Functionalizing cellulosic and lignocellulosic materials

Abstract

Irradiated lignocellulosic or cellulosic materials are provided which contain carboxylic acid groups and/or other functional groups not present in a naturally occurring cellulosic or lignocellulosic material from which the irradiated material was obtained

What is claimed is: 
     
         1 . A method comprising:
 irradiating a lignocellulosic or cellulosic material with less than 10 Mrad of electron beam radiation, electrons in the electron beam having an energy of from about 0.7 to 2.0 MeV, to provide an irradiated lignocellulosic or cellulosic material having a functionality different from that of the cellulosic or lignocellulosic material from which the irradiated material was obtained.   
     
     
         2 . The method of  claim 1  wherein the treated material comprises functional groups selected from the group consisting of carboxylic acid groups, aldehyde groups, nitroso groups, nitrile groups, nitro groups, ketone groups, amino groups, alkyl amino groups, alkyl groups, chloroalkyl groups, chlorofluoroalkyl groups, and enol groups. 
     
     
         3 . The method of  claim 1  wherein the cellulosic or lignocellulosic material is selected from the group consisting of wood, paper, and textile fibers. 
     
     
         4 . The method of  claim 1 , wherein the irradiated material comprises a mixture of nitrile groups and carboxylic acid groups. 
     
     
         3 . The method of  claim 1  wherein the naturally occurring lignocellulosic fibrous material has a lignin content of at least 2%. 
     
     
         4 . The method of  claim 1  wherein the lignocellulosic material comprises a fibrous material. 
     
     
         5 . The method of  claim 1  wherein the irradiated lignocellulosic material comprises a plurality of saccharide units arranged in a molecular chain, wherein from about 1 out of every 2 to about 1 out of every 250 saccharide units comprises a carboxylic acid group, or an ester or salt thereof, wherein the number of carboxylic acid groups is determined by titration. 
     
     
         6 . The method of  claim 5 , wherein the material includes a plurality of said molecular chains. 
     
     
         7 . The method of  claim 6 , wherein each chain comprises hemicellulose or cellulose. 
     
     
         8 . The method of  claim 6 , wherein from about 1 out of every 10 to about 1 out of every 1000 saccharide units of each chain comprises a nitroso, nitro, or nitrile group. 
     
     
         9 . The method of  claim 6 , wherein from about 1 out of every 35 to about 1 out of every 750 saccharide units of each chain comprises a nitroso, nitro, or nitrile group. 
     
     
         10 . The method of  claim 5 , wherein from about 1 out of every 5 to about 1 out of every 250 saccharide units of each chain comprises a carboxylic acid group, or an ester or salt thereof. 
     
     
         11 . The method of  claim 5 , wherein from about 1 out of every 8 to about 1 out of every 100 saccharide units of each chain comprises a carboxylic acid group, or an ester or salt thereof. 
     
     
         12 . The method of  claim 5 , wherein from about 1 out of every 10 to about 1 out of every 50 saccharide units of each chain comprise a carboxylic acid group, or an ester or salt thereof. 
     
     
         13 . The method of  claim 5 , wherein the saccharide units comprise 5 or 6 carbon saccharide units. 
     
     
         14 . The method of  claim 5 , wherein each chain has between about 10 and about 200 saccharide units. 
     
     
         15 . The method of  claim 5 , wherein the average molecular weight of the material relative to PEG standards is from about 1,000 to about 1,000,000, wherein the molecular weight is determined using GPC, utilizing a saturated solution (8.4% by weight) of lithium chloride (LiCl) in dimethyl acetamide (DMAc) as the mobile phase. 
     
     
         16 . The method of  claim 5 , wherein from about 1 out of every 5 to about 1 out of every 1500 saccharide units comprises a nitroso, nitro, or nitrile group.