Process for preparing a polyolefin composition

Abstract

A process for continuously preparing a polyolefin composition made from or containing a bimodal or multimodal polyolefin and one or more additives in an extruder device equipped with at least one hopper. The process includes the steps of supplying a bimodal or multimodal polyolefin in form of a polyolefin powder to the hopper; (a) measuring the flow rate of the polyolefin powder or (b) measuring the flow rate of the prepared polyolefin pellets; supplying one or more additives to the hopper; adjusting the flow rates of the additives supplied to the hopper in response to the measured flow rate of the polyolefin powder or adjusting the flow rate of the polyolefin powder in response to the measured flow rate of the polyolefin pellets; melting and homogenizing the polyolefin powder and additives within the extruder device; and pelletizing the molten polyolefin composition into the polyolefin pellets.

1 . A process for continuously preparing polyolefin pellets of a polyolefin composition in an extruder device, comprising:
 (i) supplying a bimodal or multimodal polyolefin at a flow rate as a polyolefin powder to a hopper of the extruder device;   (ii) (a) measuring the flow rate of the polyolefin powder supplied to the hopper or
 (b) measuring a flow rate of the polyolefin pellets prepared in the extruder device; 
   (iii) supplying one or more additives to the same hopper;   (iv) (a) when measuring the flow rate of the polyolefin powder supplied to the hopper, adjusting the flow rates of the additives supplied to the hopper in response to the measured flow rate of the polyolefin powder or
 (b) when measuring the flow rate of the polyolefin pellets prepared in the extruder device, adjusting the flow rate of the polyolefin powder to the hopper in response to the measured flow rate of the polyolefin pellets and either
 (1) keeping the flow rates of the additives supplied to the hopper constant or 
 (2) adjusting the flow rates of the one or more additives supplied to the hopper in response to the measured flow rate of the polyolefin pellets; 
 
   (v) transferring the polyolefin powder and the additives from the hopper into the extruder device;   (vi) melting and homogenizing the polyolefin powder and the additives within the extruder device to form a molten polyolefin composition; and   (vii) pelletizing the molten polyolefin composition, thereby yielding the polyolefin pellets.   
     
     
         2 . The process of  claim 1 , wherein the flow rate of the polyolefin powder is measured. 
     
     
         3 . The process of  claim 1 , wherein the flow rate of the polyolefin pellets prepared in the extruder device is measured. 
     
     
         4 . The process of  claim 2 , wherein the flow rate of the polyolefin powder or the flow rate of the polyolefin pellets is measured by a solids flow meter. 
     
     
         5 . The process of any of  claim 1 , wherein the polyolefin powder is supplied from a storage vessel, into which the polyolefin powder is kept in free flowing state by a discharging aid. 
     
     
         6 . The process of any of  claim 1 , wherein the polyolefin powder and the additives are first supplied to a mixing device, which mixes the polyolefin powder and the additives, and the mixture of polyolefin powder and additives is then transferred from the mixing device to the hopper, and wherein the flow rates of the additives are measured while being supplied to the mixing device and the flow rates of the additives supplied to the mixing device are adjusted in response to the measured flow rate of the polyolefin powder supplied to the mixing device or the flow rates of the additives and the polyolefin powder supplied to the mixing device are adjusted in response to the measured flow rate of the polyolefin pellets. 
     
     
         7 . The process of  claim 6 , wherein the mixing device is a paddle mixer comprising two horizontally orientated counter-rotating shafts. 
     
     
         8 . The process of  claim 1 , wherein the polyolefin powder is transferred from the storage vessel to the hopper by gravity. 
     
     
         9 . The process of  claim 1 , wherein the polyolefin powder is obtained by polymerizing one or more 1-olefins in a cascade of at least two polymerization reactors. 
     
     
         10 . The process of  claim 1 , wherein the polyolefin is a polyethylene. 
     
     
         11 . The process of  claim 10 , wherein the polyethylene is a high density polyethylene having a density determined according to ISO 1183 at 23° C. from about 0.945 to about 0.965 g/cm 3 . 
     
     
         12 . The process of  claim 1 , wherein one of the additives is carbon black. 
     
