US2017349975A1PendingUtilityA1

Metal alloys including copper

Assignee: ADVANCED ALLOY HOLDINGS PTY LTDPriority: Oct 28, 2014Filed: Oct 27, 2015Published: Dec 7, 2017
Est. expiryOct 28, 2034(~8.3 yrs left)· nominal 20-yr term from priority
C22C 9/06C22F 1/00C22F 1/16C22C 45/00C22C 30/02C22C 2202/02C22C 30/06C22C 30/04C22C 9/02C22C 9/04C22C 9/10C22C 9/01C22C 9/05
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Claims

Abstract

The present invention relates to metal alloys including copper.

Claims

exact text as granted — not AI-modified
1 . An alloy consisting of: 
       
         
           
                 
                 
                 
               
                     
                     
                 
                     
                   Copper 
                   10 to 50 at. % 
                 
                     
                   Nickel 
                   5 to 50 at. % 
                 
                     
                   Manganese 
                   5 to 50 at. % 
                 
                     
                   Zinc 
                   0 to 50 at. % 
                 
                     
                   Aluminium 
                   0 to 40 at. % 
                 
                     
                   Tin 
                   0 to 40 at. % 
                 
                     
                   Chromium 
                   0 to 2 at. % 
                 
                     
                   Iron 
                   0 to 2 at. % 
                 
                     
                   Cobalt 
                   0 to 2 at. % 
                 
                     
                   Lead 
                   0 to 2 at. % 
                 
                     
                   Silicon 
                   0 to 25 at. % 
                 
                     
                     
                 
             
                
               
               
                
                
                
                
                
                
                
                
                
                
                
                
               
            
           
         
         and wherein the alloy has entropy of mixing (ΔS mix ) of at least 1.1R when calculated according to: 
       
       
         
           
             
               
                 
                   
                     
                       Δ 
                        
                       
                           
                       
                        
                       
                         S 
                         mix 
                       
                     
                     = 
                     
                       
                         - 
                         R 
                       
                        
                       
                         
                           ∑ 
                           
                             i 
                             = 
                             1 
                           
                           n 
                         
                          
                         
                             
                         
                          
                         
                           ( 
                           
                             
                               c 
                               i 
                             
                              
                             
                               lnc 
                               i 
                             
                           
                           ) 
                         
                       
                     
                   
                 
                 
                   
                     ( 
                     
                       Equation 
                        
                       
                           
                       
                        
                       1 
                     
                     ) 
                   
                 
               
             
           
         
         where c is the molar percentage of the ith component and R is the gas constant. 
       
     
     
         2 . An alloy as defined in  claim 1 , wherein the alloy includes any one or more of: 
       
         
           
                 
                 
                 
               
                     
                     
                 
                     
                   Aluminium 
                   1 to 30 at. % 
                 
                     
                   Tin 
                   1 to 30 at. % 
                 
                     
                   Zinc 
                   1 to 50 at. % 
                 
                     
                   Silicon 
                   1 to 25 at. % 
                 
                     
                     
                 
             
                
               
               
                
                
                
                
                
               
            
           
         
       
     
     
         3 . An alloy of  claim 1  consisting of: 
       
         
           
                 
                 
                 
               
                     
                     
                 
                     
                   Copper 
                   10 to 50 at. % 
                 
                     
                   Nickel 
                   5 to 50 at. % 
                 
                     
                   Manganese 
                   5 to 50 at. % 
                 
                     
                   Chromium 
                   0 to 2 at. % 
                 
                     
                   Iron 
                   0 to 2 at. % 
                 
                     
                   Cobalt 
                   0 to 2 at. % 
                 
                     
                   Lead 
                   0 to 2 at. %, and one of: 
                 
                     
                   Zinc 
                   1 to 50 at. % 
                 
                     
                   Aluminium 
                   1 to 40 at. % 
                 
                     
                   Tin 
                   1 to 40 at. % or 
                 
                     
                   Silicon 
                   1 to 25 at. % 
                 
                     
                     
                 
             
                
               
               
                
                
                
                
                
                
                
                
                
                
                
                
               
            
           
         
         and wherein the alloy has entropy of mixing (ΔS mix ) of at least 1.1R when calculated according to: 
       
       
         
           
             
               
                 
                   
                     
                       Δ 
                        
                       
                           
                       
                        
                       
                         S 
                         mix 
                       
                     
                     = 
                     
                       
                         - 
                         R 
                       
                        
                       
                         
                           ∑ 
                           
                             i 
                             = 
                             1 
                           
                           n 
                         
                          
                         
                             
                         
                          
                         
                           ( 
                           
                             
                               c 
                               i 
                             
                              
                             
                               lnc 
                               i 
                             
                           
                           ) 
                         
                       
                     
                   
                 
                 
                   
                     ( 
                     
                       Equation 
                        
                       
                           
                       
                        
                       1 
                     
                     ) 
                   
                 
               
             
           
         
         where c is the molar percentage of the ith component and R is the gas constant. 
       
     
     
         4 . An alloy consisting of copper and three alloying elements selected from nickel, manganese, zinc, aluminium and tin and wherein the alloy has entropy of mixing (ΔS mix ) of at least 1.1R when calculated according to: 
       
         
           
             
               
                 
                   
                     
                       Δ 
                        
                       
                           
                       
                        
                       
                         S 
                         mix 
                       
                     
                     = 
                     
                       
                         - 
                         R 
                       
                        
                       
                         
                           ∑ 
                           
                             i 
                             = 
                             1 
                           
                           n 
                         
                          
                         
                             
                         
                          
                         
                           ( 
                           
                             
                               c 
                               i 
                             
                              
                             
                               lnc 
                               i 
                             
                           
                           ) 
                         
                       
                     
                   
                 
                 
                   
                     ( 
                     
                       Equation 
                        
                       
                           
                       
                        
                       1 
                     
                     ) 
                   
                 
               
             
           
         
         where c is the molar percentage of the ith component and R is the gas constant. 
       
