Methods of making saccharide siloxane copolymers

Abstract

A method of making a saccharide siloxane copolymer includes reacting an amine functional saccharide with an epoxy functional silane containing at least one condensable or hydrolysable group. This product is reacted with an oligomer to form the saccharide siloxane copolymer.

What is claimed is: 
     
         1 . A method of making a saccharide siloxane copolymer, the method comprising:
 (a) reacting an amine functional saccharide with an epoxy functional silane containing at least one condensable or hydrolysable group, the epoxy functional silane containing at least one condensable or hydrolysable group being an amino radical, a ketoxime, an ureido group, an acetoxy group, a carboxyl group, a carboxylic amide radical, a cyano group, isocyanate group, sulfate group, sulfate ester group, phosphate group, or a phosphate ester group;   (b) reacting the product of step (a) with an oligomer to form the saccharide siloxane copolymer; and   (c) optionally, further including an endcapper to form the saccharide siloxane copolymer.   
     
     
         2 . The method of  claim 1 , wherein the amine functional saccharide is selected from the group consisting of N-methylglucamine, N-ethylglucamine and mixtures thereof. 
     
     
         3 . The method of  claim 1 , wherein the amine functional saccharide is selected from the group consisting of glucosamine, galactosamine, muramic acid, mannosamine, chitosan, a chitosan monomer, a chitosan oligomer, meglumine or mixtures thereof. 
     
     
         4 . The method of  claim 1 , wherein the epoxy functional silane containing at least one condensable or hydrolysable group is a glycidoxypropyl functional silane. 
     
     
         5 . The method of  claim 1 , wherein the epoxy functional silane containing at least one condensable or hydrolysable group is an epoxycyclohexylethyl functional silane, an epoxy alkane or a limonene epoxide functional silane. 
     
     
         6 . The method of  claim 1 , further including an endcapper to form the saccharide siloxane copolymer, the endcapper being trimethyl alkoxysilane. 
     
     
         7 . The method of  claim 1 , wherein the oligomer is a partially capped siloxane. 
     
     
         8 . The method of  claim 1 , wherein the oligomer is a cyclic siloxane or a disilanol siloxane. 
     
     
         9 . The method of  claim 1 , wherein step (b) includes reacting the product of step (a) with capped and uncapped oligomers. 
     
     
         10 . The method of  claim 1 , wherein step (b) includes reacting the product of step (a) with a silane endcapper and an uncapped oligomer. 
     
     
         11 . The method of  claim 1 , wherein the saccharide siloxane copolymer is an emulsion. 
     
     
         12 . The method of  claim 1 , wherein step (b) further includes using an acid or base catalyst. 
     
     
         13 . A method of making a saccharide siloxane copolymer, the method comprising:
 (a) reacting N-methylglucamine, N-ethylglucamine or a mixture thereof with an epoxy functional silane containing at least one condensable or hydrolysable group being an amino radical, a ketoxime, an ureido group, an acetoxy group, a carboxyl group, a carboxylic amide radical, a cyano group, isocyanate group, sulfate group, sulfate ester group, phosphate group, or a phosphate ester group; and   (b) reacting the product of step (a) with a disilanol oligomer to form the saccharide siloxane copolymer.   
     
     
         14 . The method of  claim 2 , wherein the amine functional saccharide includes N-methylglucamine. 
     
     
         15 . The method of  claim 2 , wherein the amine functional saccharide includes M-ethylglucamine. 
     
     
         16 . The method of  claim 1 , wherein the reaction of step (a) is performed in a polar solvent. 
     
     
         17 . The method of  claim 16 , wherein the polar solvent includes methanol, ethanol, isopropanol, or any combination thereof. 
     
     
         18 . The method of  claim 1 , further including an endcapper to form the saccharide siloxane copolymer.