Shelf life of polyol blends containing halogenated olefins by encapsulation of active components

Abstract

The shelf life of polyurethane polyol pre-blends containing halogenated olefins is extended by encapsulation of active components such as catalysts anti/or surfactants. The active component is encapsulated in a crystallizable or thermoplastic polymer. The encapsulated particles have a size of 2,800 microns or less and the active components are not significantly leaked out, particularly in the presence of halogenated olefins.

1 . A polyol, polyisocyante or isocyante foam formed from a foam premix which exhibits prolonged shelf-life/stability comprising a polyol, polyisocyante or isocyante foam froming component; a surfactant encapsulated in an encapsulating agent; a catalyst encapsulated in an encapsulating agent; a halogenated hydroolefin blowing agent; a carbon dioxide generating agent; and optionally an ester. 
     
     
         2 . The polyol, polyisocyante or isocyante foam of  claim 1 , wherein said encapsulating agent is a thermoplastic or crystallizable polymer. 
     
     
         3 . The polyol, polyisocyante or isocyante foam of  claim 2 , wherein said crystallizable polymer is a side chain crystallizable polmer. 
     
     
         4 . The polyol, polyisocyante or isocyante foam of  claim 3 , wherein said side chain crystallizable polmer is selected from the group consisting of alkyl acrylate and alkyl methacrylate having substituted or unsubstituted side chains of from about 6 to 50 carbons. 
     
     
         5 . The polyol, polyisocyante or isocyante foam of  claim 1 , wherein said surfactant encapsulated in an encapsulating agent and said acatalyst encapsulated in an encapsulating agent have a particle size of about 2800 microns or less. 
     
     
         6 . The polyol, polyisocyante or isocyante foam of  claim 2 , wherein said thermoplastic or crystallizable polymer have a transition point of from about 30° to 250° C. 
     
     
         7 . The polyol, polyisocyante or isocyante foam of  claim 1 , further comprising a co-blowing agentselected from the list consisting of hydrofluorocarbons, hydrofluoroolefins other than said blwoing agent, hydrofluororethers, C1 to C5 alcohols, C1 to C4 aldehydes, C1 to C4 ketones, C1 to C4 ethers, diethers, hydrochlorofluoroolefins other than said blowing agent and mixtures thereof. 
     
     
         8 . The polyol, polyisocyante or isocyante foam of  claim 1 , further comprising a metallic salt selected from the group consisting of alkali earth carboxylates, alkali carboxylates, and carboxylates and mixtures thereof of metals selected from the group consisting of zinc, cobalt, tin, cerium, lanthanum, aluminum, vanadium, manganese, copper, nickel, iron, titanium, zirconium, chromium, scandium, calcium, magnesium, strontium, and barium and mixtures thereof. 
     
     
         9 . The polyol, polyisocyante or isocyante foam of  claim 1 , wherein said catalyst is selected form the group consisting of amine catalysts and metallic compounds. 
     
     
         10 . The polyol, polyisocyante or isocyante foam of  claim 5 , wherein said amine catalyst is sleeted from the group consisting of N-(3-dimethylaminopropyl)-N,N-diisopropanolamine, N,N-bis(3-dimethylaminopropyl)-N-isopropanolamine, 1,3-propanediamine, N′-(3-dimethylamino)propyl-N,N-dimethyl-, triethylenediamine, 1,2-dimethylimidazole, 1,3-propanediamine,N′-(3-(dimethylamino)propyl)-N,N-dimethyl-, N,N,N′N′-tetramethylhexanediamine, N,N″,N″-trimethylaminoethylpiperazine, N,N,N′,N′tetramethylethylenediamine, N,N-dimethylcyclohexylamine (DMCHA), Bis(N,N-dimethylaminoethyl)ether (BDMAFE), 1,4-diazadicyclo[2,2,2]octane (DABCO), 24(2-dimethylaminoethoxy)-ethyl methyl-amino)ethanol, 1-(bis(3-dimethylamino)-propyl)amino-2-propanol, N,N′,N″-tris(3-dimethylamino-propyl)hexahydrotriazine, dimorpholinodiethylether (DMDEE), N.N-dimethylbenzylamine, N,N,N′,N″,N″-pentaamethyldipropylenetriamine, N,N′-diethylpiperazine, dicyclohexylmethylamine, ethyldiisopropylamine, dimethylcyclohexylamine, dimethylisopropylamine, methylisopropylbenzylamine, methylcyclopentylbenzylamine, isopropyl-sec-butyl-trifluoroethylamine, diethyl-(α-phenyethyl)amine, tri-n-propylamine, dicyclohexylamine, t-butylisopropylamine, di-t-butylamine, cyclohexyl-t-butylamine, de-sec-butylamine, dicyclopentylamine, di-(α-trifluoromethylethypamine, di-(α-phenylethyl) amine, triphenylmethylamine, and 1,1-diethyl-n-propylamine, morpholines, imidazoles, dimorpholinodiethylether, N-ethylmorpholine, N-methylmorpholine, bis(dimethylaminoethyl)ether, imidizole, n-methylimidazole, 1,2-dimethylimidazole, dimorpholinodimethylether, N,N,N′,N′,N″,N″-pentamethyldipropylenetriamine, and bis(diethylaminoethyl)ether, bis(dimethylaminopropyl)ether, bis-(2-dimethylaminoethyl)ether; N,N-dimethylethanolamine; N-ethylmorpholine; N-methylmorpholine; N,N,N′-trimethyl-N′-hydroxyethyl-bisaminoethylether; N-(3-dimethylaminopropyl)-N,N-diisopropanolamine; N,N-bis(3-dimethylaminopropyl)-N-isopropanolamine; 2-(2-dimethylaminoethoxy)ethanol; N,N,N′-trimethylaminoethyl-ethanolamine; and 2,2% dimorpholinodiethylether, and mixtures thereof 
     
     
         11 . The polyol, polyisocyante or isocyante foam of  claim 5 , wherein said halogenated hydroolefin blowing agent is selected from the group consisting of hydrofluoroolefins and hydrochlorofluoroolefins. 
     
     
         12 . The polyol, polyisocyante or isocyante foam of  claim 1 , further comprising a stabilizer selected from the group consisting of 1,2-epoxy butane, glycidyl methyl ether, cyclic-terpenes such as dl-limonene, l-limonene, d-limonene, and etc, 1,2-epoxy-2,2-methylpropane, nitromethane, diethylhydroxyl amine, alpha methylstyrene, isoprene, p-methoxyphenol, m-methoxyphenol, dl-limonene oxide, hydrazines, 2,6-di-t-butyl phenol, hydroquinone, organic acids such as carboxylic acid, dicarboxylic acid, phosphonic acid, sulfonic acid, sulfamic acid, hydroxamic acid, formic acid, acetic acid, propionic acid, butyric acid, caproic acid, isocaprotic acid, 2-ethylhexanoic acid, caprylic acid, cyanoacetic acid, pyruvic acid, benzoic acid, oxalic acid, malonic acid, succinic acid, adipic acid, azelaic acid, trifluoroacetic acid, methanesulfonic acid, benzenesulfonic acid and mixtures thereof.