Polycrystalline diamond and manufacturing method thereof, scribe tool, scribing wheel, dresser, rotating tool, orifice for water jet, wiredrawing die, cutting tool, and electron emission source

Abstract

Nano polycrystalline diamond is composed of carbon, an element of different type which is an element other than carbon and is added to be dispersed in carbon at an atomic level, and an inevitable impurity. The polycrystalline diamond has a crystal grain size not greater than 500 nm. The polycrystalline diamond can be fabricated by subjecting graphite in which the element of different type which is an element other than carbon has been added to be dispersed in carbon at an atomic level to heat treatment within high-pressure press equipment.

1 .- 4 . (canceled) 
     
     
         5 . A method for manufacturing polycrystalline diamond, comprising the steps of:
 preparing graphite that an element of different type which is an element other than carbon is added to be dispersed in carbon at an atomic level; and   converting said graphite to diamond by subjecting said graphite to heat treatment within high-pressure press equipment.   
     
     
         6 . The method for manufacturing polycrystalline diamond according to  claim 5 , wherein
 in said step of converting said graphite to diamond, said graphite is subjected to heat treatment within said high-pressure press equipment without adding a sintering aid or a catalyst.   
     
     
         7 . The method for manufacturing polycrystalline diamond according to  claim 5 , wherein
 said step of preparing graphite includes the step of forming graphite on a base material by introducing a gas mixture of a gas containing said element of different type and a hydrocarbon gas within a vacuum chamber and thermally decomposing said gas mixture at a temperature not lower than 1500° C.   
     
     
         8 . The method for manufacturing polycrystalline diamond according to  claim 7 , wherein
 in said step of converting said graphite to diamond, said graphite formed on said base material is subjected to heat treatment within said high-pressure press equipment.   
     
     
         9 . The method for manufacturing polycrystalline diamond according to  claim 7 , wherein
 said gas mixture is fed toward a surface of said base material.   
     
     
         10 . The method for manufacturing polycrystalline diamond according  claim 7 , wherein
 said hydrocarbon gas is a methane gas.   
     
     
         11 .- 14 . (canceled) 
     
     
         15 . A method for manufacturing polycrystalline diamond, comprising the steps of:
 preparing graphite that a group III element is added to be dispersed in carbon at an atomic level; and   converting said graphite to diamond by subjecting said graphite to heat treatment within high-pressure press equipment.   
     
     
         16 . The method for manufacturing polycrystalline diamond according to  claim 15 , wherein
 in said step of converting said graphite to diamond, said graphite is subjected to heat treatment within said high-pressure press equipment without adding a sintering aid or a catalyst.   
     
     
         17 . The method for manufacturing polycrystalline diamond according to  claim 15 , wherein
 said step of preparing graphite includes the step of forming graphite on a base material by introducing a gas mixture of a gas containing said group III element and a hydrocarbon gas within a vacuum chamber and thermally decomposing said gas mixture at a temperature not lower than 1500° C.   
     
     
         18 . The method for manufacturing polycrystalline diamond according to  claim 17 , wherein
 in said step of converting said graphite to diamond, said graphite formed on said base material is subjected to heat treatment at a high pressure not lower than 8 GPa and at 1500° C. or higher.   
     
     
         19 . The method for manufacturing polycrystalline diamond according to  claim 17 , wherein
 said gas mixture is fed toward a surface of said base material.   
     
     
         20 . The method for manufacturing polycrystalline diamond according to  claim 17 , wherein
 said hydrocarbon gas is a methane gas.   
     
     
         21 .- 31 . (canceled) 
     
     
         32 . A method for manufacturing polycrystalline diamond, comprising the steps of:
 preparing graphite that a group V element is added to be dispersed in carbon at an atomic level, which has a crystal grain size not greater than 10 μm; and   converting said graphite to diamond by subjecting said graphite to heat treatment within high-temperature and high-pressure press equipment.   
     
     
         33 . The method for manufacturing polycrystalline diamond according to  claim 32 , wherein
 in said step of converting said graphite to diamond, said graphite is subjected to heat treatment within said high-temperature and high-pressure press equipment without adding a sintering aid or a catalyst.   
     
     
         34 . The method for manufacturing polycrystalline diamond according to  claim 32 , wherein
 said step of preparing graphite includes the step of forming graphite on a base material by introducing a gas mixture of a gas containing said group V element and a hydrocarbon gas within a vacuum chamber and thermally decomposing said gas mixture at a temperature not lower than 1500° C.   
     
     
         35 . The method for manufacturing polycrystalline diamond according to  claim 34 , wherein
 in said step of converting said graphite to diamond, said graphite formed on said base material is subjected to heat treatment within said high-temperature and high-pressure press equipment.   
     
     
         36 . The method for manufacturing polycrystalline diamond according to  claim 34 , wherein
 said gas mixture is fed toward a surface of said base material.   
     
     
         37 . The method for manufacturing polycrystalline diamond according  claim 34 , wherein
 said hydrocarbon gas is a methane gas.   
     
     
         38 . (canceled)