Cosmetic compositions containing phenolic compounds

Abstract

A method of photoprotecting a keratinous substrate comprising applying a composition onto the keratinous substrate, the composition comprising at least one phenolic compound chosen from at least one ortho-diphenol, at least one phenolic compound having a carboxylic acid moiety, and mixtures thereof; a compound chosen from at least one polyamine, at least one water soluble metal salt, and mixtures thereof; and a cosmetically acceptable carrier. The present disclosure also relates to photoprotective compositions for application onto hair and skin, the compositions comprising at least one phenolic compound chosen from at least one ortho-diphenol, at least one phenolic compound having a carboxylic acid moiety, and mixtures thereof; a compound chosen from at least one polyamine, at least one water soluble metal salt, and mixtures thereof; and a cosmetically acceptable carrier.

What is claimed is: 
     
         1 . A photoprotective composition comprising:
 (a) at least one phenolic compound chosen from at least one ortho-diphenol, at least one phenolic compound having a carboxylic acid moiety, and mixtures thereof;   (b) a compound chosen from at least one polyamine, at least one water soluble metal salt, and mixtures thereof;   (c) a cosmetically acceptable carrier.   
     
     
         2 . The composition according to  claim 1 , wherein (a) is chosen from compounds derived from plant extracts, fruit extracts, citrus fruit extracts, and vegetable extracts. 
     
     
         3 . The composition according to  claim 1 , wherein (a) is an ortho-diphenol compound chosen from phenolic compounds, polyphenolic compounds, catechol compounds, catechin/epicatechin compounds, betacyanin compounds, polycyclic compounds having at least one 1,2-dihydroxybenzene moiety, and mixtures thereof. 
     
     
         4 . The composition according to  claim 1 , wherein (a) is an ortho-diphenol compound chosen from caffeoylquinic acid, caffeic acid, dihydrocaffeic acid, n-hexadecyl caffeate, caffeoyltartaric acid, chlorogenic acid, rosmarinic acid, oleuropein, hydroxytyrosol, pyrogallol, quercetin, myricetin, luteolin, isoquercitrin, carnosic acid, rutin, baicalein, gallic acid, epigallocatechol gallate, ethylhexyl gallate, digalloyl trioleate, catechin, epicatechin, epigallocatechol gallate epigallocatechin, cichoric acid, and mixtures thereof. 
     
     
         5 . The composition according to  claim 1 , wherein (a) is a phenolic compound having a carboxylic acid moiety chosen from polyphenolic compounds, catechol compounds, catechin/epicatechin compounds, betacyanin compounds, polycyclic compounds, and mixtures thereof. 
     
     
         6 . The composition according to  claim 1 , wherein (a) is a phenolic compound having a carboxylic acid moiety chosen from ferulic acid, caffeoylquinic acid, caffeic acid, dihydrocaffeic acid, n-hexadecyl caffeate, caffeoyltartaric acid and its derivatives, chlorogenic acid, rosmarinic acid, oleuropein, hydroxytyrosol, pyrogallol, quercetin, myricetin, luteolin, isoquercitrin, carnosic acid, rutin, baicalein, kaempferol, gallic acid, epigallocatechol gallate, ethylhexyl gallate, digalloyl trioleate, digalloyl trioleate, catechin, epicatechin, epicatechin-3-gallate, epigallocatechin, epigallocatechin-3-gallate, peonidin, oenin, cichoric acid, coumaric acid, quinic acid, and mixtures thereof. 
     
     
         7 . The composition according to  claim 1 , wherein (a) is selected from ferulic acid and caffeic acid, their salts, their esters and mixtures thereof. 
     
     
         8 . The composition according to  claim 1 , wherein (a) is present in an amount ranging from greater than 0% by weight to about 20% by weight, based on the total weight of the composition. 
     
     
         9 . The composition according to  claim 1 , wherein (a) is present in an amount ranging from greater than 0.1% by weight to about 5% by weight, based on the total weight of the composition. 
     
     
         10 . The composition according to  claim 1 , wherein (b) is a polyamine chosen from a polyethyleneimine, a polyvinylamine, an aminated polysaccharide, an amine substituted polyalkylene glycol, an amine substituted polyacrylate crosspolymer, an amine substituted polyacrylate, an amine substituted polymethacrylate, an aminosilicone, a protein, an amine substituted polyester, a polyamino acid, an amodimethicone, a polyalkylamine, diethylene triamine, triethylenetetramine, spermidine, spermine and mixtures thereof. 
     
     
         11 . The composition according to  claim 1 , wherein (b) is selected from polyethyleneimine, an alkoxylated polyamine, and a polyamino acid chosen from polylysine, polyarginine, chitosan, and mixtures thereof. 
     
     
         12 . The composition according to  claim 1 , wherein (b) is a polyamine present in an amount ranging from greater than 0% by weight to about 50% by weight, based on the total weight of the composition. 
     
     
         13 . The composition according to  claim 1 , wherein (b) is a polyamine present in an amount ranging from about 0.1 to about 20% by weight, based on the total weight of the composition. 
     
     
         14 . The composition according to  claim 1 , wherein (b) is a water soluble metal salt chosen from a water soluble divalent metal salt. 
     
     
         15 . The composition according to  claim 1 , wherein (b) is a water soluble metal salt present in an amount ranging from greater than 0% by weight to about 20% by weight, based on the total weight of the composition. 
     
     
         16 . The composition according to  claim 1 , wherein (b) is a water soluble metal salt present in an amount ranging from about 0.1% to about 5% by weight, based on the total weight of the composition. 
     
     
         17 . The composition according to  claim 1 , wherein (b) is selected from zinc sulfate, zinc acetate and zinc chloride. 
     
     
         18 . The composition according to  claim 1 , wherein (b) is zinc chloride. 
     
     
         19 . A photoprotective composition comprising:
 (a) from about 0.1% to about 5% by weight of at least one phenolic compound chosen from caffeic acid, ferulic acid, their salts, their esters, and mixtures thereof, and   (b) from about 0.1% to about 5% by weight of at least one polyamine chosen from polyethyleneimine, a polyamino acid, an alkoxylated polyamine and mixtures thereof;   (c) a cosmetically acceptable carrier,   
       wherein all weights are based on the total weight of the photoprotective composition. 
     
     
         20 . A photoprotective composition comprising:
 (a) from about 0.1% to about 5% by weight of at least one phenolic compound chosen from caffeic acid, ferulic acid, their salts, their esters, and mixtures thereof;   (b) from about 0.1% to about 5% by weight of at least one water soluble zinc metal salt;   (c) from about 0.1% to about 20% by weight of at least one polyamine chosen from polyethyleneimine, a polyamino acid, an alkoxylated polyamine and mixtures thereof;   (d) a cosmetically acceptable carrier, wherein all weights are based on the total weight of the photoprotective composition.