US2016122358A1PendingUtilityA1

Novel substituted pyrazolo-piperazines as casein kinase 1 d/e inhibitors

Assignee: BRISTOL MYERS SQUIBB COPriority: Nov 14, 2013Filed: Jan 13, 2016Published: May 5, 2016
Est. expiryNov 14, 2033(~7.3 yrs left)· nominal 20-yr term from priority
A61P 35/00A61P 35/02A61P 43/00A61P 19/02A61P 25/00C07D 487/20C07D 491/147C07D 491/20C07D 519/00C07D 487/10C07D 487/04
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Claims

Abstract

The invention provides compounds of Formula (I): and pharmaceutically acceptable salts thereof. The compounds of Formula (I) inhibit protein kinase activity thereby making them useful as anticancer agents.

Claims

exact text as granted — not AI-modified
What is claimed is: 
     
         1 . A compound according to Formula (I): 
       
         
           
           
               
               
           
         
         or a pharmaceutically acceptable salt thereof, wherein: 
         X is independently selected from 0 and NH; 
         R 1  is independently selected from carbocyclyl substituted with 1-5 R 5 , and heterocyclyl comprising carbon atoms and 1 to 3 heteroatoms selected from N, NR 4 , O, S, and substituted with 1-5 R 5 ; 
         R 2  is independently selected from (i) alkyl optionally substituted with F, Cl, Br, OR b , CN, NR a R a , —C(═O)NR a R a , C 2-6  alkenyl substituted with 0-5 R e , C 2-6  alkynyl substituted with 0-5 R e , carbocyclyl substituted with 1-8 R 7 , and heterocyclyl comprising carbon atoms and 1 to 4 heteroatoms selected from N, NR 6 , O, S, and substituted with 1-8 R 7 , (ii) cycloalkyl substituted with 1-8 R 7 , and (iii) cycloheteroalkyl substituted with 1-8 R 7 ; 
         R 3a , R 3b , R 3c , R 3d , R 3e  and R 3f  are independently selected from H, CN, C 1-4 alkyl substituted with 1-3
 R 8 , —C(═O)OR b , —C(═O)NR a R a , —C(═O)R b , —NR a C(═O)R b , —NR a C(═O)OR b , —(CH 2 ) r -carbocyclyl substituted with 1-3 R 8 , and —(CH 2 ) r -heterocyclyl substituted with 1-3 R 8 ; 
 
         alternatively, R 3a  and R 3b , or R 3c  and R 3d , or R 3e  and R 3f , together with the carbon atom to which they are both attached form a spiral carbocyclic or heterocyclic ring comprising carbon atoms and 1 to 4 heteroatoms selected from N, O, S, each substituted with 1-5 R 8 ; 
         alternatively, R 3a  and R 3c  or R 3b  and R 3d  together form a heterocyclic ring comprising carbon atoms and 1 to 4 heteroatoms selected from N, O, S, and substituted with 1-5 R 8 ; 
         R 4  is independently selected from H, C 1-4  alkyl substituted with 0-3 R e , —(CH 2 ) r CN, —(CH 2 ) r OR b ,
 (CH 2 ) r S(O) p R c , —(CH 2 ) r C(═O)R b , —(CH 2 ) r NR a R a , —(CH 2 ) r C(═O)NR a R a , —(CH 2 ) r NR a C(═O)R b , —(CH 2 ) r NR a C(═O)OR b , —(CH 2 ) r OC(═O)NR a R a , —(CH 2 ) r NR a C(═O)NR a R a , —(CH 2 ) r C(═O)OR b , —(CH 2 ) r S(O) 2 NR a R a , —(CH 2 ) r NR a S(O) 2 NR a R a , —(CH 2 ) r NR a S(O) 2 R c , (CH 2 ) r -carbocyclyl substituted with 0-3 R e , and —(CH 2 ) r -heterocyclyl substituted with 0-3 R e ; 
 
         R 5 , at each occurrence, is independently selected from H, C 1-4  alkyl substituted with 0-3 R e , F, Cl, Br, ═O, CN, NO 2 , —OR b , —(CH 2 ) r CN, —(CH 2 ) r OR b ,
 (CH 2 ) r S(O) p R c , —(CH 2 ) r C(═O)R b , —(CH 2 ) r NR a R a , —(CH 2 ) r C(═O)NR a R a , —(CH 2 ) r NR a C(═O)R b , —(CH 2 ) r NR a C(═O)OR b , —(CH 2 ) r OC(═O)NR a R a , —(CH 2 ) r NR a C(═O)NR a R a , —(CH 2 ) r C(═O)OR b , —(CH 2 ) r S(O) 2 NR a R a , —(CH 2 ) r NR a S(O) 2 NR a R a , —(CH 2 ) r NR a S(O) 2 R c , (CH 2 ) r -carbocyclyl substituted with 0-3 R e , and —(CH 2 ) r -heterocyclyl substituted with 0-3 R e ; 
 
