Air cathode for air batteries and air battery

Abstract

An air cathode for air batteries, having excellent high-rate discharge performance, and an air battery comprising the air cathode, are set forth. The air cathode for air batteries uses oxygen as an active material and may be configured to form an air battery comprising the air cathode, an anode and an electrolyte layer present between the air cathode and the anode. The air cathode includes: a catalyst layer that contains at least an electrode catalyst and an electroconductive material; an oxide as the electrode catalyst, which is active against at least oxygen reduction reaction; and at least one kind of metal carbide as the electroconductive material, selected from a tungsten carbide, a titanium carbide and a molybdenum carbide.

1 . An air cathode for air batteries, using oxygen as an active material and configured to form an air battery comprising the air cathode, an anode and an electrolyte layer present between the air cathode and the anode,
 the air cathode comprising:   a catalyst layer which contains at least an electrode catalyst and an electroconductive material;   an oxide as the electrode catalyst, which is active against at least oxygen reduction reaction; and   at least one kind of metal carbide as the electroconductive material, selected from the group consisting of a titanium carbide and a molybdenum carbide,   wherein the ratio of the amount of the titanium carbide to the amount of the catalyst layer is 5 to 71% by weight.   
     
     
         2 . The air cathode for air batteries according to  claim 1 , wherein the ratio of the amount of the titanium carbide to the total amount of the oxide and the titanium carbide is 5 to 71% by weight. 
     
     
         3 . The air cathode for air batteries according to  claim 1 , wherein the ratio of the amount of the molybdenum carbide to the total amount of the oxide and the molybdenum carbide is 5 to 71% by weight. 
     
     
         4 . The air cathode for air batteries according to  claim 1 , wherein the oxide is a complex oxide comprising at least one kind of metal element selected from the group consisting of iron, cobalt, nickel, titanium, manganese and copper and having a perovskite structure or spinel structure. 
     
     
         5 . The air cathode for air batteries according to  claim 4 , wherein the oxide is a complex oxide having a perovskite structure and having a composition represented by La 1-x A x BO 3  (wherein A is at least one kind selected from the group consisting of Sr and Ca; B is at least one kind selected from the group consisting of Co, Fe and Mn; and x is a number which satisfies 0≦x≦1). 
     
     
         6 . The air cathode for air batteries according to  claim 1 , wherein the electroconductive material further comprises an electroconductive carbon. 
     
     
         7 . The air cathode for air batteries according to  claim 1 , further comprising a gas diffusion layer comprising at least electroconductive carbon particles and a binder,
 wherein the catalyst layer and the gas diffusion layer are stacked in this order from the electrolyte layer side.   
     
     
         8 . An air battery comprising: an air cathode using oxygen as an active material, an anode and an electrolyte layer present between the air cathode and the anode,
 wherein the air cathode is the air cathode for air batteries defined by  claim 1 .