Photochromic glass

Abstract

Provided is photochromic glass. The photochromic glass includes a photochromic layer having visible-light transmittance decreased at short-wavelength light and having visible-light transmittance increased at long-wavelength light, a short-wavelength transmission layer provided on a surface of the photochromic layer to transmit only the short-wavelength light among lights entering the photochromic layer, and a wavelength conversion layer provided on another surface of the photochromic layer opposite to the surface to convert a wavelength of light entering the photochromic layer into a long wavelength, or a long-wavelength transmission layer transmitting only the long-wavelength among lights entering the photochromic layer. The visible-light transmittance of the photochromic layer may adjust on both surfaces of the photochromic layer through the incident direction of light. It is possible to implement various colors according to the photochromic layer and further provide a heat insulation function due to the blocking of an infrared ray of the short-wavelength transmission layer.

What is claimed is: 
     
         1 . Photochromic glass comprising:
 a photochromic layer having visible-light absorbance increased when an ultraviolet ray is irradiated, and having transmittance increased when a near infrared ray is irradiated;   a short-wavelength transmission layer disposed on a first surface of the photo-chromic layer and having higher transmittance on short-wavelength light than long-wavelength light; and   a wavelength conversion layer disposed on a second surface opposite to the first surface of the photo-chromic layer, and converting the short-wavelength light into long-wavelength light.   
     
     
         2 . The photochromic glass of  claim 1 , wherein the photo-chromic layer comprises azobenzene, spiro-naphtoxazine, naphtopyran, spiropyran, furylfulgide, stilbene, nitron, fulgide, triarylmethane, diarylethene, MoO x , or WO x . 
     
     
         3 . The photochromic glass of  claim 1 , wherein transmittance or reflectance of the short-wavelength transmission layer varies according to light entering a first surface of the short-wavelength transmission layer or light entering a second surface of the short-wavelength transmission layer opposite to the first surface of the short-wavelength transmission layer. 
     
     
         4 . The photochromic glass of  claim 1 , wherein the short-wavelength transmission layer has a thickness smaller than about 500 nm and comprises a transparent electrode material selected from ITO, ZnO:Al, ZnO:Ga, ZnO:B, SnO 2 , ZnO, TiO 2  and V 2 O 5 . 
     
     
         5 . The photochromic glass of  claim 1 , wherein the short-wavelength transmission layer is a multi-layer photofunctional thin film having a thickness smaller than about 500 nm. 
     
     
         6 . The photochromic glass of  claim 5 , wherein the multi-layer photofunctional thin film comprises a dielectric selected from ITO, ZnO:Al, ZnO:Ga, ZnO:B, SnO 2 , ZnO, TiO 2  and V 2 O 5 . 
     
     
         7 . The photochromic glass of  claim 5 , wherein the multi-layer photofunctional thin film comprises ultra-thin metal selected from silver (Ag), copper (Cu), aluminum (Al), gold (Au), platinum (Pt), zinc (Zn), chromium (Cr) and molybdenum (Mo). 
     
     
         8 . The photochromic glass of  claim 1 , wherein the wavelength conversion layer comprises an organic dye, lanthanide-based inorganic thin film, TiO x  or ZnO x . 
     
     
         9 . Photochromic glass comprising:
 a photochromic layer having visible-light absorbance increased when an ultraviolet ray is irradiated, and having transmittance increased when a near infrared ray is irradiated;   a short-wavelength transmission layer disposed on a first surface of the photo-chromic layer and having higher transmittance on short-wavelength light than long-wavelength light; and   a long-wavelength transmission layer disposed on a second surface opposite to the first surface of the photo-chromic layer, absorbing and blocking the short-wavelength light.   
     
     
         10 . The photochromic glass of  claim 9 , wherein the photo-chromic layer comprises azobenzene, spiro-naphtoxazine, naphtopyran, spiropyran, furylfulgide, stilbene, nitron, fulgide, triarylmethane, diarylethene, MoO x , or WO x . 
     
     
         11 . The photochromic glass of  claim 9 , wherein transmittance or reflectance of the short-wavelength transmission layer varies according to light entering a first surface of the short-wavelength transmission layer or light entering a second surface of the short-wavelength transmission layer opposite to the first surface of the short-wavelength transmission layer. 
     
     
         12 . The photochromic glass of  claim 9 , wherein the short-wavelength transmission layer has a thickness smaller than about 500 nm and comprises a transparent electrode material selected from ITO, ZnO:Al, ZnO:Ga, ZnO:B, SnO 2 , ZnO, TiO 2  and V 2 O 5 . 
     
     
         13 . The photochromic glass of  claim 9 , wherein the short-wavelength transmission layer is a multi-layer photofunctional thin film having a thickness smaller than about 500 nm. 
     
     
         14 . The photochromic glass of  claim 13 , wherein the multi-layer photofunctional thin film comprises a dielectric selected from ITO, ZnO:Al, ZnO:Ga, ZnO:B, SnO 2 , ZnO, TiO 2  and V 2 O 5 . 
     
     
         15 . The photochromic glass of  claim 13 , wherein the multi-layer photofunctional thin film comprises ultra-thin metal selected from silver (Ag), copper (Cu), aluminum (Al), gold (Au), platinum (Pt), zinc (Zn), chromium (Cr) and molybdenum (Mo). 
     
     
         16 . The photochromic glass of  claim 9 , wherein transmittance or reflectance of the long-wavelength transmission layer varies according to light entering a first surface of the long-wavelength transmission layer or light entering a second surface of the long-wavelength transmission layer opposite to the first surface of the long-wavelength transmission layer. 
     
     
         17 . The photochromic glass of  claim 9 , wherein the long-wavelength transmission layer has a thickness of about 20 nm to about 500 nm. 
     
     
         18 . The photochromic glass of  claim 9 , wherein the long-wavelength transmission layer comprises a light absorbing material having a band gap of about 1.5 eV to about 2.5 eV. 
     
     
         19 . The photochromic glass of  claim 18 , wherein the light absorbing material comprises amorphous silicon, microcrystalline silicon, amorphous silicon-germanium, CIGS, CdTe, GaAs, INP, SiC, SiN or SiO. 
     
     
         20 . The photochromic glass of  claim 18 , wherein the long-wavelength transmission layer further comprises a dielectric selected from ITO, ZnO:Al, ZnO:Ga, SnO 2 , ZnO, TiO 2 , Al 2 O 3 , SiO 2  and ZrO 2 .