         R 6  is independently selected from H, —C(═O)R b , —CO(═O)R b , —S(O) p R c , C 1-6  alkyl substituted with 0-5 R e , —(CH 2 ) r —C 3-6 carbocyclyl substituted with 0-5 R e , and —(CH 2 ) r -heterocyclyl substituted with 0-5 R e ; 
         R 7 , at each occurrence, is independently selected from H, F, Cl, Br, ═O, —(CR d R d ) r CN, NO 2 , —(CR d R d ) r OR b , —S(O) p R c , —C(═O)R b , —(CR d R d ) r NR a R a , —(CR d R d ) r C(═O)NR a R a , —NR a C(═O)R b , —NR a C(═O)OR b , —OC(═O)NR a R a , —NR a C(═O)NR a R a , —(CR d R d ) r C(═O)OR b , —S(O) 2 NR a R a , —NR a S(O) 2 NR a R a , —NR a S(O) 2 R c , C 1-6  alkyl substituted with 0-5 R e , —(CR d R d ) r —C 3-6 carbocyclyl substituted with 0-5 R e ,
 and —(CR d R d ) r -heterocyclyl substituted with 0-5 R e ; 
 
         R 8 , at each occurrence, is independently selected from H, F, Cl, Br, CN, C 1-6  alkyl substituted with 0-5 R e , C 2-6  alkenyl, C 2-6  alkynyl, —(CH 2 ) r —C 3-6  cycloalkyl substituted with 0-5 R e , —(CH 2 ) r -aryl substituted with 0-5 R e , —(CH 2 ) r -heterocyclyl substituted with 0-5 R e , CO 2 H, —(CH 2 ) r OR b , and —(CH 2 ) r NR a R a ; 
         R a , at each occurrence, is independently selected from H, CN, C 1-6  alkyl substituted with 0-5 R e , C 2-6  alkenyl substituted with 0-5 R e , C 2-6  alkynyl substituted with 0-5 R e , —(CH 2 ) r —C 3-10 carbocyclyl substituted with 0-5 R e , and —(CH 2 ) r -heterocyclyl substituted with 0-5 R e ; or R a  and R a  together with the nitrogen atom to which they are both attached form a heterocyclic ring substituted with 0-5 R e ; 
         R b , at each occurrence, is independently selected from H, C 1-6  alkyl substituted with 0-5 R e , C 2-6  alkenyl substituted with 0-5 R e , C 2-6  alkynyl substituted with 0-5 R e , —(CH 2 ) r —C 3-10 carbocyclyl substituted with 0-5 R e , and —(CH 2 ) r -heterocyclyl substituted with 0-5 R e ; 
         R c , at each occurrence, is independently selected from C 1-6  alkyl substituted with 0-5 R e , C 2-6 alkenyl substituted with 0-5 R e , C 2-6 alkynyl substituted with 0-5 R e , C 3-6 carbocyclyl, and heterocyclyl; 
         R d , at each occurrence, is independently selected from H and C 1-4 alkyl substituted with 0-5 R e ; 
         R e , at each occurrence, is independently selected from F, Cl, Br, CN, NO 2 , ═O, C 1-6  alkyl substituted with 0-5 R f , C 2-6  alkenyl, C 2-6  alkynyl, —(CH 2 ) r —C 3-6  cycloalkyl, —(CH 2 ) r -aryl, —(CH 2 ) r -heterocyclyl, CO 2 H, —(CH 2 ) r OR f , SR f , and —(CH 2 ) r NR f R f ; 
         R f , at each occurrence, is independently selected from H, C 1-5  alkyl optionally substituted with F, Cl, Br, C 3-6  cycloalkyl, and phenyl, or R f  and R f  together with the nitrogen atom to which they are both attached form a heterocyclic ring optionally substituted with C 1-4 alkyl; 
         p, at each occurrence, is independently selected from zero, 1, and 2; and 
         r, at each occurrence, is independently selected from zero, 1, 2, 3, and 4. 
       
     
     
         2 . The compound according to  claim 1 , having Formula (II): 
       
         
           
           
               
               
           
         
         or a pharmaceutically acceptable salt thereof, wherein: 
         R 1  is independently selected from aryl substituted with 1-4 R 5 , and 5- to 12-membered heteroaryl comprising carbon atoms and 1 to 3 heteroatoms selected from N, NR 4 , O, S, and substituted with 1-4 R 5 ; 
         R 2  is independently selected from (i) alkyl optionally substituted with F, Cl, Br, OR b , CN, NR a R a , —C(═O)NR a R a , C 2-6  alkenyl substituted with 0-5 R e , C 2-6  alkynyl substituted with 0-5 R e , carbocyclyl substituted with 1-8 R 7 , and heterocyclyl comprising carbon atoms and 1 to 4 heteroatoms selected from N, NR 6 , O, S, and substituted with 1-8 R 7 , (ii) cycloalkyl substituted with 1-8 R 7 , and (iii) cycloheteroalkyl substituted with 1-8 R 7 ; 
         R 3a , R 3b , R 3c , and R 3d  are independently selected from H, CN, C 1-4 alkyl substituted with 1-3
 R 8 , —C(═O)OR b , —C(═O)NR a R a , —C(═O)R b , —NR a C(═O)R b , —NR a C(═O)OR b , —(CH 2 ) r -carbocyclyl substituted with 1-3 R 8 , and —(CH 2 ) r -heterocyclyl substituted with 1-3 R 8 ; 
 
