Divalent Cation Removal From Rich Monoethylene Glycol (MEG) Feed Streams By Ion Exchange

Abstract

A system and process for removing divalent cations from a rich MEG feed stream is presented. An ion exchange bed containing a cation exchange resin adsorbs the divalent cations in the rich MEG feed stream as it flows through the ion exchange bed. After the divalent ions have been removed, the feed stream flows through a flash separator and a distillation column to reclaim MEG. Alternatively, the feed stream flows through a distillation column to regenerate MEG. The spent cation exchange resin may be regenerated in place using a regeneration brine comprised of sodium chloride and water. After use, the regeneration brine may be disposed as waste or recycled to the brine storage tank and re-used to regenerate the cation exchange resin.

What is claimed is: 
     
         1 . A system for removing divalent cations from a rich MEG feed stream, the system comprising:
 an ion exchange bed through which the rich MEG feed stream flows, the ion exchange bed containing a cation exchange resin that adsorbs the divalent cations in the rich MEG feed stream.   
     
     
         2 . A system according to  claim 1  further comprising a flash separator followed by a distillation column for reclaiming MEG from the rich MEG feed stream after the divalent cations have been removed. 
     
     
         3 . A system according to  claim 1  further comprising a distillation column for regenerating MEG from the rich MEG feed stream after the divalent cations have been removed. 
     
     
         4 . A system according to  claim 1  wherein a regeneration brine is used to regenerate the cation exchange resin without removing it from the ion exchange bed. 
     
     
         5 . A system according to  claim 4  wherein the regeneration brine is comprised of sodium chloride produced as the rich MEG feed stream is treated in the flash separator. 
     
     
         6 . A system according to  claim 4  wherein the regeneration brine is comprised of water produced as the rich MEG feed stream is treated in the distillation column. 
     
     
         7 . A system according to  claim 4  wherein the regeneration brine is held in a brine storage tank before it flows through the ion exchange bed. 
     
     
         8 . A system according to  claim 4  wherein the regeneration brine is routed to the brine storage tank after it flows through the ion exchange bed and re-used to regenerate the cation exchange resin. 
     
     
         9 . A process for removing divalent cations from a rich MEG feed stream, the process comprising the steps of:
 providing an ion exchange bed containing a cation exchange resin; and   passing the rich MEG feed stream through the ion exchange bed where the divalent cations are adsorbed by the cation exchange resin.   
     
     
         10 . A process according to  claim 9  further comprising the step of MEG reclamation, wherein the rich MEG feed stream from the ion exchange bed is passed through a flash separator followed by a distillation column to yield lean MEG and distilled water. 
     
     
         11 . A process according to  claim 9  further comprising the step of MEG regeneration, wherein the rich MEG feed stream from the ion exchange bed is passed through a distillation column to yield lean MEG and water vapor. 
     
     
         12 . A process according to  claim 9  further comprising the step of regenerating the cation exchange resin by passing a regeneration brine through the ion exchange bed in a direction opposite that of the rich MEG feed stream. 
     
     
         13 . A process according to  claim 12  wherein the regeneration brine is held in a brine storage tank before it flows through the ion exchange bed. 
     
     
         14 . A process according to  claim 12  wherein the regeneration brine is comprised of sodium chloride produced as the rich MEG feed stream is treated in the flash separator. 
     
     
         15 . A process according to  claim 12  wherein the regeneration brine is comprised of water produced as the rich MEG feed stream is treated in the distillation column. 
     
     
         16 . A process according to  claim 12  further comprising the step of routing the regeneration brine to the brine storage tank after it has flowed through the ion exchange bed and re-using it to regenerate the cation exchange resin.