     
         13 . The process of  claim 12 , wherein the carbon black is fed in form of a carbon black masterbatch. 
     
     
         14 . The process of  claim 1 , further comprising the steps of:
 (viii) supplying polyolefin pellets to the hopper; and   (ix)adjusting the flow rate of the polymer pellets fed to the hopper in response to the measured flow rate of the polyolefin powder or in response to the measured flow rate of the polyolefin pellets.   
     
     
         15 . The process of  claim 1 , wherein the extruder device is selected from the group consisting of a continuous mixer with counter rotating and intermeshing double screw and (b) extruder devices having at least one co-rotating double screw extruder. 
     
     
         16 . The process of  claim 3 , wherein the flow rate of the polyolefin pellets is measured by a solids flow meter. 
     
     
         17 . A process for continuously preparing a polyolefin composition comprising bimodal or multimodal polyolefin and one or more additives in an extruder device equipped with at least one hopper, wherein polyolefin pellets are prepared from the polyolefin composition in the extruder device, the process comprising:
 (i) supplying a bimodal or multimodal polyolefin in form of a polyolefin powder which has been obtained by polymerizing one or more 1-olefins in a cascade of at least two polymerization reactors to the hopper;   (ii) measuring the flow rate of the polyolefin powder supplied to the hopper or measuring a flow rate of the polyolefin pellets prepared in the extruder device;   (iii) supplying one or more additives to the same hopper;   (iv) when measuring the flow rate of the polyolefin powder supplied to the hopper, adjusting the flow rates of the one or more additives supplied to the hopper in response to the measured flow rate of the polyolefin powder or, when measuring the flow rate of the polyolefin pellets prepared in the extruder device, adjusting the flow rate of the polyolefin powder to the hopper in response to the measured flow rate of the polyolefin pellets and either keeping the flow rates of the one or more additives supplied to the hopper constant or also adjusting the flow rates of the one or more additives supplied to the hopper in response to the measured flow rate of the polyolefin pellets;   (v) transferring the polyolefin powder and the additives from the hopper into the extruder device;   (vi) melting and homogenizing the polyolefin powder and additives within the extruder device to form a molten polyolefin composition; and   (vii) pelletizing the molten polyolefin composition.   
     
     
         18 . The process of  claim 17 , wherein the polyolefin is a polyethylene. 
     
     
         19 . The process of  claim 18 , wherein the polyethylene is a high density polyethylene having a density determined according to ISO 1183 at 23° C. from 0.945 to 965 g/cm 3 . 
     
     
         20 . A process for continuously preparing a polyolefin composition comprising bimodal or multimodal polyolefin and one or more additives in an extruder device equipped with at least one hopper, wherein polyolefin pellets are prepared from the polyolefin composition in the extruder device, the process comprising:
 (i) supplying a bimodal or multimodal polyolefin in form of a polyolefin powder to the hopper;   (ii) measuring the flow rate of the polyolefin powder supplied to the hopper or measuring a flow rate of the polyolefin pellets prepared in the extruder device;   (iii) supplying one or more additives to the same hopper;   (iv) when measuring the flow rate of the polyolefin powder supplied to the hopper, adjusting the flow rates of the one or more additives supplied to the hopper in response to the measured flow rate of the polyolefin powder or, when measuring the flow rate of the polyolefin pellets prepared in the extruder device, adjusting the flow rate of the polyolefin powder to the hopper in response to the measured flow rate of the polyolefin pellets and either keeping the flow rates of the one or more additives supplied to the hopper constant or also adjusting the flow rates of the one or more additives supplied to the hopper in response to the measured flow rate of the polyolefin pellets;   (v) transferring the polyolefin powder and the additives from the hopper into the extruder device;   (vi) melting and homogenizing the polyolefin powder and additives within the extruder device to form a molten polyolefin composition;   (vii) pelletizing the molten polyolefin composition;   (viii) supplying polyolefin pellets to the same hopper; and   (ix) adjusting the flow rate of the polymer pellets fed to the hopper in response to the measured flow rate of the polyolefin powder or in response to the measured flow rate of the polyolefin pellets.