         alternatively, R 3a  and R 3b , or R 3c  and R 3d , or R 3e  and R 3f , together with the carbon atom to which they are both attached form a spiral carbocyclic or heterocyclic ring comprising carbon atoms and 1 to 4 heteroatoms selected from N, O, S, each substituted with 0-5 R e ; 
         alternatively, R 3a  and R 3c  or R 3b  and R 3d  together form a heterocyclic ring comprising carbon atoms and 1 to 4 heteroatoms selected from N, O, S, and substituted with 0-5 R e ; 
         R 4  is independently selected from H and C 1-4  alkyl substituted with 0-3 R e ; 
         R 5 , at each occurrence, is independently selected from H, C 1-4  alkyl substituted with 0-3 R e , F, Cl, Br, ═O, CN, NO 2 , —OR b , —(CH 2 ) r CN, —(CH 2 ) r OR b ,
 (CH 2 ) r S(O) p R c , —(CH 2 ) r C(═O)R b , —(CH 2 ) r NR a R a , —(CH 2 ) r C(═O)NR a R a , —(CH 2 ) r NR a C(═O)R b , —(CH 2 ) r NR a C(═O)OR b , —(CH 2 ) r OC(═O)NR a R a , —(CH 2 ) r NR a C(═O)NR a R a , —(CH 2 ) r C(═O)OR b , —(CH 2 ) r S(O) 2 NR a R a , —(CH 2 ) r NR a S(O) 2 NR a R a , —(CH 2 ) r NR a S(O) 2 R c , (CH 2 ) r -carbocyclyl substituted with 0-3 R e , and —(CH 2 ) r -heterocyclyl substituted with 0-3 R e ; 
 
         R 6  is independently selected from H, —C(═O)R b , —CO(═O)R b , —S(O) p R c , C 1-6  alkyl substituted with 0-5 R e , —(CH 2 ) r —C 3-6 carbocyclyl substituted with 0-5 R e , and —(CH 2 ) r -heterocyclyl substituted with 0-5 R e ; 
         R 7 , at each occurrence, is independently selected from H, F, Cl, Br, ═O, —(CR d R d ) r CN, NO 2 , —(CR d R d ) r OR b , —S(O) p R c , —C(═O)R b , —(CR d R d ) r NR a R a , —(CR d R d ) r C(═O)NR a R a , —NR a C(═O)R b , —NR a C(═O)OR b , —OC(═O)NR a R a , —NR a C(═O)NR a R a , —(CR d R d ) r C(═O)OR b , —S(O) 2 NR a R a , —NR a S(O) 2 NR a R a , —NR a S(O) 2 R c , C 1-6  alkyl substituted with 0-5 R e , —(CR d R d ) r —C 3-6 carbocyclyl substituted with 0-5 R e ,
 and —(CR d R d ) r -heterocyclyl substituted with 0-5 R e ; 
 
         R 8 , at each occurrence, is independently selected from H, F, Cl, Br, CN, C 1-6  alkyl substituted with 0-5 R e , C 2-6  alkenyl, C 2-6  alkynyl, —(CH 2 ) r —C 3-6  cycloalkyl substituted with 0-5 R e , —(CH 2 ) r -aryl substituted with 0-5 R e , —(CH 2 ) r -heterocyclyl substituted with 0-5 R e , CO 2 H, —(CH 2 ) r OR b , and —(CH 2 ) r NR a R a ; 
         R a , at each occurrence, is independently selected from H, CN, C 1-6  alkyl substituted with 0-5 R e , C 2-6  alkenyl substituted with 0-5 R e , C 2-6  alkynyl substituted with 0-5 R e , —(CH 2 ) r —C 3-10 carbocyclyl substituted with 0-5 R e , and —(CH 2 ) r -heterocyclyl substituted with 0-5 R e ; or R a  and R a  together with the nitrogen atom to which they are both attached form a heterocyclic ring substituted with 0-5 R e ; 
         R b , at each occurrence, is independently selected from H, C 1-6  alkyl substituted with 0-5 R e , C 2-6  alkenyl substituted with 0-5 R e , C 2-6  alkynyl substituted with 0-5 R e , —(CH 2 ) r —C 3-10 carbocyclyl substituted with 0-5 R e , and —(CH 2 ) r -heterocyclyl substituted with 0-5 R e ; 
         R c , at each occurrence, is independently selected from C 1-6  alkyl substituted with 0-5 R e , C 2-6 alkenyl substituted with 0-5 R e , C 2-6 alkynyl substituted with 0-5 R e , C 3-6 carbocyclyl, and heterocyclyl; 
         R d , at each occurrence, is independently selected from H and C 1-4 alkyl substituted with 0-5 R e ; 
         R e , at each occurrence, is independently selected from F, Cl, Br, CN, NO 2 , ═O, C 1-6  alkyl substituted with 0-5 R f , C 2-6  alkenyl, C 2-6  alkynyl, —(CH 2 ) r —C 3-6  cycloalkyl, CO 2 H, —(CH 2 ) r OR f , SR f , and —(CH 2 ) r NR f R f ; 
         R f , at each occurrence, is independently selected from H, C 1-5  alkyl, C 3-6  cycloalkyl, and phenyl, or R f  and R f  together with the nitrogen atom to which they are both attached form a heterocyclic ring optionally substituted with C 1-4 alkyl; 
         p, at each occurrence, is independently selected from zero, 1, and 2; and 
         r, at each occurrence, is independently selected from zero, 1, 2, 3, and 4. 
       
