System and method for generating a chlorine-containing compound

Abstract

A system ( 10 ) for generating a chlorine-containing compound includes an anodic chamber ( 12 ), a cathodic chamber ( 20 ), and a brine chamber ( 30 ). The anodic chamber ( 12 ) includes an anodic electrode ( 14 ) and the cathodic chamber ( 20 ) includes a cathodic electrode ( 22 ). A membrane ( 28 ) separates the anodic and cathodic chambers ( 12 ), ( 20 ). The brine chamber ( 30 ) includes an anodic electrode ( 32 ) and a cathodic electrode ( 34 ). Concentration and type of the chlorine-containing compound can be selectively and consistently controlled by the system ( 10 ) in real time.

1 . A system for generating a chlorine-containing compound, said system comprising:
 an anodic chamber comprising an anodic electrode and having an inlet and an outlet;   a cathodic chamber spaced from and adjacent said anodic chamber, said cathodic chamber comprising a cathodic electrode and having an inlet and an outlet;   a membrane disposed between and separating said anodic chamber and said cathodic chamber;   a brine chamber having an anodic electrode and a cathodic electrode spaced from said anodic electrode, said brine chamber having an inlet for receiving a first aqueous salt solution and an outlet;   a first power supply coupled to and in electrical communication with said cathodic electrode of said cathodic chamber and said anodic electrode of said anodic chamber;   a second power supply which is the same as or different from said first power supply, said second power supply being coupled to and in electrical communication with said anodic and cathodic electrodes of said brine chamber; and   optionally, a microprocessor coupled to and in electrical communication with at least one of said first and second power supplies for measuring and/or controlling amperage and/or potential difference between said anodic and cathodic electrodes of said brine chamber and/or between said anodic electrode of said anodic chamber and said cathodic electrode of said cathodic chamber;   wherein said outlet of said brine chamber is coupled to and in fluid communication with one of said inlet of said anodic chamber and said inlet of said cathodic chamber;   wherein the other of said inlet of said anodic chamber and said inlet of said cathodic chamber is for receiving a second aqueous salt solution the same as or different from the first aqueous salt solution; and   wherein the chlorine-containing compound is generated in one of said anodic chamber and said cathodic chamber and recovered from one of said outlet of said anodic chamber and said outlet of said cathodic chamber.   
     
     
         2 . A system as set forth in  claim 1  wherein said outlet of said brine chamber is coupled to and in fluid communication with said inlet of said anodic chamber such that the chlorine-containing compound is generated in said anodic chamber and recovered from said outlet of said anodic chamber and wherein the chlorine-containing compound comprises hypochlorous acid. 
     
     
         3 . (canceled) 
     
     
         4 . A system as set forth in  claim 2  wherein the hypochlorous acid has a free available chlorine (FAC) value of from 50 to 5,000 ppm. 
     
     
         5 . (canceled) 
     
     
         6 . A system as set forth in  claim 2  wherein sodium hydroxide is generated in said cathodic chamber and is optionally recovered from said outlet of said cathodic chamber. 
     
     
         7 . A system as set forth in  claim 1  wherein said outlet of said brine chamber is coupled to and in fluid communication with said inlet of said cathodic chamber such that the chlorine-containing compound is generated in said cathodic chamber and wherein the chlorine-containing compound comprises sodium hypochlorite. 
     
     
         8 . (canceled) 
     
     
         9 . A system as set forth in  claim 7  wherein hydrochloric acid is generated in said anodic chamber and is optionally recovered from said outlet of said anodic chamber. 
     
     
         10 . A system as set forth in  claim 1  further comprising a fluid regulator comprising at least one of a flow control regulator, a pressure regulator, and a metering pump for controlling a flow rate of at least one of the first aqueous salt solution and the second aqueous salt solution. 
     
     
         11 . A system as set forth in  claim 1  from any external fluid regulators and/or metering pumps to induce fluid flow such that the system is free from moving parts or components during use of the system and fluid flow is driven via convection. 
     
     
         12 . A system as set forth in  claim 1  wherein said anodic electrode of said anodic chamber and said anodic electrode of said brine chamber each comprise graphite. 
     
