980 MPa or higher.   
     
     
         2 . The high-strength plated steel sheet according to  claim 1 , wherein the base steel sheet further contains, in mass %, at least one of (a) to (c):
 (a) at least one selected from the group consisting of Cr: more than 0% to 1% or less, Mo: more than 0% to 1%, or less and B: more than 0% to 0.01% or less;   (b) at least one selected from the group consisting of Ti: more than 0% to 0.2% or less, Nb: More than 0% to 0.2 or less and V: more than 0% to 0.2% or less; and   (c) at least one selected from the group consisting of Cu: more than 0% to 1% or less and Ni: more than 0% to 1% or less.   
     
     
         3 . The high-strength plated steel sheet according to  claim 1 , wherein the average depth d of the internal oxide layer and the average depth D of the soft layer satisfy D>2d. 
     
     
         4 . The high-strength plated steel sheet according to  claim 2 , wherein the average depth d of the internal oxide layer and the average depth D of the soft layer satisfy D>2d. 
     
     
         5 . A method for producing the high strength plated steel sheet according to  claim 1 , the method comprising:
 coiling, at a temperature of 600° C. or higher, a steel sheet containing, in mass %,
 C: 0.05 to 0.25%, 
 Si: 0.25 to 3%, 
 Mn: 1.5 to 4%, 
 P: more than 0% to 0.1% or less, 
 S: more than 0% to 0.05% or less, 
 Al: 0.005 to 1%, and 
 N: more than 0% to 0.01% or less; 
   subsequently pickling and cold rolling the steel sheet such that the internal oxide layer with the average depth d of 4 μm or more remains;   subsequently oxidizing the steel sheet at an air ratio of 0.9 to 1.4 in an oxidation zone;   subsequently soaking the steel sheet at a temperature of (Ac 1  point +50° C.) to (Ac 3  point 20° C.) in a reduction zone; and   subsequently cooling the steel sheet at an average cooling rate of 5° C./sec or higher down to a cooling stop temperature.   
     
     
         6 . A method for producing the high-strength plated steel sheet according to  claim 1 , the method comprising:
 coiling, at a temperature of 500° C. or higher, a steel sheet containing in mass %.
 C: 0.05 to 0.25%, 
 Si: 0.25 to 3%, 
 Mn: 1.5 to 4%, 
 P: more than 0% to 0.1% or less, 
 S: more than 0% to 0.05% or less, 
 Al: 0.005 to 1%, and 
 N: more than 0% to 0.01% or less: 
   subsequently keeping the steel sheet at a temperature of 500° C. or higher for 80 minutes or longer;   subsequently pickling and cold rolling the steel sheet such that the internal oxide layer with the average depth d of 4 μm or more remains;   subsequently oxidizing the steel sheet at an air ratio of 0.9 to 1.4 in an oxidation zone;   subsequently soaking the steel sheet at a temperature of (Ac 1  point +50° C.) to (Ac 3  point +20° C.) in a reduction zone; and   subsequently cooling the steel sheet at an average cooling rate of 5° C./sec or higher down to a cooling stop temperature.

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