     
     
         3 . The compound according to  claim 2 , wherein:
 R 1  is independently selected from aryl, pyridyl, pyrimidinyl, pyrazinyl, pyridazinyl, triazinyl, furyl, thienyl, imidazolyl, thiazolyl, indolyl, oxazolyl, isoxazolyl, pyrazolyl, triazolyl, tetrazolyl, indazolyl, 1,2,4-thiadiazolyl, isothiazolyl, quinolinyl, isoquinolinyl, each substituted with 1-4 R 4  and R 5 ;   R 4 , at each occurrence, is independently selected from H and C 1-4  alkyl substituted with 0-3 R e ;   R 5 , at each occurrence, is independently selected from H, C 1-4  alkyl substituted with 0-3 R e , F, Cl, Br, ═O, CN,
 NO 2 , —OR b , —S(O) p R c , —CN, —OR b , —(CH 2 ) r C(═O)R b , —(CH 2 ) r NR a R a , —(CH 2 ) r C(═O)NR a R a , —(CH 2 ) r NHC(═O)R b , —(CH 2 ) r NHC(═O)OR b , —(CH 2 ) r OC(═O)NR a R a , —(CH 2 ) r NHC(═O)NR a R a , —(CH 2 ) r C(═O)OR b , —(CH 2 ) r S(O) 2 NR a R a , —(CH 2 ) r NHS(O) 2 NR a R a , —(CH 2 ) r NHS(O) 2 R c , (CH 2 ) r -carbocyclyl substituted with 0-3 R e , 
 and —(CH 2 ) r -heterocyclyl substituted with 0-3 R e ; 
   R a , at each occurrence, is independently selected from H, CN, C 1-6  alkyl substituted with 0-5 R e , C 2-6  alkenyl substituted with 0-5 R e , C 2-6  alkynyl substituted with 0-5 R e , —(CH 2 ) r —C 3-10 carbocyclyl substituted with 0-5 R e , and —(CH 2 ) r -heterocyclyl substituted with 0-5 R e ; or R a  and R a  together with the nitrogen atom to which they are both attached form a heterocyclic ring substituted with 0-5 R e ;   R b , at each occurrence, is independently selected from H, C 1-6  alkyl substituted with 0-5 R e , C 2-6  alkenyl substituted with 0-5 R e , C 2-6  alkynyl substituted with 0-5 R e , —(CH 2 ) r —C 3-10 carbocyclyl substituted with 0-5 R e , and —(CH 2 ) r -heterocyclyl substituted with 0-5 R e ;   R c , at each occurrence, is independently selected from C 1-6  alkyl substituted with 0-5 R e , C 2-6 alkenyl substituted with 0-5 R e , C 2-6 alkynyl substituted with 0-5 R e , C 3-6 carbocyclyl, and heterocyclyl;   R e , at each occurrence, is independently selected from F, Cl, Br, CN, NO 2 , ═O, C 1-6  alkyl substituted with 0-5 R f , C 2-6  alkenyl, C 2-6  alkynyl, —(CH 2 ) r —C 3-6  cycloalkyl, CO 2 H, —(CH 2 ) r OR f , SR f , and —(CH 2 ) r NR f R f ;   R f , at each occurrence, is independently selected from H, C 1-5  alkyl, C 3-6  cycloalkyl, and phenyl, or R f  and R f  together with the nitrogen atom to which they are both attached form a heterocyclic ring optionally substituted with C 1-4 alkyl;   p, at each occurrence, is independently selected from zero, 1, and 2; and   r, at each occurrence, is independently selected from zero, 1, 2, 3, and 4.   
     
     
         4 . The compound according to  claim 3 , wherein:
 R 1  is independently selected from   
       
         
           
           
               
               
           
         
         
           
           
               
               
           
         
         R 4 , at each occurrence, is independently selected from H, C 1-4  alkyl substituted with 0-3 R e ; 
         R 5 , at each occurrence, is independently selected from H, C 1-4  alkyl substituted with 0-3 R e , F, Cl, Br, ═O, CN,
 NO 2 , —OR b , —S(O) p R c , —CN, —OR b , —(CH 2 ) r C(═O)R b , —(CH 2 ) r NR a R a , —(CH 2 ) r C(═O)NR a R a , —(CH 2 ) r NHC(═O)R b , —(CH 2 ) r NHC(═O)OR b , —(CH 2 ) r OC(═O)NR a R a , —(CH 2 ) r NHC(═O)NR a R a , —(CH 2 ) r C(═O)OR b , —(CH 2 ) r S(O) 2 NR a R a , —(CH 2 ) r NHS(O) 2 NR a R a , —(CH 2 ) r NHS(O) 2 R c , (CH 2 ) r —C 3-6 cycloalkyl, —(CH 2 ) r -aryl substituted with 0-3 R e , and —(CH 2 ) r -heterocyclyl substituted with 0-3 R e ; 
 
         R a , at each occurrence, is independently selected from H, CN, C 1-6  alkyl substituted with 0-5 R e , C 2-6  alkenyl substituted with 0-5 R e , C 2-6  alkynyl substituted with 0-5 R e , —(CH 2 ) r —C 3-10 carbocyclyl substituted with 0-5 R e , and —(CH 2 ) r -heterocyclyl substituted with 0-5 R e ; or R a  and R a  together with the nitrogen atom to which they are both attached form a heterocyclic ring substituted with 0-5 R e ; 
         R b , at each occurrence, is independently selected from H, C 1-6  alkyl substituted with 0-5 R e , C 2-6  alkenyl substituted with 0-5 R e , C 2-6  alkynyl substituted with 0-5 R e , —(CH 2 ) r —C 3-10 carbocyclyl substituted with 0-5 R e , and —(CH 2 ) r -heterocyclyl substituted with 0-5 R e ; 
         R c , at each occurrence, is independently selected from C 1-6  alkyl substituted with 0-5 R e , C 2-6 alkenyl substituted with 0-5 R e , C 2-6 alkynyl substituted with 0-5 R e , C 3-6 carbocyclyl, and heterocyclyl; 
         R e , at each occurrence, is independently selected from F, Cl, Br, CN, NO 2 , ═O, C 1-6  alkyl, C 2-6  alkenyl, C 2-6  alkynyl, —(CH 2 ) r —C 3-6  cycloalkyl, and CO 2 H; 
         p, at each occurrence, is independently selected from zero, 1, and 2; and 
         r, at each occurrence, is independently selected from zero, 1, 2, 3, and 4. 
       