     
     
         5 . An alloy comprising copper and three or more alloying elements selected from nickel, manganese, zinc, aluminium and tin and wherein the alloy has entropy of mixing (ΔS mix ) of at least 1.1R when calculated according to: 
       
         
           
             
               
                 
                   
                     
                       Δ 
                        
                       
                           
                       
                        
                       
                         S 
                         mix 
                       
                     
                     = 
                     
                       
                         - 
                         R 
                       
                        
                       
                         
                           ∑ 
                           
                             i 
                             = 
                             1 
                           
                           n 
                         
                          
                         
                             
                         
                          
                         
                           ( 
                           
                             
                               c 
                               i 
                             
                              
                             
                               lnc 
                               i 
                             
                           
                           ) 
                         
                       
                     
                   
                 
                 
                   
                     ( 
                     
                       Equation 
                        
                       
                           
                       
                        
                       1 
                     
                     ) 
                   
                 
               
             
           
         
         where c is the molar percentage of the ith component and R is the gas constant. 
       
     
     
         6 . The alloy defined in  claim 5 , wherein the alloy further comprises one or more alloying elements selected from the group consisting of: 
       
         
           
                 
                 
                 
               
                     
                     
                 
                     
                   Chromium 
                   0 to 2 at. % 
                 
                     
                   Iron 
                   0 to 2 at. % 
                 
                     
                   Cobalt 
                   0 to 2 at. % 
                 
                     
                   Lead 
                   0 to 2 at. % 
                 
                     
                   Silicon 
                   0 to 25 at. % 
                 
                     
                     
                 
             
                
               
               
                
                
                
                
                
                
               
            
           
         
       
     
     
         7 . The alloy defined in any one of  claims 1  to  6 , wherein the alloy has entropy in the range of 1.1R to 2.5R. 
     
     
         8 . The alloy defined in any one of  claims 1  to  6 , wherein the alloy has entropy in the range of 1.3 to 2.0R. 
     
     
         9 . The alloy defined in any one of  claims 1  to  8 , wherein the copper, nickel and manganese are present in substantially equal atomic percentages. 
     
     
         10 . The alloy defined in any one of  claims 1  to  9 , wherein the alloy consists of [Cu+Mn+Ni] 60 to 95 at. % with the balance being Al. 
     
     
         11 . The alloy defined in any one of  claims 1  to  10 , wherein the alloy consists of Cu, Mn, Ni and Al and has an as-cast hardness (H V ) in the range of 154 to 398. 
     
     
         12 . The alloy defined in any one of  claims 1  to  9 , wherein the alloy consists of [Cu+Mn+Ni] 75 to 95 at. % with the balance being Si. 
     
     
         13 . The alloy defined in any one of  claims 1  to  9  or  12 , wherein the alloy consists of Cu, Mn, Ni and Si and has an as-cast hardness (H V ) in the range of 187 to 370. 
     
     
         14 . The alloy defined in any one of  claims 1  to  9 , wherein the alloy consists of [Cu+Mn+Ni] 75 to 95 at. % with the balance being Sn. 
     
     
         15 . The alloy defined in any one of  claims 1  to  9  or  14 , wherein the alloy consists of Cu, Mn, Ni and Sn and has an as-cast hardness (H V ) in the range of 198 to 487. 
     
     
         16 . The alloy defined in any one of  claims 1  to  9 , wherein the alloy consists of [Cu+Mn+Ni] 50 to 95 at. % with the balance being Zn. 
     
     
         17 . The alloy defined in any one of  claims 1  to  9  or  16 , wherein the alloy consists of Cu, Mn, Ni and Zn and has an as-cast hardness (H V ) in the range of 102 to 253. 
     
     
         18 . The alloy defined in any one of  claims 1  to  9 , wherein the alloy is a quinary alloy consisting of [Cu+Mn+Ni] 50 to 95 at. % with the balance being Al and Zn. 
     
     
         19 . The alloy defined in any one of  claims 1  to  9  or  18 , wherein the alloy consists of Cu, Mn, Ni, Al and Zn and has an as-cast hardness (H V ) in the range of 200 to 303. 
     
     
         20 . The alloy defined in any one of  claims 1  to  9 , wherein the alloy is a quinary alloy consisting of [Cu+Mn+Ni] 75 to 90 at. % with the balance being Al and Sn. 
     
     
         21 . The alloy of any one of  claims 1  to  9 , wherein the alloy is a quinary alloy consisting of [Cu+Mn+Ni] 50 to <100 at. % with the balance being Sn and Zn. 
     
     
         22 . The alloy defined in any one of  claim 1  to  9 , wherein the alloy consists of Cu, Mn, Ni, Al, Zn, Sn and comprises a single phase or duplex phase brass. 
     
     
         23 . The alloy defined in any one of  claims 1  to  22 , wherein the alloy has compressive yield strength in the range of 140 to 760 MPa. 
     
     
         24 . The alloy defined in any one of  claims 1  to  23 , wherein the alloy has strain at compressive failure of <2% to 80%.

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