Inks comprising liquid rubber for 3d printing

Abstract

In one aspect, inks for use with a three-dimensional printing system are described herein. In some embodiments, an ink described herein comprises up to about 90 wt. % monofunctional curable material, up to about 10 wt. % difunctional curable material, and up to about 10 wt. % liquid rubber, based on the total weight of the ink, wherein the liquid rubber comprises one or more curable moieties. In some cases, the liquid rubber comprises one or more ethyleneically unsaturated moieties. For example, in some instances, the liquid rubber comprises a butadiene acrylonitrile copolymer.

1 . An ink for use in a three-dimensional printing system comprising:
 up to 90 wt. % monofunctional curable material;   up to 10 wt. % difunctional curable material; and   up to 10 wt. % liquid rubber, based on the total weight of the ink, wherein the liquid rubber comprises one or more curable moieties.   
     
     
         2 . The ink of  claim 1 , wherein the monofunctional curable material comprises one or more species of (meth)acrylates. 
     
     
         3 . The ink of  claim 1 , wherein the monofunctional curable material is present in the ink in an amount of 70-90 wt. %, based on the total weight of the ink. 
     
     
         4 . The ink of  claim 1 , wherein the difunctional curable material comprises one or more species of (meth)acrylates. 
     
     
         5 . The ink of  claim 1 , wherein the difunctional curable material is present in the ink in an amount of 3-7 wt. %, based on the total weight of the ink. 
     
     
         6 . The ink of  claim 1 , wherein the liquid rubber comprises one or more ethyleneically unsaturated moieties. 
     
     
         7 . The ink of  claim 1 , wherein the liquid rubber comprises a butadiene acrylonitrile copolymer. 
     
     
         8 . The ink of  claim 1 , wherein the butadiene acrylonitrile copolymer has an acrylonitrile content of 18-26%. 
     
     
         9 . The ink of  claim 1 , wherein the butadiene acrylonitrile copolymer is carboxylic acid terminated. 
     
     
         10 . The ink of  claim 1 , wherein the butadiene acrylonitrile copolymer is amine terminated. 
     
     
         11 . The ink of  claim 1 , wherein the butadiene acrylonitrile copolymer is vinyl terminated. 
     
     
         12 . The ink of  claim 1 , wherein the butadiene acrylonitrile copolymer is (meth)acrylate terminated. 
     
     
         13 . The ink of  claim 1 , wherein the liquid rubber is present in the ink in an amount of 1-5 weight %, based on the total weight of the ink. 
     
     
         14 . The ink of  claim 1  further comprising a colorant. 
     
     
         15 . The ink of  claim 1  further comprising one or more additives selected from the group consisting of photoinitiators, inhibitors, stabilizing agents, sensitizers, and combinations thereof. 
     
     
         16 . The ink of  claim 1 , wherein the ink when cured has a Shore A hardness of 20-40. 
     
     
         17 . The ink of  claim 1 , wherein the ink when cured has an elongation at break of at least 300%. 
     
     
         18 . The ink of  claim 1 , wherein the ink when cured has a Shore A hardness of 20-40 and an elongation at break of 300-800%. 
     
     
         19 . A method of printing a three-dimensional article comprising:
 selectively depositing layers of an ink in a fluid state onto a substrate, wherein the ink comprises the ink of  claim 1 .   
     
     
         20 . A printed three-dimensional article formed from the ink of  claim 1 .