Red light-emitting fluorescent substance and light-emitting device employing the same

Abstract

The embodiment provides a red light-emitting fluorescent substance represented by the following formula (1): (M 1-x EC x ) a M 1 b AlO c N d   (1). In the formula (1), M is an element selected from the group consisting of IA group elements, IIA group elements, IIIA group elements, IIIB group elements, rare earth elements and IVA group elements; EC is an element selected from the group consisting of Eu, Ce, Mn, Tb, Yb, Dy, Sm, Tm, Pr, Nd, Pm, Ho, Er, Cr, Sn, Cu, Zn, As, Ag, Cd, Sb, Au, Hg, Tl, Pb, Bi and Fe; M 1 is different from M and is selected from the group consisting of tetravalent elements; and x, a, b, c and d are numbers satisfying the conditions of 0<x<0.2, 0.55<a<0.80, 2.10<b<3.90, 0<c≦0.25 and 4<d<5, respectively. This substance emits luminescence having a peak in the wavelength range of 620 to 670 nm when excited by light of 250 to 500 nm.

1 . A fluorescent substance represented by the following formula (1):
   (M 1-x EC x ) a M 1   b AlO c N d   (1)
   in which M is an element selected from the group consisting of IA group elements, IIA group elements, IIIA group elements, IIIB group elements, rare earth elements and IVA group elements; EC is an element selected from the group consisting of Eu, Ce, Mn, Tb, Yb, Dy, Sm, Tm, Pr, Nd, Pm, Ho, Er, Cr, Sn, Cu, Zn, As, Ag, Cd, Sb, Au, Hg, Tl, Pb, Bi and Fe; M 1  is different from M and is selected from the group consisting of tetravalent elements; and x, a, b, c and d are numbers satisfying the conditions of 0<x<0.2, 0.55<a<0.80, 2.10<b<3.90, 0<c≦0.25 and 4<d<5, respectively; and   emitting luminescence having a peak in the wavelength range of 620 to 670 nm under excitation by light in the wavelength range of 250 to 500 nm.   
     
     
         2 . The fluorescent substance according to  claim 1 , wherein said M 1  in the formula (1) is Si. 
     
     
         3 . The fluorescent substance according to  claim 1 , wherein said M in the formula (1) is an element selected from the group consisting of Li, Na, K, Mg, Ca, Sr, Ba, B, In, Ga, Y, Sc, Gd, La, Lu and Ge. 
     
     
         4 . The fluorescent substance according to  claim 1 , wherein said b in the formula (1) is a number satisfying the condition of 2.1<b<2.5. 
     
     
         5 . The fluorescent substance according to  claim 1 , wherein said c in the formula (1) is a number satisfying the condition of 0.05<c≦0.21. 
     
     
         6 . The fluorescent substance according to  claim 1 , which has a crystal structure belonging to the orthorhombic system. 
     
     
         7 . The fluorescent substance according to  claim 1 , which contains a component whose XRD profile measured by use of a specific X-ray of CuKα shows diffraction peaks simultaneously at seven or more positions selected from the group consisting of eleven positions: 15.0 to 15.25°, 23.1 to 23.20°, 24.85 to 25.05°, 26.95 to 27.15°, 29.3 to 29.6°, 30.9 to 31.1°, 31.6 to 31.8°, 33.0 to 33.20°, 35.25 to 35.45°, 36.1 to 36.25° and 56.4 to 56.65°, in terms of diffraction angle (2θ). 
     
     
         8 . A light-emitting device comprising the fluorescent substance (R) according to  claim 1  and a light-emitting element to excite said fluorescent substance. 
     
     
         9 . The device according to  claim 8 , wherein
 said light-emitting element is a light-emitting element (S2) giving off light in the wavelength range of 250 to 430 nm,   another fluorescent substance (Y) is further incorporated that emits luminescence having a peak in the wavelength range of 540 to 580 nm under excitation by light of said light-emitting element (S2), and   still another fluorescent substance (B) is furthermore incorporated that emits luminescence having a peak in the wavelength range of 400 to 490 nm under excitation by light of said light-emitting element (S2).   
     
     
         10 . The device according to  claim 9 , wherein said fluorescent substance (Y) is Y 3 Al 5 O 12 :Ce 3+ . 
     
     
         11 . The device according to  claim 9 , wherein said fluorescent substance (B) is selected from the group consisting of (Ba,Eu)MgAl 10 O 17 , (Sr,Ca,Ba,Eu) 10 (PO 4 ) 5 C 12  and (Sr,Eu)Si 9 Al 19 ON 31 . 
     
     
         12 . The device according to  claim 8 , wherein
 said light-emitting element is a light-emitting element (S1) giving off light in the wavelength range of 250 to 500 nm, and   another fluorescent substance (G) is further incorporated that emits luminescence having a peak in the wavelength range of 490 to 540 nm under excitation by light of said light-emitting element (S1).   
     
     
         13 . The device according to  claim 8 , wherein
 said light-emitting element is a light-emitting element (S2) giving off light in the wavelength range of 250 to 430 nm,   another fluorescent substance (G) is further incorporated that emits luminescence having a peak in the wavelength range of 490 to 540 nm under excitation by light of said light-emitting element (S2), and   still another fluorescent substance (B) is furthermore incorporated that emit luminescence having a peak in the wavelength range of 400 to 490 nm under excitation by light of said light-emitting element (S2).   
     
     
         14 . The device according to  claim 13 , wherein said fluorescent substance (B) is selected from the group consisting of (Ba,Eu)MgAl 10 O 17 , (Sr,Ca,Ba,Eu) 10 (PO 4 ) 6 Cl 2  and (Sr,Eu)Si 9 Al 19 ON 31 . 
     
     
         15 . A light-emitting device module comprising a plural number of the devices according to  claim 8  and a substrate on which said plural devices are placed. 
     
     
         16 . The module according to  claim 15 , satisfying the condition of 1≦(d/a)≦5 in which a is the longitudinal length of each of said devices and d is the shortest interval between neighboring two of said devices. 
     
     
         17 . (canceled)