     
     
         5 . The compound according to  claim 4 , having Formula (III), 
       
         
           
           
               
               
           
         
         or a pharmaceutically acceptable salt thereof, wherein: 
         R 2  is independently selected from (i) alkyl optionally substituted with F, Cl, Br, OR b , CN, NR a R a , —C(═O)NR a R a , C 2-6  alkenyl substituted with 0-5 R e , C 2-6  alkynyl substituted with 0-5 R e , carbocyclyl substituted with 1-8 R 7 , and heterocyclyl comprising carbon atoms and 1 to 4 heteroatoms selected from N, NR 6 , O, S, and substituted with 1-8 R 7 , (ii) cycloalkyl substituted with 1-8 R 7 , and (iii) cycloheteroalkyl substituted with 1-8 R 7 ; 
         R 3a , R 3b , R 3c , and R 3d  are independently selected from H, CN, C 1-4 alkyl substituted with 1-3
 R 8 , —C(═O)OR b , —C(═O)NR a R a , —C(═O)R b , —NR a C(═O)R b , —NR a C(═O)OR b , —(CH 2 ) r -carbocyclyl substituted with 1-3 R 8 , and —(CH 2 ) r -heterocyclyl substituted with 1-3 R 8 ; 
 
         alternatively, R 3a  and R 3b , or R 3c  and R 3d , together with the carbon atom to which they are both attached form a spiral carbocyclic or heterocyclic ring comprising carbon atoms and 1 to 4 heteroatoms selected from N, O, S, each substituted with 1-5 R 8 ; 
         alternatively, R 3a  and R 3c  or R 3b  and R 3d  together form a heterocyclic ring comprising carbon atoms and 1 to 4 heteroatoms selected from N, O, S, and substituted with 1-5 R 8 ; 
         R 5 , at each occurrence, is independently selected from H, C 1-4  alkyl substituted with 0-3 R e , F, Cl, Br, —S(O) p R c , —CN, —OR b , NR a R a , C 3-6 cycloalkyl, aryl substituted with 0-3 R e , and heterocyclyl substituted with 0-3 R e ; 
         R 6  is independently selected from H, —C(═O)R b , —CO(═O)R b , —S(O) p R c , C 1-6  alkyl substituted with 0-5 R e , —(CH 2 ) r —C 3-6 carbocyclyl substituted with 0-5 R e , and —(CH 2 ) r -heterocyclyl substituted with 0-5 R e ; 
         R 7 , at each occurrence, is independently selected from H, F, Cl, Br, ═O, —(CR d R d ) r CN, NO 2 , —(CR d R d ) r OR b , —S(O) p R c , —C(═O)R b , —(CR d R d ) r NR a R a , —(CR d R d ) r C(═O)NR a R a , —NR a C(═O)R b , —NR a C(═O)OR b , —OC(═O)NR a R a , —NR a C(═O)NR a R a , —(CR d R d ) r C(═O)OR b , —S(O) 2 NR a R a , —NR a S(O) 2 NR a R a , —NR a S(O) 2 R c , C 1-6  alkyl substituted with 0-5 R e , —(CR d R d ) r —C 3-6 carbocyclyl substituted with 0-5 R e ,
 and —(CR d R d ) r -heterocyclyl substituted with 0-5 R e ; 
 
         R 8 , at each occurrence, is independently selected from H, F, Cl, Br, CN, C 1-6  alkyl substituted with 0-5 R e , C 2-6  alkenyl, C 2-6  alkynyl, —(CH 2 ) r —C 3-6  cycloalkyl substituted with 0-5 R e , —(CH 2 ) r -aryl substituted with 0-5 R e , —(CH 2 ) r -heterocyclyl substituted with 0-5 R e , CO 2 H, —(CH 2 ) r OR b , and —(CH 2 ) r NR a R a ; 
         R a , at each occurrence, is independently selected from H, CN, C 1-6  alkyl substituted with 0-5 R e , C 2-6  alkenyl substituted with 0-5 R e , C 2-6  alkynyl substituted with 0-5 R e , —(CH 2 ) r —C 3-10 carbocyclyl substituted with 0-5 R e , and —(CH 2 ) r -heterocyclyl substituted with 0-5 R e ; or R a  and R a  together with the nitrogen atom to which they are both attached form a heterocyclic ring substituted with 0-5 R e ; 
         R b , at each occurrence, is independently selected from H, C 1-6  alkyl substituted with 0-5 R e , C 2-6  alkenyl substituted with 0-5 R e , C 2-6  alkynyl substituted with 0-5 R e , —(CH 2 ) r —C 3-10 carbocyclyl substituted with 0-5 R e , and —(CH 2 ) r -heterocyclyl substituted with 0-5 R e ; 
         R c , at each occurrence, is independently selected from C 1-6  alkyl substituted with 0-5 R e , C 2-6 alkenyl substituted with 0-5 R e , C 2-6 alkynyl substituted with 0-5 R e , C 3-6 carbocyclyl, and heterocyclyl; 
         R d , at each occurrence, is independently selected from H and C 1-4 alkyl substituted with 0-5 R e ; 
         R e , at each occurrence, is independently selected from F, Cl, Br, CN, NO 2 , ═O, CO 2 H, C 1-6  alkyl substituted with 0-5 R f , C 2-6  alkenyl, C 2-6  alkynyl, —(CH 2 ) r —C 3-6  cycloalkyl, —(CH 2 ) r OR f , SR f , and —(CH 2 ) r NR f R f ; 
         R f , at each occurrence, is independently selected from H, C 1-5  alkyl, C 3-6  cycloalkyl, and phenyl, or R f  and R f  together with the nitrogen atom to which they are both attached form a heterocyclic ring optionally substituted with C 1-4 alkyl; 
         p, at each occurrence, is independently selected from zero, 1, and 2; and 
         r, at each occurrence, is independently selected from zero, 1, 2, 3, and 4. 
       
