Polycarbonate compositions having improved adhesion to polyurethane layers

Abstract

The present invention relates to compositions and composite components formed from these compositions and a polyurethane layer, which are notable for improved adhesion between the two layers, and a process for producing the composite components.

1 . A composition omprising
 A) 55 to 75 parts by weight of at least one polymer selected from the group consisting of aromatic polycarbonate and aromatic polyester carbonate,   B) 25 to 45 parts by weight of at least one mixture comprising at least one polybutadiene-based graft polymer prepared by emulsion, suspension or solution polymerization and at least one polybutadiene-free vinyl (co)polymer,   C) 0.1 to 20.0 parts by weight (based in each case on the sum total of components A and B) of at least one polymer additive,   where the polybutadiene content based on the sum total of the parts by weight of components A and B is 10% to 20% by weight,   and where the total content of butadiene-free vinyl (co)polymer from component B based on the sum total of the parts by weight of components A and B is 12% to 23% by weight, and where the sum total of the parts by weight of components A and B in the polycarbonate composition is normalized to 100.   
     
     
         2 . A composition according to  claim 1 , wherein the butadiene-based graft polymer of Component B is prepared by emulsion polymerization. 
     
     
         3 . A composition according to  claim 1 , wherein the polybutadiene-based graft polymer comprises
 B.1 5% to 95% by weight, based on the graft polymer, of at least one vinyl monomer on   B.2 95% to 5% by weight, based on the graft polymer, of one or more polybutadiene graft bases.   
     
     
         4 . A composition according to  claim 3 , wherein component B.1 comprises mixtures of
 B.1.1 50% to 99% by weight, based on B.1, of vinylaromatics and/or ring-substituted vinylaromatics (optionally styrene, α-methylstyrene, p-methylstyrene, p-chlorostyrene) and   B.1.2 1% to 50% by weight, based on B.1, of vinyl cyanides (unsaturated nitriles optionally acrylonitrile and methacrylonitrile) and/or derivatives (optionally anhydrides and imides) of unsaturated carboxylic acids, optionally maleic anhydride and N-phenylmaleimide.   
     
     
         5 . A composition according to  claim 1  wherein,
 57 to 74 parts by weight of component A); 26 to 43 parts by weight of component B); 0.2 to 15.0 parts by weight of component C); 
 where the polybutadiene content based on the sum total of the parts by weight of components A and B is 11% to 18% by weight 
 and where the total content of butadiene-free vinyl (co)polymer from component B, based on the sum total of the parts by weight of components A and B, is 12% to 20% by weight, 
 and where the sum total of the parts by weight of components A and B in the polycarbonate composition has been normalized to 100. 
 
     
     
         6 . A composition according to  claim 1 , wherein
 64 to 73 parts by weight of component A); 27 to 36 parts by weight of component B); 0.3 to 10.0 parts by weight of component C);   where the polybutadiene content based on the sum total of the parts by weight of components A and B is 12% to 17% by weight   and where the total content of butadiene-free vinyl (co)polymer from component B, based on the sum total of the parts by weight of components A and B, is 13% to 19% by weight,   and where the sum total of the parts by weight of components A and B in the polycarbonate composition has been normalized to 100.   
     
     
         7 . A composition according to  claim 1   wherein component C comprises at least one polymer additive selected from the group consisting of thermal stabilizers, demoulding agents, colourants and UV absorbers.   
     
     
         8 . A composite component comprising
 a) a carrier composed of a thermoplastic composition according to  claim 1     b) at least one polyurethane layer selected from the group consisting of coating materials, foams and compact skins, comprising   at least one polyisocyanate component,   least one polyfunctional H-active compound, and   optionally at least one polyurethane additive and/or processing aid,   and having a molar ratio of NCO- to H-active groups of 1:1 to 1.1:1.   
     
     
         9 . A composite component according to  claim 8 , wherein the polyurethane layer is a coating material having a layer thickness of 50-300 μm. 
     
     
         10 . A composite component according to  claim 8 , wherein the polyurethane layer is a foam having a layer thickness of 1 mm to 1 cm. 
     
     
         11 . A composite component according to  claim 8 , wherein the polyurethane layer is a compact skin having a layer thickness of 1 mm to 4 mm. 
     
     
         12 . A process for producing a composite component according to  claim 8 , wherein the polyurethane layer has been produced by full polymerization of a reactive polyurethane raw material mixture comprising
 at least one polyisocyanate component,   at least one polyfunctional H-active compound, and   optionally at least one polyurethane additive and/or processing aid, in direct contact with the carrier which has been shaped beforehand from the thermoplastic composition and solidified.   
     
     
         13 . A process for producing a composite component according to  claim 8 , wherein
 (i) the melt of the thermoplastic composition is injected into a first mould cavity and then cooled,   (ii) the cooled thermoplastic component is transferred into a larger cavity and a defined gap is produced thereby,   (iii) the gap which thus results between the thermoplastic component and the mould surface of the enlarged cavity is injected with a reactive polyurethane raw material mixture comprising   at least one polyisocyanate component,   at least one polyfunctional H-active compound, and   optionally at least one polyurethane additive and/or processing aid,   the polyurethane raw material mixture polymerizing fully in direct contact with the surface of the thermoplastic carrier to give a compact polyurethane layer or to give a polyurethane foam layer,   (iv) the composite component is demoulded from the mould cavity, and wherein (i) to (iv) following one another in immediate succession.   
     
     
         14 . A process according to  claim 13 , wherein in (iii) the surface of the injection mould in contact with the thermoplastic composition is heated to a temperature in the range of 60 to 90° C. and the surface of the injection mould in contact with the reactive polyurethane mixture to a temperature in the range of 60 to 90° C. 
     
     
         15 . A composite component according to  claim 8  capable of being used as an interior or exterior component of a rail vehicle, aircraft or motor vehicle and for electrical/electronic components and IT components.