     
         13 . A system as set forth in  claim 1  further comprising a brine tank having an outlet coupled to and in fluid communication with said inlet of said brine chamber and coupled to and in fluid communication with one of said inlet of said anodic chamber and said inlet of said cathodic chamber. 
     
     
         14 . A method of generating a chlorine-containing compound in a system which comprises an anodic chamber comprising an anodic electrode and having an inlet and an outlet; a cathodic chamber spaced from and adjacent the anodic chamber, the cathodic chamber comprising a cathodic electrode and having an inlet and an outlet; a membrane disposed between and separating the anodic chamber and the cathodic chamber; a brine chamber having an anodic electrode and a cathodic electrode spaced from the anodic electrode, the brine chamber having an inlet for receiving a first aqueous salt solution and an outlet; a first power supply coupled to and in electrical communication with the cathodic electrode of the cathodic chamber and the anodic electrode of the anodic chamber; a second power supply which is the same as or different from the first power supply, the second power supply being coupled to and in electrical communication with the anodic and cathodic electrodes of the brine chamber; and optionally a microprocessor coupled to and in electrical communication with at least one of the first and second power supplies; wherein the outlet of the brine chamber is coupled to and in fluid communication with one of the inlet of the anodic chamber and the inlet of the cathodic chamber; wherein the other of the inlet of the anodic chamber and the inlet of the cathodic chamber is for receiving a second aqueous salt solution the same as or different from the first aqueous salt solution; and wherein the chlorine-containing compound is generated in one of the anodic chamber and the cathodic chamber and recovered from one of the outlet of the anodic chamber and the outlet of the cathodic chamber; said method comprising the steps of:
 applying an electric potential difference between the anodic electrode of the anodic chamber and the cathodic electrode of the cathodic chamber via the first power supply;   applying an electric potential difference between the anodic and cathodic electrodes of the brine chamber via the second power supply; and   optionally, measuring and/or controlling amperage and/or potential difference between the anodic and cathodic electrodes of the brine chamber and/or between the anodic electrode of the anodic chamber and the cathodic electrode of the cathodic chamber via the microprocessor to generate the chlorine-containing compound.   
     
     
         15 . A method as set forth in  claim 14  wherein the outlet of the brine chamber is coupled to and in fluid communication with the inlet of the anodic chamber such that the chlorine-containing compound is generated in the anodic chamber and recovered from the outlet of the anodic chamber and wherein the chlorine-containing compound comprises hypochlorous acid. 
     
     
         16 . (canceled) 
     
     
         17 . A method as set forth in  claim 15  wherein the hypochlorous acid has a free available chlorine (FAC) value of from 50 to 5,000 ppm. 
     
     
         18 . (canceled) 
     
     
         19 . A method as set forth in  claim 15  wherein sodium hydroxide is generated in the cathodic chamber and is optionally recovered from the outlet of the cathodic chamber. 
     
     
         20 . A method as set forth in  claim 14  wherein the outlet of the brine chamber is coupled to and in fluid communication with the inlet of the cathodic chamber such that the chlorine-containing compound is generated in the cathodic chamber and wherein the chlorine-containing compound comprises sodium hypochlorite. 
     
     
         21 . (canceled) 
     
     
         22 . A method as set forth in  claim 20  wherein hydrochloric acid is generated in the anodic chamber and is optionally recovered from the outlet of the anodic chamber. 
     
     
         23 . A method as set forth in  claim 14  wherein the system further comprises a fluid regulator comprising at least one of a flow control regulator, a pressure regulator, and a metering pump, and wherein said method further comprises the step of controlling flow rate of at least one of the first aqueous salt solution and the second aqueous salt solution. 
     
     
         24 . A method as set forth in  claim 14  wherein the system is free from any external fluid regulators and/or metering pumps to induce fluid flow such that the system is free from moving parts or components during use of the system and fluid flow is driven via convection. 
     
     
         25 . A method as set forth in  claim 14  wherein the anodic electrode of the anodic chamber and the anodic electrode of the brine chamber each comprise graphite.