Continuous electrodeposition of a coating on metal sheet stock

Abstract

Electrodeposition of coil metal sheet stock using an aqueous dispersion of a poly(urethane-carbonate) is disclosed. The coated sheet stock can be used in forming coated metal cans.

What is claimed is: 
     
         1 . A method for electrocoating a continuous length of flat metal sheet comprising:
 (a) withdrawing the flat metal sheet from a supply source and continuously   (b) passing the sheet into an aqueous electrodeposition bath that contains as an electrocoating vehicle a salt of a poly(urethane-carbonate),   (c) electrodepositing a coating of a poly(urethane-carbonate) as the sheet passes through the electrodeposition bath to form a coated sheet,   (d) passing the coated sheet through a curing station to form a cured coating,   (e) leading the sheet with the cured coating to a point of accumulation.   
     
     
         2 . The method of  claim 1  in which the flat metal sheet is aluminum or steel. 
     
     
         3 . The method of  claim 1  in which the poly(urethane-carbonate) is prepared by reacting a polyisocyanate with a polycarbonate polyol. 
     
     
         4 . The method of  claim 1  in which the polycarbonate polyol is a diol. 
     
     
         5 . The method of  claim 4  in which the polycarbonate diol has an M n  of 500-5000. 
     
     
         6 . The method of  claim 4  in which the polycarbonate diol is an alkyl-substituted or an alkoxy-substituted 1,3-propanediol. 
     
     
         7 . The method of  claim 4  in which the alkyl-substituted 1,3-propanediol is selected from the class consisting of 2-alkyl-1,3-propanediol and 2,2-dialkyl-1,3-propanediol. 
     
     
         8 . The method of  claim 7  in which the alkyl contains from 1 to 8 carbon atoms. 
     
     
         9 . The method of  claim 7  in which the alkyl is selected from ethyl and butyl. 
     
     
         10 . The method of  claim 3  in which the polyisocyanate is a cycloaliphatic diisocyanate. 
     
     
         11 . The method of  claim 3  in which the poly(urethane-carbonate) is prepared by reacting an isocyanate prepolymer comprising the reaction product of:
 (a) a polyisocyanate, 
 (b) a polycarbonate diol, 
 (c) an isocyanate group reactive compound comprising one or more ionic groups or potential ionic groups per molecule, 
 (d) a chain extender that is reactive with isocyanate groups, and 
 (e) optionally a neutralizing agent that reacts with potential ionic groups of the poly(urethane-carbonate) to form ionic groups. 
 
     
     
         12 . The method of  claim 11  in which the reaction product is prepared in aqueous medium. 
     
     
         13 . The method of  claim 11  in which the polyisocyanate is a cycloaliphatic diisocyanate. 
     
     
         14 . The method of  claim 11  in which the chain extender is a cycloaliphatic diamine. 
     
     
         15 . The method of  claim 11  in which the chain extender is isophorone diamine. 
     
     
         16 . The method of  claim 11  in which the poly(urethane-carbonate) has a number average molecular weight of at least 15,000. 
     
     
         17 . The method of  claim 1  in which the electrodeposition bath is substantially free of bisphenol A and derivatives thereof. 
     
     
         18 . The method of  claim 1  in which the coated metal sheet is taken from the point of accumulation, cut into metal blanks and the blanks formed into a food or beverage can or portion thereof. 
     
     
         19 . The method of  claim 18  wherein the sheet is formed into a can end or a can body. 
     
     
         20 . The method of  claim 18  wherein the can is a two-piece drawn food or beverage can, a three-piece food or beverage can, a food or beverage can end, a drawn and ironed food or beverage can. 
     
     
         21 . An article comprising:
 (a) a metal food or beverage container including a portion thereof, and   (b) a coating composition applied to a surface of the container, the coating composition comprising an aqueous poly(urethane-carbonate) dispersion.   
     
     
         22 . The article of  claim 21  in which the coating composition is applied to the interior surface of a food or beverage container including a portion thereof. 
     
     
         23 . The article of  claim 21  in which the metal is aluminum or steel. 
     
     
         24 . The article of  claim 21  in which the poly(urethane-carbonate) is prepared by reacting a polyisocyanate with a polycarbonate polyol. 
     
     
         25 . The article of  claim 21  in which the polycarbonate polyol is a diol. 
     
     
         26 . The article of  claim 25  in which the polycarbonate diol has an M n  of 500-5000. 
     
     
         27 . The article of  claim 25  in which the polycarbonate diol is an alkyl-substituted or an alkoxy-substituted 1,3-propanediol. 
     
     
         28 . The article of  claim 25  in which the alkyl-substituted 1,3-propanediol is selected from the class consisting of 2-alkyl-1,3-propanediol and 2,2-dialkyl-1,3-propanediol. 
     
     
         29 . The article of  claim 28  in which the alkyl contains from 1 to 8 carbon atoms. 
     
     
         30 . The article of  claim 28  in which the alkyl is selected from ethyl and butyl. 
     
     
         31 . The article of  claim 21  in which the poly(urethane-carbonate) is prepared by reacting an isocyanate prepolymer comprising the reaction product of:
 (a) a polyisocyanate, 
 (b) a polycarbonate diol, 
 (c) an isocyanate group reactive compound comprising one or more ionic groups or potential ionic groups per molecule, 
 (d) a chain extender that is reactive with isocyanate groups, and 
 (e) optionally a neutralizing agent that reacts with potential ionic groups of the poly(urethane-carbonate) to form ionic groups.