US2017081781A1PendingUtilityA1

Low-temperature selective epitaxial growth of silicon for device integration

Assignee: IBMPriority: Feb 23, 2011Filed: Dec 7, 2016Published: Mar 23, 2017
Est. expiryFeb 23, 2031(~4.6 yrs left)· nominal 20-yr term from priority
H10P 50/242H10P 14/3448H10P 14/3442H10P 14/3411H10P 14/2911H10P 14/2905H10P 14/271H10P 14/24C30B 29/06C30B 25/183C30B 25/186C30B 25/105C30B 25/04C30B 25/14C30B 33/12H01L 21/02395H01L 21/02532H01L 21/02381H01L 21/02639H01L 21/3065H01L 21/0262H01L 21/02584
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Claims

Abstract

An epitaxy method includes providing an exposed crystalline region of a substrate material. Silicon is epitaxially deposited on the substrate material in a low temperature process wherein a deposition temperature is less than 500 degrees Celsius. A source gas is diluted with a dilution gas with a gas ratio of dilution gas to source gas of less than 1000.

Claims

exact text as granted — not AI-modified
What is claimed is: 
     
         1 . An epitaxy method, comprising:
 providing a crystalline substrate material;   growing an insulator on the substrate material;   opening the insulator to form exposed areas of the substrate material;   depositing silicon on the exposed areas of the substrate material to form epitaxial silicon on the exposed areas and form non-epitaxial silicon in other than the exposed areas in a low temperature process wherein a deposition temperature is less than 500 degrees Celsius; and   etching the non-epitaxial silicon using a plasma to further epitaxial deposition of silicon over the exposed areas, wherein the steps of depositing and etching are concurrently performed.   
     
     
         2 . The method as recited in  claim 1 , wherein depositing silicon includes a radio frequency or direct current plasma enhanced chemical vapor deposition process. 
     
     
         3 . The method as recited in  claim 1 , wherein depositing silicon includes diluting a source gas with a dilution gas including at least one of H 2 , HCl, Cl 2  and Ar with a gas ratio of dilution gas to source gas of less than 1000, wherein the source gas includes one of SiH 4 , dichlorosilane (DCS), SiF 4  or SiCl 4 . 
     
     
         4 . The method as recited in  claim 3 , wherein diluting include diluting SiH 4  with at least one of H 2  with a gas ratio of over 5. 
     
     
         5 . The method as recited in  claim 1 , wherein the deposition temperature is less than 250 degrees Celsius. 
     
     
         6 . The method as recited in  claim 1 , wherein the substrate material includes one of Si, Ge, and III-V materials. 
     
     
         7 . The method as recited in  claim 1 , further comprising introducing a dopant with a gas ratio which provides a doped epitaxial silicon. 
     
     
         8 . The method as recited in  claim 7 , wherein the doped epitaxial silicon includes at least one of carbon, germanium, phosphorus, arsenic or boron. 
     
     
         9 . The method as recited in  claim 1 , wherein the plasma includes at least one of H 2 , HCl, Cl 2  or Ar. 
     
     
         10 . An epitaxy method, comprising:
 providing a crystalline substrate material;   growing an insulator on the substrate material;   opening the insulator to form exposed areas of the substrate material; and   depositing silicon on the exposed areas of the substrate material to form epitaxial silicon on the exposed areas areas in a low temperature process wherein a deposition temperature is less than 500 degrees Celsius concurrently with etching non-epitaxial silicon using a plasma.   
     
     
         11 . The method as recited in  claim 10 , wherein depositing silicon includes a radio frequency or direct current plasma enhanced chemical vapor deposition process. 
     
     
         12 . The method as recited in  claim 10 , wherein depositing silicon includes diluting a source gas with a dilution gas including at least one of H 2 , HCl, Cl 2  and Ar with a gas ratio of dilution gas to source gas of less than 1000, wherein the source gas includes one of SiH 4 , dichlorosilane (DCS), SiF 4  or SiCl 4 . 
     
     
         13 . The method as recited in  claim 12 , wherein diluting include diluting SiH 4  with at least one of H 2  with a gas ratio of over 5. 
     
     
         14 . The method as recited in  claim 10 , wherein the deposition temperature is less than 250 degrees Celsius. 
     
     
         15 . The method as recited in  claim 10 , wherein the substrate material includes one of Si, Ge, and III-V materials. 
     
     
         16 . The method as recited in  claim 10 , further comprising introducing a dopant with a gas ratio which provides a doped epitaxial silicon. 
     
     
         17 . The method as recited in  claim 16 , wherein the doped epitaxial silicon includes at least one of carbon, germanium, phosphorus, arsenic or boron. 
     
     
         18 . The method as recited in  claim 10 , wherein the plasma includes at least one of H 2 , HCl, Cl 2  or Ar. 
     
     
         19 . An epitaxy method, comprising:
 forming an insulator having an opening exposing a portion of an underlying crystalline material;   depositing silicon on the exposed areas of the crystalline material to form epitaxial silicon on the exposed areas and form non-epitaxial silicon in other than the exposed areas in a low temperature process wherein a deposition temperature is less than 500 degrees Celsius; and   etching the non-epitaxial silicon using a plasma to further epitaxial deposition of silicon over the exposed areas, wherein the steps of depositing and etching are concurrently performed.   
     
     
         20 . The epitaxy method of  claim 19 , wherein the plasma includes at least one of H 2 , HCl, Cl 2  or Ar.

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