     
     
         6 . The compound according to  claim 5 , wherein:
 R 2  is independently selected from   
       
         
           
           
               
               
           
         
         
           
           
               
               
           
         
         R 3a  and R 3b  are independently selected from H, CH 2 CH 3 , CH 3 , CH 2 OH, CH 2 CH 2 OH, CH 2 CH 2 OC 1-4 alkyl, CH 2 F, CHF 2 , CH 2 CH 2 F, CF 3 , CH 2 OCHF 2 , CH 2 CN, CH 2 CH 2 CN, CH 2 OC 1-4 alkyl, C(CH 3 ) 3 , CH(CH 3 ) 2 , C(CH 3 ) 20 H, C(CH 3 ) 2 F, C(═O)NH—C 3-6 cycloalkyl, C(═O)NH-heterocyclyl, and —CH 2 -heterocyclyl, wherein the heterocyclyl is independently selected from 
       
       
         
           
           
               
               
           
         
         R 3c  and R 3d  are independently selected from H, CH 3 , CH(CH 3 ) 2 , CF 3 , and C 3-6  cycloalkyl; 
         R 5 , at each occurrence, is independently selected from H, C 1-4  alkyl substituted with 0-3 R e , F, Cl, Br, —S(O) p R c , —CN, —OR b , NR a R a , C 3-6 cycloalkyl, and aryl substituted with 0-3 R e ; 
         R 7 , at each occurrence, is independently selected from H, F, Cl, Br, ═O, —(CH 2 ) r CN, NO 2 , —(CH 2 ) r OR b , —S(O) p R c , —C(═O)R b , —NR a R a , —C(═O)NR a R a , —NHC(═O)R b , —NHC(═O)OR b , —OC(═O)NR a R a , —NHC(═O)NR a R a , —C(═O)OR b , —S(O) 2 NR a R a , —NHS(O) 2 NR a R a , —NHS(O) 2 R c , C 1-6  alkyl substituted with 0-5 R e , aryl substituted with 0-5 R e , and heterocyclyl substituted with 0-5 R e ; 
         R 8 , at each occurrence, is independently selected from H, F, Cl, Br, CN, C 1-6  alkyl substituted with 0-5 R e , —(CH 2 ) r —C 3-6  cycloalkyl substituted with 0-5 R e , —(CH 2 ) r -aryl substituted with 0-5 R e , —(CH 2 ) r -heterocyclyl substituted with 0-5 R e , CO 2 H, —(CH 2 ) r OR b , and —(CH 2 ) r NR a R a ; 
         R a , at each occurrence, is independently selected from H, CN, C 1-6  alkyl substituted with 0-5 R e , C 2-6  alkenyl substituted with 0-5 R e , C 2-6  alkynyl substituted with 0-5 R e , —(CH 2 ) r —C 3-10 carbocyclyl substituted with 0-5 R e , and —(CH 2 ) r -heterocyclyl substituted with 0-5 R e ; or R a  and R a  together with the nitrogen atom to which they are both attached form a heterocyclic ring substituted with 0-5 R e ; 
         R b , at each occurrence, is independently selected from H, C 1-6  alkyl substituted with 0-5 R e , C 2-6  alkenyl substituted with 0-5 R e , C 2-6  alkynyl substituted with 0-5 R e , aryl substituted with 0-5 R e , and heterocyclyl substituted with 0-5 R e ; 
         R c , at each occurrence, is independently selected from C 1-6  alkyl substituted with 0-5 R e , C 3-6 carbocyclyl, and heterocyclyl; 
         R e , at each occurrence, is independently selected from F, Cl, Br, CN, NO 2 , ═O, CO 2 H, C 1-6  alkyl, C 2-6  alkenyl, C 2-6  alkynyl, and —(CH 2 ) r —C 3-6  cycloalkyl; 
         p, at each occurrence, is independently selected from zero, 1, and 2; and 
         r, at each occurrence, is independently selected from zero, 1, 2, 3, and 4. 
       
     
     
         7 . The compound according to  claim 6 , wherein:
 R 2  is independently selected from   
       
         
           
           
               
               
           
         
         R 3a  and R 3b  are independently H; 
         R 3c  and R 3d  are independently H; 
         R 5 , at each occurrence, is independently selected from H, F, Cl, and Br. 
       
