Soec stack with integrated heater

Abstract

An integrated heater for a Solid Oxide Electrolysis System is integrated directly in the SOEC stack, and can operate and heat the stack independently of the electrolysis process.

1 . A solid oxide electrolysis system comprising a planar solid oxide electrolysis cell stack and a heating unit for continuous operation when the solid oxide electrolysis cell stack is in operation, wherein said heating unit is an integrated part of the solid oxide electrolysis system. 
     
     
         2 . A solid oxide electrolysis system according to  claim 1 , wherein the operation temperature of said heating unit is at least the operation temperature of the cell stack minus 50° C., preferably at least the operation temperature of the cell stack. 
     
     
         3 . A solid oxide electrolysis system according to  claim 1 , wherein said heating unit has a ratio between heat transferring loss from surfaces and useful heat transferring to the cell stack of less than 200%, preferably less than 30%, preferably less than 2%. 
     
     
         4 . A solid oxide electrolysis system according to  claim 1 , wherein said heating unit is directly connected to one end plate of the cell stack and wherein the outer dimensions of the connected part of the heating unit corresponds to the outer planar dimensions of said end plate of the cell stack. 
     
     
         5 . A solid oxide electrolysis system according to  claim 1 , wherein said heating unit is arranged at one end of the cell stack and the heating unit is connected to said one end of the cell stack. 
     
     
         6 . A solid oxide electrolysis system according to  claim 1 , wherein the heating unit is arranged between the ends of two cell stacks in a sandwich arrangement. 
     
     
         7 . A solid oxide electrolysis system according to  claim 6 , wherein a plurality, preferably two heating units are arranged between the ends of two cell stacks in a sandwich arrangement. 
     
     
         8 . A solid oxide electrolysis system according to  claim 1 , wherein the heating unit comprises an electrical resistance element. 
     
     
         9 . A solid oxide electrolysis system according to  claim 8 , wherein the electrical resistance element is formed as a planar plate heating element where the current is propagating perpendicularly to the heating plate plane. 
     
     
         10 . A solid oxide electrolysis system according to  claim 8 , wherein the heating unit comprises an electrically isolating element serving to electrically isolate the electrical resistance element from the cell stack. 
     
     
         11 . A solid oxide electrolysis system according to  claim 1 , wherein the heating unit comprises a ceramic resistive heater. 
     
     
         12 . A solid oxide electrolysis system according to  claim 1 , wherein the heating unit comprises a chemical heater. 
     
     
         13 . A solid oxide electrolysis system according to  claim 12 , wherein the chemical heater comprises a catalyst enabling combustion in the chemical heater at a lower temperature than the auto ignition temperature of a burner gas provided to the chemical heater. 
     
     
         14 . A solid oxide electrolysis system according to  claim 1 , wherein said heating unit is placed in the vicinity of the manifolding where the process gas enter the cell stack whereby the heating unit heats up the process gas entering the cell stack which results in a uniform heating of the cell stack. 
     
     
         15 . A solid oxide electrolysis system according to  claim 14 , wherein said heating unit is placed between two manifolds for process gas and said two manifolds are arranged between the ends of two cell stacks in a sandwich arrangement. 
     
     
         16 . A solid oxide electrolysis system according to  claim 1 , wherein said heating unit is formed by an external manifolding for a process gas for the cell stack and the heating is performed by adding a burner gas to the process gas in the external manifolding. 
     
     
         17 . A solid oxide electrolysis system according to  claim 14 , wherein the manifolding is for a process gas on a cathode side of the SOEC cell stack. 
     
     
         18 . A solid oxide electrolysis system according to  claim 14 , wherein the manifolding is for a process gas on an anode side of the SOEC cell stack.