Method and catalyst for the simultaneous removal of carbon monoxide and nitrogen oxides from flue or exhaust gas

Abstract

A method and a catalyst, where flue gas or exhaust gas containing harmful carbon monoxide, organic compounds (VOC) and NO x is contacted with a layered catalyst in which a first layer comprises an oxidation catalyst and in an underlying layer a NH3-SCR catalyst for the simultaneous removal of the carbon monoxide and NO x .

1 . Method for the reduction of amounts carbon monoxide, volatile organic compounds and nitrogen oxides in flue or exhaust gas comprising the steps of:
 introducing ammonia and/or a precursor thereof into the flue or exhaust gas;   converting the precursor if any into ammonia;   contacting the gas and the ammonia at a temperature of up to 350° C. with a layered catalyst comprising an upper first catalyst layer with an oxidation catalyst and an underlying second catalyst layer with an NH3-SCR catalyst supporting completely the first layer and oxidizing at least part of the amounts of carbon monoxide and the volatile organic compounds in the upper first layer without affecting the ammonia further contained in the gas and reducing the amounts of nitrogen oxides in the underlying second catalyst layer by reaction with the ammonia.   
     
     
         2 . The method of  claim 1 , wherein the oxidation catalyst in the first layer consists of palladium, vanadium oxide and titanium oxide. 
     
     
         3 . The method of  claim 2 , wherein the oxidation catalyst consists of 0.45 wt % palladium, 4.5 wt % vanadium pentoxide and supported on titanium oxide. 
     
     
         4 . The method of  claim 1 , wherein the first catalyst layer has a layer thickness of between 10 and 200 micron. 
     
     
         5 . The method of  claim 1 , wherein the first catalyst layer has a layer thickness of between 10 and 50 micron. 
     
     
         6 . The method of  claim 1 , wherein the NH-3-SCR catalyst in the second catalyst layer comprises oxides of tungsten, molybdenum, vanadium and titanium. 
     
     
         7 . The method of  claim 1 , wherein the flue or exhaust gas is additionally treated with a conventional not layered SCR catalyst either upstream or downstream the layered catalyst. 
     
     
         8 . A catalyst for simultaneous oxidation of carbon monoxide and volatile organic compounds and selective reduction of nitrogen oxides by reaction with ammonia, the catalyst comprises a first layer of an oxidation catalyst and a second layer of an NH3-SCR catalyst completely supporting the first layer. 
     
     
         9 . The catalyst of  claim 8 , wherein the oxidation catalyst consists of palladium, oxides of vanadium and oxides of titanium. 
     
     
         10 . The catalyst of  claim 9 , wherein the oxidation catalyst consists of 0.45 wt % palladium, 4.5 wt % vanadium pent-oxide and supported on titanium oxide. 
     
     
         11 . The catalyst of  claim 8 , wherein the first catalyst layer has a layer thickness of between 10 and 200 micron. 
     
     
         12 . The catalyst of  claim 8 , wherein the first catalyst layer has a layer thickness of between 10 and 50 micron. 
     
     
         13 . The catalyst of  claim 8 , wherein the NH3-SCR catalyst in the second catalyst layer comprises oxides of tungsten, molybdenum, vanadium and titanium.