     
     
         8 . The compound according to  claim 5 , wherein:
 R 2  is independently selected from   
       
         
           
           
               
               
           
         
         R 3a  and R 3b  are independently selected from H, CH 2 CH 3 , CH 3 , CH 2 OH, CH 2 CH 2 OH, CH 2 CH 2 OC 1-4 alkyl, CH 2 F, CHF 2 , CH 2 CH 2 F, CF 3 , CH 2 OCHF 2 , CH 2 CN, CH 2 CH 2 CN, CH 2 OC 1-4 alkyl, C(CH 3 ) 3 , CH(CH 3 ) 2 , C(CH 3 ) 2 OH, C(CH 3 ) 2 F, C(═O)NH—C 3-6 cycloalkyl, C(═O)NH-heterocyclyl, and —CH 2 -heterocyclyl, wherein the heterocyclyl is independently selected from 
       
       
         
           
           
               
               
           
         
         R 3c  and R 3d  are independently selected from H, CH 3 , CH(CH 3 ) 2 , CF 3 , and C 3-6  cycloalkyl; 
         R 5 , at each occurrence, is independently selected from H, C 1-4  alkyl substituted with 0-3 R e , F, Cl, Br, —S(O) p R c , —CN, —OR b , NR a R a , C 3-6 cycloalkyl, and aryl substituted with 0-3 R e ; 
         R 7 , at each occurrence, is independently selected from H, F, Cl, Br, ═O, —(CH 2 ) r CN, NO 2 , —(CH 2 ) r OR b , —S(O) p R c , —C(═O)R b , —NR a R a , —C(═O)NR a R a , —NHC(═O)R b , —NHC(═O)OR b , —OC(═O)NR a R a , —NHC(═O)NR a R a , —C(═O)OR b , —S(O) 2 NR a R a , —NHS(O) 2 NR a R a , —NHS(O) 2 R c , C 1-6  alkyl substituted with 0-5 R e , aryl substituted with 0-5 R e , and heterocyclyl substituted with 0-5 R e ; 
         R 8 , at each occurrence, is independently selected from H, F, Cl, Br, CN, C 1-6  alkyl substituted with 0-5 R e , —(CH 2 ) r —C 3-6  cycloalkyl substituted with 0-5 R e , —(CH 2 ) r -aryl substituted with 0-5 R e , —(CH 2 ) r -heterocyclyl substituted with 0-5 R e , CO 2 H, —(CH 2 ) r OR b , and —(CH 2 ) r NR a R a ; 
         R a , at each occurrence, is independently selected from H, CN, C 1-6  alkyl substituted with 0-5 R e , C 2-6  alkenyl substituted with 0-5 R e , C 2-6  alkynyl substituted with 0-5 R e , —(CH 2 ) r —C 3-10 carbocyclyl substituted with 0-5 R e , and —(CH 2 ) r -heterocyclyl substituted with 0-5 R e ; or R a  and R a  together with the nitrogen atom to which they are both attached form a heterocyclic ring substituted with 0-5 R e ; 
         R b , at each occurrence, is independently selected from H, C 1-6  alkyl substituted with 0-5 R e , C 2-6  alkenyl substituted with 0-5 R e , C 2-6  alkynyl substituted with 0-5 R e , aryl substituted with 0-5 R e , and heterocyclyl substituted with 0-5 R e ; 
         R c , at each occurrence, is independently selected from C 1-6  alkyl substituted with 0-5 R e , C 3-6 carbocyclyl, and heterocyclyl; 
         R e , at each occurrence, is independently selected from F, Cl, Br, CN, NO 2 , ═O, CO 2 H C 1-6  alkyl, C 2-6  alkenyl, C 2-6  alkynyl, and —(CH 2 ) r —C 3-6  cycloalkyl; 
         p, at each occurrence, is independently selected from zero, 1, and 2; and 
         r, at each occurrence, is independently selected from zero, 1, 2, 3, and 4. 
       
     
     
         9 . The compound according to  claim 5 , or a pharmaceutically acceptable salt thereof, wherein R 3a  and R 3b , or R 3c  and R 3d , together with the carbon atom to which they are both attached form a spiral carbocyclic or heterocyclic ring comprising carbon atoms and 1 to 4 heteroatoms selected from N, O, S, each substituted with 1-5 R 8 . 
     
     
         10 . The compound according to  claim 9 , having Formula (IV): 
       
         
           
           
               
               
           
         
         or a pharmaceutically acceptable salt thereof, wherein: 
         Ring A is C 3-6 cycloalkyl or heterocyclyl; 
         R 2  is independently selected from 
       
       
         
           
           
               
               
           
         
         
           
           
               
               
           
         
         
           
           
               
               
           
         
         R 5 , at each occurrence, is independently selected from H, C 1-4  alkyl substituted with 0-3 R e , F, Cl, Br, —S(O) p R c , —CN, —OR b , NR a R a , C 3-6 cycloalkyl, aryl substituted with 0-3 R e , and heterocyclyl substituted with 0-3 R e ; 
         R 7 , at each occurrence, is independently selected from H, F, Cl, Br, CN, NO 2 , —OR b , —S(O) p R c , —C(═O)R b , —NR a R a , —C(═O)NR a R a , —NHC(═O)R b , —NHC(═O)OR b , —OC(═O)NR a R a , —NHC(═O)NR a R a , —C(═O)OR b , —S(O) 2 NR a R a , C 1-6  alkyl substituted with 0-5 R e , aryl substituted with 0-5 R e , and heterocyclyl substituted with 0-5 R e ; 
         R 8 , at each occurrence, is independently selected from H, F, Cl, Br, CN, C 1-6  alkyl substituted with 0-5 R e , C 2-6  alkenyl, C 2-6  alkynyl, —(CH 2 ) r —C 3-6  cycloalkyl substituted with 0-5 R e , —(CH 2 ) r -aryl substituted with 0-5 R e , —(CH 2 ) r -heterocyclyl substituted with 0-5 R e , CO 2 H, —(CH 2 ) r OR b , and —(CH 2 ) r NR a R a ; 
         R a , at each occurrence, is independently selected from H, CN, C 1-6  alkyl substituted with 0-5 R e , C 2-6  alkenyl substituted with 0-5 R e , C 2-6  alkynyl substituted with 0-5 R e , —(CH 2 ) r —C 3-10 carbocyclyl substituted with 0-5 R e , and —(CH 2 ) r -heterocyclyl substituted with 0-5 R e ; or R a  and R a  together with the nitrogen atom to which they are both attached form a heterocyclic ring substituted with 0-5 R e ; 
         R b , at each occurrence, is independently selected from H, C 1-6  alkyl substituted with 0-5 R e , C 2-6  alkenyl substituted with 0-5 R e , C 2-6  alkynyl substituted with 0-5 R e , aryl substituted with 0-5 R e , and heterocyclyl substituted with 0-5 R e ; 
         R c , at each occurrence, is independently selected from C 1-6  alkyl substituted with 0-5 R e , C 3-6 carbocyclyl, and heterocyclyl; 
         R e , at each occurrence, is independently selected from F, Cl, Br, CN, NO 2 , ═O, CO 2 H, C 1-6  alkyl, C 2-6  alkenyl, C 2-6  alkynyl, and —(CH 2 ) r —C 3-6  cycloalkyl; 
         p, at each occurrence, is independently selected from zero, 1, and 2; and 
         r, at each occurrence, is independently selected from zero, 1, 2, 3, and 4. 
       
     
     
         11 . The compound according to  claim 5 , or a pharmaceutically acceptable salt thereof, wherein:
 R 3a  and R 3c  together form a carbocyclic or heterocyclic ring comprising carbon atoms and 1 to 4 heteroatoms selected from N, O, S, wherein the carbocyclic or heterocyclic ring is substituted with 1-5 R 8 ; and   R 3b  and R 3d  are independently selected from H and C 1-4 alkyl.   
     
     
         12 . The compound according to  claim 11 , having Formula (V): 
       
         
           
           
               
               
           
         
         or a pharmaceutically acceptable salt thereof, wherein: 
         R 2  is independently selected from 
       
       
         
           
           
               
               
           
         
         
           
           
               
               
           
         
         
           
           
               
               
           
         
         R 5 , at each occurrence, is independently selected from H, C 1-4  alkyl substituted with 0-3 R e , F, Cl, Br, —S(O) p R c , —CN, —OR b , NR a R a , C 3-6 cycloalkyl, aryl substituted with 0-3 R e , and heterocyclyl substituted with 0-3 R e ; 
         R 7 , at each occurrence, is independently selected from H, F, Cl, Br, CN, NO 2 , —OR b , —S(O) p R c , —C(═O)R b , —NR a R a , —C(═O)NR a R a , —NHC(═O)R b , —NHC(═O)OR b , —OC(═O)NR a R a , —NHC(═O)NR a R a , —C(═O)OR b , —S(O) 2 NR a R a , C 1-6  alkyl substituted with 0-5 R e , aryl substituted with 0-5 R e , and heterocyclyl substituted with 0-5 R e ; 
         R a , at each occurrence, is independently selected from H, CN, C 1-6  alkyl substituted with 0-5 R e , C 2-6  alkenyl substituted with 0-5 R e , C 2-6  alkynyl substituted with 0-5 R e , —(CH 2 ) r —C 3-10 carbocyclyl substituted with 0-5 R e , and —(CH 2 ) r -heterocyclyl substituted with 0-5 R e ; or R a  and R a  together with the nitrogen atom to which they are both attached form a heterocyclic ring substituted with 0-5 R e ; 
         R b , at each occurrence, is independently selected from H, C 1-6  alkyl substituted with 0-5 R e , C 2-6  alkenyl substituted with 0-5 R e , C 2-6  alkynyl substituted with 0-5 R e , aryl substituted with 0-5 R e , and heterocyclyl substituted with 0-5 R e ; 
         R c , at each occurrence, is independently selected from C 1-6  alkyl substituted with 0-5 R e , C 3-6 carbocyclyl, and heterocyclyl; 
         R e , at each occurrence, is independently selected from F, Cl, Br, CN, NO 2 , ═O, CO 2 H, C 1-6  alkyl, C 2-6  alkenyl, C 2-6  alkynyl, and —(CH 2 ) r —C 3-6  cycloalkyl; 
         p, at each occurrence, is independently selected from zero, 1, and 2; and 
         r, at each occurrence, is independently selected from zero, 1, 2, 3, and 4. 
       
     
     
         13 . A pharmaceutical composition comprising one or more compounds of any one of  claims 1 - 12  and a pharmaceutically acceptable carrier. 
     
     
         14 . A method of inhibiting casein kinase Iδ/ε activity in a patient, comprising administering to the patient in need thereof, a therapeutically effective amount of one or more compounds according to any one of  claims 1 - 12 . 
     
     
         15 . A method for treating a disease, with the pathological conditions of which the activation of casein kinase Iδ/ε is associated, wherein the method comprises administering to a patient, a pharmaceutical composition comprising, as an active ingredient of one or more compounds according to any one of  claims 1 - 12 , or the salt thereof, wherein the disease is selected from a circadian rhythm disorder, a neurodegenerative disease, and cancer.

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